Carbon fiber reinforced ABS (Acrylonitrile Butadiene Styrene) resin composite material with superior heat conductivity and preparation method

An ABS resin and composite material technology, applied in the field of carbon fiber composite materials, can solve the problems of complex preparation process, high density, decreased mechanical properties, etc., and achieve the effects of expanding application fields, simple preparation process, and improving mechanical properties

Inactive Publication Date: 2014-11-19
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, metal thermally conductive fillers have the disadvantages of high density, corrosion, and the decline in the mechanical properties of ABS materials; inorganic non-metallic fillers are not very effective in improving the thermal conductivity of ABS resins, and often reduce the mechanical properties of ABS resins.
Although the method of using carbon materials such as graphene, carbon nanotubes and nano-carbon fibers can significantly improve the thermal conductivity of ABS resin, these materials are expensive and cannot be industrialized, and the technologies involved are only in laboratory research. stage
Document 1 prepared the thermally conductive ABS / pitch carbon fiber composite material by impregnating the acetone solution of ABS resin into the self-made pitch-based carbon fiber, vacuuming the solvent, and then hot-pressing. Organic solvents will cause harm such as the decline of mechanical properties, and it is completely unfeasible in industry; in addition, there are still problems such as not suitable for the preparation of products with complex structures, materials with only one-dimensional and two-dimensional thermal conductivity, and mechanical properties that have not been improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028]Take by weight 90 parts of content ABS resin, 10 parts of maleic anhydride grafted ABS, 10 parts of carbon fiber, 10 parts of inorganic filler (talcum powder, magnesium oxide and aluminum oxide, weight ratio 1: 3: 1), coupling agent (γ -Aminopropyltriethoxysilane and γ-glycidyloxypropyltrimethoxysilane, weight ratio 1:1) 0.5 parts, antioxidant (tetrakis[β-(3,5-di-tert-butyl- 4-hydroxyphenyl) propionic acid] pentaerythritol ester) 0.2 part and lubricant 0 part batching; ABS resin, maleic anhydride grafted ABS resin, inorganic filler, coupling agent, antioxidant and lubricant etc. are put into high-speed mixing Mix evenly in the machine at high speed, feed to the hopper of the extruder, add carbon fiber at the fiber feeding port of the extruder, control the temperature of each zone from the feeding port to the die head of the extruder to be 150°C, 175°C, 185°C, 195°C °C, 195 °C, 200 °C, the speed of the main machine is 50 Hz, and the composite material can be obtained by e...

Embodiment 2

[0031] Take by weight 90 parts of content ABS resin, 10 parts of maleic anhydride grafted ABS, 80 parts of carbon fiber, 10 parts of inorganic filler (talcum powder, magnesium oxide and aluminum oxide, weight ratio 1: 3: 1), coupling agent (γ -Aminopropyltriethoxysilane and γ-glycidyloxypropyltrimethoxysilane, weight ratio 1:1) 5 parts, antioxidant (tetrakis[β-(3,5-di-tert-butyl- 4-hydroxyphenyl) propionic acid] pentaerythritol ester) 1 part and lubricant (ethylene bisfatty acid amide) 3 parts of ingredients; ABS resin, maleic anhydride grafted ABS resin, inorganic filler, coupling agent, antioxidant and lubricants are put into the high-speed mixer and mixed evenly at high speed, and the material is fed to the hopper of the extruder, and the carbon fiber is added at the fiber feeding port of the extruder. 175°C, 185°C, 195°C, 195°C, 200°C, the speed of the main engine is 50 Hz, and the composite material can be obtained by extruding and granulating through a twin-screw extrude...

Embodiment 3

[0034] Take by weight 90 parts of content ABS resin, 10 parts of maleic anhydride grafted ABS, 40 parts of carbon fiber, 10 parts of inorganic filler (talcum powder, magnesium oxide and aluminum oxide, weight ratio 1: 3: 1), coupling agent (γ -Aminopropyltriethoxysilane and γ-glycidyloxypropyltrimethoxysilane, weight ratio 1:1) 2 parts, antioxidant (tetrakis[β-(3,5-di-tert-butyl- 4-hydroxyphenyl) propionic acid] pentaerythritol ester) 0.6 part and lubricant (ethylene bis fatty acid amide) 1 part batching; ABS resin, maleic anhydride grafted ABS resin, inorganic filler, coupling agent, antioxidant and lubricants are put into the high-speed mixer and mixed evenly at high speed, and the material is fed to the hopper of the extruder, and the carbon fiber is added at the fiber feeding port of the extruder. 175°C, 185°C, 195°C, 195°C, 200°C, the speed of the main engine is 50 Hz, and the composite material can be obtained by extruding and granulating through a twin-screw extruder. ...

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Abstract

The invention discloses a carbon fiber reinforced ABS (Acrylonitrile Butadiene Styrene) resin composite material with superior heat conductivity and a preparation method. The composite material consists of the following materials in parts by weight: 90 parts of ABS resin, 10 parts of maleic anhydride grafted ABS, 10-80 parts of carbon fibers, 10-20 parts of an inorganic filler, 0.5-5 parts of a coupling agent, 0.2-1 part of an antioxidant and 0-3 parts of a lubricating agent. The preparation method comprises the following steps: mixing the raw materials in a certain mixture ratio; mixing the raw materials except the carbon fibers at a high speed; and adding an obtained mixture into a hopper of a double-screw extruder, adding the carbon fibers through the fiber inlet of the extruder, extruding the mixture, and granulating the extruded mixture. Compared with the prior art, the composite material provided by the invention has high rigidity and high heat dissipation performance and is suitable for the production and machining of thin-wall light electronic / electric products; and moreover, the raw material cost is low, a preparation process is simple, and the method is suitable for industrial continuous production.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber composite materials, and in particular relates to a carbon fiber reinforced thermoplastic ABS resin composite material with excellent thermal conductivity and a preparation method thereof. Background technique [0002] ABS resin refers to acrylonitrile-butadiene-styrene copolymer, which is non-toxic, tasteless, low water absorption, mechanical properties, thermal properties, wear resistance, chemical resistance and dyeability, good molding and mechanical processing Good performance, widely used in refrigerator lining, TV casing, vacuum cleaner, air conditioner, telephone, instrument, computer, copier and other electronic and electrical industries. With social development and industrial progress, electronic components and electronic equipment are becoming more and more thin-walled, lightweight, and miniaturized. Therefore, the requirements for the rigidity and thermal conductivity of materials...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L51/00C08K7/06C08K3/04C08K3/34C08K7/20C08K3/26C08K3/30B29C47/92B29C48/92
Inventor 杨斌王新灵张媛媛刘媛袁角亮
Owner SHANGHAI JIAO TONG UNIV
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