Polyurethane composite material regenerated from waste polyurethane soles and preparation process thereof

A composite material and polyurethane technology, applied in the chemical industry, can solve the problems of land occupation, environmental pollution, waste of resources, etc., and achieve the effects of environmental protection, no discharge of three wastes, and solution to recycling problems

Inactive Publication Date: 2015-03-25
JINJIANG MINGAO TEXTILE SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If these wastes are only disposed of by landfill and incineration, it will not only

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A recycled polyurethane composite material using waste polyurethane soles, prepared from the following raw materials in parts by weight (kg): waste polyurethane soles 170, compatibilizer 10, toluene diisocyanate 5, tris(2,4-di-tert-butylphenol ) phosphite 2, medical stone powder 4, silicone 6, ammonium polyphosphate 2, polyisocyanate 12, mixed polyester polyol 3, dibutyltin dilaurate 5, alkyl alcohol amide 6, nano-alumina powder 4, Antioxidant TNP 2, aluminum stearate 7, isocyanate 8, zirconia 4, nano-montmorillonite 9, auxiliary agent 10; the auxiliary agent is made of the following raw materials in parts by weight (kg): aluminum tripolyphosphate 1 , palm wax 2, talcum powder 4, liquid paraffin 2, calcium carbonate 13, ethylene bis stearamide 3, ethyleneimine 1, hydrogenated castor oil 7, sodium stearate 10, graphene 6, epoxy resin 7; The preparation method is: weigh the aluminum tripolyphosphate, palm wax, talcum powder, liquid paraffin and calcium carbonate in the ab...

Embodiment 2

[0023] A recycled polyurethane composite material using waste polyurethane soles, prepared from the following raw materials in parts by weight (kg): waste polyurethane soles 175, compatibilizer 12, toluene diisocyanate 6, tris(2,4-di-tert-butylphenol ) phosphite 3, medical stone powder 5, silicone 7, ammonium polyphosphate 2.5, polyisocyanate 15, mixed polyester polyol 4, dibutyltin dilaurate 6, alkanolamide 7, nano-alumina powder 4.5, Antioxidant TNP 2.5, aluminum stearate 8, isocyanate 9, zirconia 5, nano-montmorillonite 10, auxiliary agent 11; the auxiliary agent is made of the following raw materials in parts by weight (kg): aluminum tripolyphosphate 1.5 , palm wax 2.5, talcum powder 4.5, liquid paraffin 2.5, calcium carbonate 14.5, ethylene bis stearamide 3.5, ethyleneimine 1.5, hydrogenated castor oil 8, sodium stearate 11, graphene 7, epoxy resin 10; The preparation method is: weigh the aluminum tripolyphosphate, palm wax, talcum powder, liquid paraffin and calcium carb...

Embodiment 3

[0026] A recycled polyurethane composite material using waste polyurethane soles, prepared from the following raw materials in parts by weight (kg): waste polyurethane soles 180, compatibilizer 14, toluene diisocyanate 7, tris(2,4-di-tert-butylphenol ) phosphite 4, medical stone powder 6, silicone 8, ammonium polyphosphate 3, polyisocyanate 18, mixed polyester polyol 5, dibutyltin dilaurate 7, alkyl alcohol amide 8, nano-alumina powder 5, Antioxidant TNP 3, aluminum stearate 9, isocyanate 10, zirconia 6, nano-montmorillonite 11, auxiliary agent 12; the auxiliary agent is made of the following raw materials in parts by weight (kg): aluminum tripolyphosphate 2 , palm wax 3, talcum powder 5, liquid paraffin 3, calcium carbonate 16, ethylene bis stearamide 4, ethyleneimine 2, hydrogenated castor oil 9, sodium stearate 12, graphene 8, epoxy resin 13; The preparation method is: weigh the aluminum tripolyphosphate, palm wax, talcum powder, liquid paraffin and calcium carbonate in the...

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PUM

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Abstract

The invention discloses a polyurethane composite material regenerated from waste polyurethane soles and a preparation process thereof. The polyurethane composite material is prepared from the following raw materials in parts by weight: 170-180 parts of waste polyurethane soles, 10-14 parts of a compatibilizer, 5-7 parts of toluene diisocynate, 2-4 parts of tri(2,4-di-tert-butylphenol) phosphite ester, 4-6 parts of medical stone powder, 6-8 parts of organic silicon, 2-3 parts of ammonium polyphosphate, 12-18 parts of polyisocyanate, 3-5 parts of hybrid polyester polyol, 5-7 parts of dibutyltin dilaurate, 6-8 parts of alkanolamide, 4-5 parts of nano-alumina powder, 2-3 parts of antioxidant TNP, 7-9 parts of aluminum stearate, 8-10 parts of isocyanate, 4-6 parts of zirconium oxide, 9-11 parts of nano montmorillonite and 10-12 parts of additives. According to the invention, on one hand, the recovery problem of the waste polyurethane soles is solved, on the other hand, the raw materials are easy to obtain, the cost is low, the operation is simple, and emission of three wastes is avoided in the production, so as to protect the environment and reduce the production cost, and ensure that the economic benefit and the social benefit are considerable.

Description

technical field [0001] The invention belongs to the field of chemical industry, and in particular relates to a recycled polyurethane composite material utilizing waste polyurethane shoe soles and a preparation process thereof. Background technique [0002] With its excellent physical properties, good processability, excellent chemical resistance and aging resistance, polyurethane has become one of the most widely used polymer materials in the field of application, and its output and application range are constantly expanding. middle. However, with the expansion of production scale and the expansion of application fields, a large amount of waste is generated during the production and use of polyurethane, including a large amount of polyurethane foam used for heat insulation and sofa cushions, waste polyurethane soles, waste polyurethane leather, etc. If these wastes are only disposed of by landfill and incineration, it will not only occupy land, but also pollute the environ...

Claims

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Application Information

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IPC IPC(8): C08L75/04C08L75/06C08K13/02C08K5/526C08K3/34C08K5/54C08K3/32C08K3/22C08K5/098C08G18/42
Inventor 杨小波陈桂兰
Owner JINJIANG MINGAO TEXTILE SCI & TECH
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