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Hygroscopic polymer and raw material obtained by containing the polymer

A technology of raw materials and polymers, applied in polyurea/polyurethane coatings, coatings, etc., can solve problems such as white appearance and shape changes, and achieve excellent hygroscopic performance and excellent water resistance.

Active Publication Date: 2017-02-08
JAPAN EXLAN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to its high hydrophilicity, the coating film and resin molded product obtained by adding the fine particles will become whitish in appearance or change in shape when wetted with water, etc., in terms of durability against water, That is, there is a problem with water resistance

Method used

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  • Hygroscopic polymer and raw material obtained by containing the polymer
  • Hygroscopic polymer and raw material obtained by containing the polymer
  • Hygroscopic polymer and raw material obtained by containing the polymer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0094] Add a monomer mixture consisting of 74 parts of acrylonitrile, 1 part of vinyl acetate, and 25 parts of divinylbenzene to 300 parts of an aqueous solution containing 0.5 parts of ammonium persulfate, and then add 0.6 parts of sodium metabisulfite. Polymerization was carried out at 65°C for 2 hours in a tank. The resulting polymer was filtered and washed with water. Next, 100 parts of this polymer was added to 567 parts of 10% sodium hydroxide aqueous solution, and the hydrolysis reaction was performed at 95 degreeC for 48 hours. Next, the obtained polymer was filtered and washed with water to obtain hygroscopic fine particles 1 . The evaluation results of the pellets are shown in Table 1, and the water resistance was good. Moreover, when the hygroscopicity expression rate was measured about the sample used for water resistance evaluation, it was 90.7% or more.

[0095] In addition, the hygroscopic microparticles 1 were pulverized to have an average particle diameter ...

Embodiment 2

[0099] In Example 1, as a monomer mixed solution, a monomer mixed solution composed of 64 parts of acrylonitrile, 1 part of vinyl acetate, and 35 parts of divinylbenzene was used, except that it was performed in the same manner as in Example 1 to obtain a hygroscopic Sexual particles3. The evaluation results of the pellets are shown in Table 1, and the water resistance was good.

Embodiment 3

[0103] In Example 1, as a monomer mixed solution, a monomer mixed solution composed of 56.7 parts of acrylonitrile, 8.3 parts of vinyl acetate, and 35 parts of divinylbenzene was used, except that the same operation as in Example 1 was used to obtain a hygroscopic Sexual particles5. The evaluation results of the pellets are shown in Table 1, and the water resistance was good.

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Abstract

[Problem] When moisture absorptive and desorptive microparticles are added to coatings or resin compacts in order to impart moisture absorptive and desorptive qualities, in cases such as when the material becomes wet with water, problems arise that include the appearance of the material becoming whitish or deformation occurring. As a result of diligent and continued research, the present inventor discovered that a vinyl-based polymer with a salt-type carboxyl group, a hydroxyl group, and a cross-linked structure, when compounded with a coating or resin compact, would provide both strong moisture absorptive and desorptive properties and outstanding water resistance, thus achieving the present invention. The purpose of the present invention is to provide, in a case where compounding is performed with a coating, resin compact, or the like, a polymer that can impart strong moisture absorptive and desorptive properties and strong moisture permeability and a polymer that can impart strong water resistance, as well as a material containing such a polymer. [Solution] A moisture absorptive and desorptive polymer characterized in that it contains 1-7 mmol / g of a salt-type carboxyl group and 0.01-10 mmol / g of a hydroxyl group and is a vinyl-based polymer with a cross-linked structure.

Description

technical field [0001] The present invention relates to a moisture-absorbing and desorbing polymer capable of obtaining moisture-absorbing and desorbing performance, high moisture-permeable performance, and excellent water resistance by adding to a coating film, a resin molded article, etc., and a molded product containing the polymer. body. Background technique [0002] For a long time, inorganic hygroscopic agents such as lithium chloride, calcium chloride, magnesium chloride, and phosphorus pentoxide have been used as a means of removing moisture in the air. Although these inorganic hygroscopic agents have a large amount of moisture absorption and a fast moisture absorption rate, they have Deliquescence, so it has the disadvantages of liquefaction after moisture absorption and contamination of other items, or difficulty in shaping and regeneration. In addition, hygroscopic agents such as silica gel, zeolite, sodium sulfate, activated alumina, and activated carbon have th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F8/12C08F8/44C08F220/06C08L101/00C08L101/02C08G18/62
CPCC09D175/04C08F8/12C08F8/44C08G18/6229C08J3/12C08J2333/20
Inventor 小见山拓三
Owner JAPAN EXLAN CO LTD