Ethoxy (2) bisphenol S diacrylate and preparation method thereof
A technology of diacrylate and ethoxylation, which is applied in chemical instruments and methods, preparation of organic compounds, organic chemistry, etc. It can solve the problems that small and medium-sized enterprises cannot afford, the catalyst regeneration process is complicated, and the catalytic efficiency is low, so as to achieve safety High, low cost, high catalytic efficiency
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Embodiment 1
[0041]Add 19.0 grams of dihydroxyethyl bisphenol S (0.056mol, 0.112mol-OH, 1eq, 2eq-OH) and 12.1 grams of acrylic acid ( 0.16mol, 3.0eq, 1.5eq-OH), 46 grams of toluene, 0.54 grams of methanesulfonic acid (0.0056mol, 10eq%), 0.16 grams of p-hydroxyanisole (0.5wt%), nitrogen protection has been passed during the reaction , after reflux reaction at 110-115°C for 6 hours, a brownish-red liquid was obtained, and about 2.0 ml of water was generated. TLC analysis (exhibiting liquid: volume of ethyl acetate / volume of cyclohexane=1 / 1) has not observed dihydroxy Ethyl bisphenol S(R f =0.07) points; and only the product ethoxylated (2) bisphenol S diacrylate (R f =0.86), the reaction was stopped.
[0042] After the reaction, the reaction mixture was washed twice with 5% aqueous sodium hydroxide solution, then washed three times with distilled water, and finally dried with anhydrous magnesium sulfate, and then 0.03 p-hydroxyanisole, a polymerization inhibitor, was added to the dried sol...
Embodiment 2
[0044] Add 19.0 grams of dihydroxyethyl bisphenol S (0.056mol, 0.112mol-OH, 1eq, 2eq-OH) and 12.1 grams of acrylic acid ( 0.16mol, 3.0eq, 1.5eq-OH), 46 grams of toluene, 0.96 grams of p-toluenesulfonic acid (0.0056mol, 10eq%), 0.16 grams of p-hydroxyanisole (0.5wt%), nitrogen protection has been passed during the reaction , after reflux reaction at 110-115°C for 6.5 hours, a brownish-red liquid was obtained, and about 2.0 ml of water was generated. TLC analysis (exhibited liquid: volume of ethyl acetate / volume of cyclohexane=1 / 1) has not observed dihydroxy Ethyl bisphenol S(R f =0.07) points; and only the product ethoxylated (2) bisphenol S diacrylate (R f =0.86), the reaction was stopped.
[0045] After the reaction, the reaction mixture was washed twice with 5% aqueous sodium hydroxide solution, then washed three times with distilled water, and finally dried with anhydrous magnesium sulfate, and then 0.03 p-hydroxyanisole, a polymerization inhibitor, was added to the dried...
Embodiment 3
[0047] The technical scheme of embodiment 3 is identical with embodiment 1, only difference is as follows:
[0048] (1) The mol ratio of dihydroxyethyl bisphenol S and acrylic acid is 1:2.2;
[0049] (2) The consumption of solvent toluene is 0.8 times of the weight sum of dihydroxyethyl bisphenol S and acrylic acid;
[0050] (3) The consumption of p-toluenesulfonic acid is 2% of the molar weight of dihydroxyethyl bisphenol S;
[0051] (4) polymerization inhibitor is p-hydroxyanisole, and its consumption is 0.1% of the gross weight of dihydroxyethyl bisphenol S and acrylic acid;
[0052] (5) The esterification reaction time is 8 hours.
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