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General light source response modified titanium dioxide solid acid catalyst and preparation method

A solid acid catalyst, titanium dioxide technology, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the constraints of commercial application of catalysts, high energy consumption, ecological System impact and other issues, to achieve good photocatalytic degradation effect, no secondary pollution, fast degradation effect

Active Publication Date: 2015-04-01
SANMING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Modern industrialized production methods and human lifestyles lead to the discharge of a large number of pollutants that pose a serious threat to the survival of animals and plants into the environment, causing irreversible environmental pollution and directly affecting and destroying the ecosystem.
Among them, industrial production wastewater and domestic sewage pollute the environment particularly seriously, which has caused many environmental pollution incidents and brought irreparable losses to the country and society.
Photocatalytic degradation of pollutants in water is an efficient, environmentally friendly, and energy-saving technology. The United States, Japan and other countries have produced corresponding photocatalytic products and commercialized them. However, my country's technology in this area still needs breakthroughs.
[0003] Titanium dioxide is a photocatalyst with potential applications, but it is difficult to compete with traditional products due to its low degradation efficiency. Therefore, the key to this technology is to improve its catalytic activity by modifying it.
At present, the method of noble metal modification can obtain better results, but another reason restricts the commercial application of this catalyst, that is, the need to use expensive and energy-intensive light sources such as xenon lamps

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 1. In 50ml of water, add 1 gram of TiO 2 and 0.01g H 2 PtC1 6 , sonicated for 5 minutes to mix the reaction solution evenly, under the condition of magnetic stirring, with 100W xenon lamp as the light source, 0.5ml absolute ethanol as the sacrificial agent, and photodeposition reaction for 1 hour; then filtered, washed, dried and ground to obtain Pt / TiO 2 catalyst;

[0022] 2. Transfer the above catalyst to a polytetrafluoroethylene-lined stainless steel autoclave, add 15ml of 1mol / L sulfuric acid, and react at 100°C for 24h; wash with deionized water until no sulfate ion is detected; then Dry at 50°C for 24 hours to obtain a solid acid catalyst that responds to Pt-modified titanium dioxide with a universal light source.

Embodiment 2

[0024] 1. In 100ml of water, directly add 5 grams of TiO 2 and 0.05 g AuC1 3 , ultrasonication for 7 minutes to mix the reaction solution evenly, under the condition of magnetic stirring, with 300W xenon lamp as light source, 2ml absolute ethanol as sacrificial agent, photodeposition reaction for 2.5 hours; then through suction filtration, washing, drying and grinding, Au / TiO 2 catalyst;

[0025] 2. Transfer the above catalyst to a polytetrafluoroethylene-lined stainless steel autoclave, add 50ml of 2mol / L sulfuric acid, and react at 150°C for 12h; wash with deionized water until no sulfate ion is detected; then Dry at 105° C. for 5 hours to obtain a universal light source response Au-modified titanium dioxide solid acid catalyst.

Embodiment 3

[0027] 1. In 150ml of water, add 10 grams of TiO 2 and 0.1 g PdC1 2 , sonicated for 10 minutes to mix the reaction solution evenly, under the condition of magnetic stirring, with 200W xenon lamp as the light source, 5ml of absolute ethanol as the sacrificial agent, photodeposition reaction for 5 hours; then through suction filtration, washing, drying and grinding, Pd / TiO 2 catalyst;

[0028] 2. Transfer the above catalyst to a polytetrafluoroethylene-lined stainless steel autoclave, add 20ml of 5mol / L sulfuric acid, and react at 200°C for 6h; wash with deionized water until no sulfate ion is detected; then After drying at 75°C for 12 hours, a general-purpose light source-responsive high-efficiency titanium dioxide-modified solid acid catalyst was obtained.

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PUM

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Abstract

The invention belongs to the field of preparation of a catalyst, and particularly relates to a general light source response modified titanium dioxide solid acid catalyst and a preparation method. The preparation method comprises the steps of bearing precious metal on a TiO2 carrier by a light source deposition method so as to prepare a precious metal / TiO2 catalyst; and then preparing the general light source response efficient modified titanium dioxide solid acid catalyst via sulfuric acid acidification and treatment. According to the invention, the defect that an existing photocatalyst can only be degraded by being irradiated by light sources which are high in price and energy consumption, such as an xenon lamp, is overcome, and the use cost is reduced; under the condition of irradiating by a common light source, the catalyst has an obvious effect of degrading macromolecule organic pollutants; moreover, the modified catalyst is stable in performance, is low in use amount, is high in degradation speed, does not generate secondary pollution, and can be recycled.

Description

technical field [0001] The invention belongs to the field of catalyst preparation, and in particular relates to a universal light source response modified titanium dioxide solid acid catalyst and a preparation method. Background technique [0002] Sustainable development is the subject of common concern of all mankind, and environmental issues are the focus of common concern of mankind. Modern industrialized production methods and human lifestyles have resulted in the discharge of a large number of pollutants that pose a serious threat to the survival of animals and plants into the environment, causing irreversible environmental pollution and directly affecting and destroying the ecosystem. Among them, industrial production wastewater and domestic sewage pollute the environment particularly seriously, which has caused many environmental pollution incidents and brought irreparable losses to the country and society. Photocatalytic degradation of pollutants in water is an eff...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/42B01J23/44B01J23/52C02F1/30C02F1/58C02F1/72
Inventor 牛玉李福颖王仁章陈伟琼翁凤妹张聚文林永斌
Owner SANMING UNIV
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