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Leather adhesive and its preparation method

An adhesive and leather technology, applied in the direction of adhesive types, polyurea/polyurethane adhesives, polymer adhesive additives, etc. The effect of improving the water resistance of the film and enhancing the bonding force

Active Publication Date: 2017-11-28
GUANGDONG FION LEATHER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Water-based polyurethane needs to have a certain water solubility to ensure the stability of its emulsion, and because water-based polyurethane contains water-based groups, it has poor water resistance. It is used for leather bonding, and there is still insufficient bonding strength. When leather When the product encounters a humid environment with a high moisture content, it is prone to cracking at the joint or separation of the adhesive from the leather; moreover, the film formed by the adhesive is not strong enough, and when external forces act, such as scratching, rubbing When kneading, pulling, etc. act on the surface of the film or the upper and lower leather surfaces connected by the film, it is easy to cause the film to be misaligned or separated from the leather because the film is too hard and brittle or the internal bonding of the film is insufficient.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0021] EXAMPLES Raw materials in the following mass percentages: 46 parts of polyurethane prepolymer prepared by reacting isophorone diisocyanate with polyadipate-1,4-butylene glycol ester diol, 14 parts of neopentyl glycol, waste 8 parts of rubber nano-powder, 9 parts of 2,2-dimethylol propionic acid, 46 parts of deionized water, 7 parts of carboxylated styrene-butadiene rubber, the following steps are used to prepare the leather adhesive of the present invention:

[0022] (1) Add polyadipate-1,4-butylene glycol ester diol and isophorone diisocyanate into a three-necked flask according to the ratio of OH:NCO=1:2, blow nitrogen gas, and stir the reactants Evenly, react at 85°C for 2 hours to obtain a polyurethane prepolymer, then add one-half of the amount of neopentyl glycol, and continue to react for 1 hour;

[0023] (2) Cool down the reaction system in step (1) to 60°C, add waste rubber nano-powder and the remaining neopentyl glycol to react for 8 minutes;

[0024] (3) Mix...

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PUM

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Abstract

The invention discloses a leather adhesive, which is prepared from the following raw materials in parts by mass: polyurethane prepolymerized by reacting isophorone diisocyanate and poly-1,4-butylene adipate diol 30~66 parts of body, 10~20 parts of neopentyl glycol, 5~15 parts of waste rubber nano-powder, 3~15 parts of 2,2-dimethylol propionic acid, 20~50 parts of deionized water, carboxylated butylbenzene 5 to 12 parts of glue: the leather adhesive of the present invention has high solid content, strong emulsion adhesion, high bonding strength, and good film-forming properties. The adhesive film formed by the adhesive has scratch resistance, strong toughness, and a preparation method Simple and other features.

Description

technical field [0001] The invention relates to a leather adhesive and a preparation method thereof, belonging to the technical field of chemical material preparation. Background technique [0002] With the development of technology, leather products have achieved diversified production and enriched people's lives. In the process of leather product processing, the bonding process of leather is an important process, and the leather adhesive affects the quality of leather products. [0003] Commonly used leather adhesives are polyurethane adhesives. Polyurethane adhesives refer to adhesives containing carbamate groups (-NHCOO-) or isocyanate groups (-NCO) in the molecular chain. At present, there are two types of polyurethane adhesives: solvent-based and water-based. Water-based polyurethane adhesives have the characteristics of low VOC content, low or no environmental pollution, and non-combustibility. Solvent-based polyurethane adhesives need to use organic solvents in th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J175/06C09J11/08C08G18/75C08G18/66C08G18/42C08G18/32C08G18/34
Inventor 林斌生
Owner GUANGDONG FION LEATHER CO LTD
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