Method for preparing high specific capacity and low leakage current carbon nanofiber nitrided conductive macromolecule composite material

A technology of carbon nanofibers and conductive polymers, which is applied in the field of carbon materials and chemical power sources, can solve problems such as unknown influences, achieve the effects of increasing nitrogen content, increasing specific capacity, and avoiding irreversible stacking

Active Publication Date: 2014-10-01
GUIZHOU AVIC JODO TECH
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Problems solved by technology

However, there are no international reports on nitrogen-doped graphene oxide, and the effect of nitrogen doping on graphene oxide and corresponding graphene is still unknown.

Method used

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  • Method for preparing high specific capacity and low leakage current carbon nanofiber nitrided conductive macromolecule composite material
  • Method for preparing high specific capacity and low leakage current carbon nanofiber nitrided conductive macromolecule composite material
  • Method for preparing high specific capacity and low leakage current carbon nanofiber nitrided conductive macromolecule composite material

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preparation example Construction

[0067] The preparation method of a carbon nanofiber nitrided conductive polymer composite material with high specific capacity and low leakage current provided in this embodiment specifically includes:

[0068] 1) Weigh with JA2003N electronic balance (Shanghai Precision Scientific Instrument Co., Ltd.), the water-soluble carboxylated graphene powder is formulated into suspoemulsion A with a content of 2-3%, and CHJ-1 constant temperature magnetic stirrer (Shanghai Nanhui Telecom Apparatus factory) stir evenly, and equal amount is divided into three parts for subsequent use, and the content of the preferred water-soluble carboxylated graphene of the present embodiment is 2%;

[0069]2) Dissolve polyacrylonitrile (PAN) in N,N-dimethylformamide (DMF), then use high-voltage electrospinning technology to weave PAN precursors, and put the spun PAN precursors in a tubular reactor Carry out carbonization to prepare carbon nanofibers (CNFs), then add carbon nanofibers (CNFs) in 1 part...

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Abstract

The invention discloses a method for preparing a high specific capacity and low leakage current carbon nanofiber nitrided conductive macromolecule composite material. The method mainly comprises the following steps: firstly, preparing carbon nanofibers (CNFs), subsequently adding the carbon nanofibers (CNFs) and a conductive macromolecule monomer into water-soluble carboxyl graphene suspension emulsion, further adding an oxidant solution, washing, nitriding to prepare a nitrogen doped porous carbon material, and finally secondarily modifying the nitrogen doped porous carbon material in the nitrogen doped porous carbon material, thereby preparing the high specific capacity and low leakage current carbon nanofiber nitrided conductive macromolecule composite material. By adopting the method, the nitrided conductive macromolecule composite material can be rapidly, effectively and cheaply prepared, meanwhile the nitrogen content of the nitrided conductive macromolecule composite material is ensured, the specific capacity is increased, and moreover by controlling variables such as the temperature and the nitrogen flowing speed, stable and effective reaction formation of the carbon nanofiber nitrided conductive macromolecule composite material is ensured, and the property of low leakage current is ensured.

Description

technical field [0001] The invention relates to the technical field of carbon materials and chemical power sources, in particular to a method for preparing a carbon nanofiber nitrided conductive polymer composite material with high specific capacity and low leakage current. Background technique [0002] Today, with the emphasis on the ecological environment and economic benefits, people are committed to obtaining low-cost and clean energy from solar and wind energy, which will fundamentally meet the growing energy demand. However, only by converting these renewable energies into electrical energy and storing them can they be used anytime and anywhere, obviously this will not be able to meet people's daily needs. Supercapacitors offer a promising way to quickly store electrical energy. In addition, supercapacitors are also widely used in many other fields, such as: mobile electronic equipment, hybrid vehicles and backup power systems. As a new type of energy device, superca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G73/06C08G61/12C08G73/02C08K13/06C08K9/04C08K7/06C08K3/04
Inventor 陆胜施洪权
Owner GUIZHOU AVIC JODO TECH
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