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High-strength wear-resisting flame-retardant modified ethylene-propylene-diene monomer rubber and preparation method thereof

An EPDM rubber and high-strength technology, applied in the field of EPDM rubber, can solve problems such as poor wear resistance, lack of flame retardancy, and hidden dangers in production safety, and achieve improved comprehensive performance, high strength, and weakened reversion effect

Inactive Publication Date: 2015-01-28
TIANCHANG HIGH TECH ENTREPRENEURSHIP SERVICE CENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can absorb a large amount of fillers and oils without greatly affecting its properties, so it can be made into low-cost rubber compounds; however, its strength is not high, its wear resistance is not good, and in actual use, its flame retardancy is lacking, which is harmful to safety production. Here comes the hidden danger

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019]A kind of high-strength wear-resistant flame-retardant modified EPDM rubber proposed by the present invention, its raw materials include by weight: 44 parts of EPDM rubber, 20 parts of chlorinated butyl rubber, 24 parts of natural rubber, LH- 0.8 parts of C96 vulcanizing agent, 1.5 parts of N,N'-m-phenylbismaleimide, 1.5 parts of accelerator TMTD, 4 parts of magnesium oxide, 1 part of stearic acid, 10 parts of trioctyl trimellitate, 2.5 parts of environmentally friendly flame retardant FR-T801, 1.6 parts of antimony trioxide, 20 parts of modified titanium dioxide, 30 parts of coal gangue powder, 20 parts of calcined clay, 1.5 parts of monoalkoxypyrophosphate titanate coupling agent , 1.3 parts of anti-aging agent 800-B, 2.1 parts of anti-aging agent BLE, wherein the ethylene-propylene ratio of EPDM rubber is 4:1, and the active chlorine content in chlorinated butyl rubber is 1.4wt%;

[0020] Wherein in the preparation process of modified titanium dioxide, 11 parts of tit...

Embodiment 2

[0023] A kind of high-strength wear-resistant flame-retardant modified EPDM rubber proposed by the present invention, its raw materials include by weight: 36 parts of EPDM rubber, 25 parts of chlorinated butyl rubber, 18 parts of natural rubber, LH- 1.5 parts of C96 vulcanizing agent, 0.5 parts of N,N'-m-phenylbismaleimide, 1.8 parts of accelerator TMTD, 2 parts of magnesium oxide, 3 parts of stearic acid, 5 parts of trioctyl trimellitate, 4 parts of environmentally friendly flame retardant FR-T801, 0.8 parts of antimony trioxide, 40 parts of modified titanium dioxide, 15 parts of coal gangue powder, 30 parts of calcined clay, 1.2 parts of monoalkoxypyrophosphate titanate coupling agent , 1.8 parts of anti-aging agent 800-B, 1.5 parts of anti-aging agent BLE, wherein the ethylene-propylene ratio of EPDM rubber is 3:2, and the active chlorine content in chlorinated butyl rubber is 1.1wt%;

[0024] Wherein in the preparation process of modified titanium dioxide, 8 parts of titan...

Embodiment 3

[0027] A kind of high-strength wear-resistant flame-retardant modified EPDM rubber proposed by the present invention, its raw materials include by weight: 40 parts of EPDM rubber, 22 parts of chlorinated butyl rubber, 20 parts of natural rubber, LH- 0.9 parts of C96 vulcanizing agent, 1.2 parts of N,N'-m-phenylbismaleimide, 1.6 parts of accelerator TMTD, 3 parts of magnesium oxide, 1.5 parts of stearic acid, 8 parts of trioctyl trimellitate, 3 parts of environmentally friendly flame retardant FR-T801, 1.2 parts of antimony trioxide, 25 parts of modified titanium dioxide, 10 parts of coal gangue powder, 23 parts of calcined clay, 1.4 parts of monoalkoxypyrophosphate titanate coupling agent , 1.4 parts of anti-aging agent 800-B, 2 parts of anti-aging agent BLE, wherein the ethylene-propylene ratio of EPDM rubber is 4:1, and the active chlorine content in chlorinated butyl rubber is 1.2wt%;

[0028] Wherein in the preparation process of modified titanium dioxide, 10 parts of tita...

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PUM

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Abstract

The invention discloses high-strength wear-resisting flame-retardant modified ethylene-propylene-diene monomer rubber. The high-strength wear-resisting flame-retardant ethylene-propylene-diene monomer rubber is prepared from the following raw materials in parts by weight: 36-44 parts of ethylene-propylene-diene monomer rubber, 20-25 parts of chlorinated butyl rubber, 18-24 parts of natural rubber, 0.8-1.5 parts of a vulcanizing agent LH-C96, 0.5-1.5 parts of N,N'-1,3-Phenylenedimaleimide, 1.5-1.8 parts of an accelerant TMTD (Tetramethylthiuram Disulfide), 2-4 parts of magnesium oxide, 1-3 parts of stearic acid, 5-10 parts of trioctyl trimellitate, 2.5-4 parts of an environment-friendly flame retardant FR-T 801, 0.8-1.6 parts of antimony trioxide, 20-40 parts of modified titanium dioxide, 15-30 parts of coal gangue powder, 20-30 parts of calcined clay, 1.2-1.5 parts of a monoalkoxy pyrophosphate type titanate coupling agent, 1.3-1.8 parts of an antiager 800-B, and 1.5-2.1 parts of an antiager BLE (High temperature condensation compound of diphenylamine and acetone). The invention further discloses a preparation method of the high-strength wear-resisting flame-retardant modified ethylene-propylene-diene monomer rubber.

Description

technical field [0001] The invention relates to the technical field of EPDM rubber, in particular to a high-strength wear-resistant and flame-retardant modified EPDM rubber and a preparation method thereof. [0002] Background technique [0003] EPDM rubber is a terpolymer of ethylene, propylene and non-conjugated dienes. It has excellent resistance to oxidation and ozone. EPDM rubber is non-polar and resistant to polar solutions and chemicals. properties, low water absorption, so it has good insulation and strong corrosion resistance, and because EPDM rubber belongs to the polyolefin family, it has excellent vulcanization characteristics; among all rubbers, EPDM rubber has the lowest proportion. It can absorb a large amount of fillers and oils without greatly affecting its properties, so it can be made into low-cost rubber compounds; however, its strength is not high, its wear resistance is not good, and in actual use, its flame retardancy is lacking, which is harmful to...

Claims

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Application Information

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IPC IPC(8): C08L23/16C08L23/28C08L7/00C08K13/06C08K9/10C08K3/22C08K5/3415C08K5/40C08K5/12C08K5/09B29B7/28
CPCB29B7/005B29B7/183B29B7/7495C08L23/16C08L2201/02C08L2201/08C08L2205/02C08L2205/03C08L23/283C08L7/00C08K13/06C08K9/10C08K2003/2237C08K2003/222C08K3/346C08K5/09C08K5/12C08K3/2279C08K5/40C08K5/3415C08K3/00
Inventor 周丹
Owner TIANCHANG HIGH TECH ENTREPRENEURSHIP SERVICE CENT
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