Novel acidic anti-staining soap lotion and preparation method thereof
An anti-staining soaping agent and acid technology, applied in the field of textile printing and dyeing, can solve the problems of unsatisfactory anti-staining effect, reducing the pressure of sewage treatment, unsuitable anti-staining agent, etc., so as to improve the dyeing fastness and reduce the production process. , the effect of strong dispersing and chelating ability
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Embodiment 1-1
[0024] Example 1-1 Preparation of Didodecylamine Polyoxyethylene Ether Diquaternary Ammonium Salt
[0025] Add 715.6g (0.30mol) of didodecanylamine polyoxyethylene ether and 37.5g (0.15mol) of biphenyl benzyl dichloride into a four-neck flask, raise the temperature to 100°C-150°C, react for 4 hours, then cool down to 50°C , add 85.3g of deionized water, heat preservation reaction for 10h, to obtain a brown viscous liquid.
Embodiment 1-2
[0026] Embodiment 1-2 Preparation of maleic anhydride-acrylic acid-N-vinylpyrrolidone terpolymer
[0027] In a four-neck flask equipped with a reflux condenser and a dropping funnel, add 50.0 g of maleic anhydride and 55.0 g of water, heat to 60°C-70°C and stir to make it completely dissolved and transparent; add NaOH aqueous solution to adjust the pH to neutral, Continue to raise the temperature. When the temperature rises to 80°C-90°C, add 150.0g of acrylic acid, 12.5g of N-vinylpyrrolidone and 5.0g of ammonium persulfate solution dropwise at the same time. React at a constant temperature of 90°C for 6h. After the reaction is completed, adjust the pH to 3-5 with NaOH aqueous solution, and cool down to 50°C to obtain a light yellow viscous liquid.
Embodiment 1-3
[0028] Embodiment 1-3 soaping agent preparation
[0029] In a four-neck flask, add 100.0 g of didodecylamine polyoxyethylene ether bisquaternary ammonium salt and 235.0 g of deionized water, heat up to 60°C-70°C and stir evenly; add maleic anhydride-acrylic acid-N - 150.0 g of vinylpyrrolidone terpolymer and 15.0 g of carboxyethylthiosuccinic acid, and continue stirring for 30 minutes. Prepare the soaping agent used in this experiment.
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