Leather adhesive and its preparation method
An adhesive and leather technology, applied in the direction of adhesive types, polyurea/polyurethane adhesives, polymer adhesive additives, etc. The effect of improving the water resistance of the film and enhancing the bonding force
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[0021] EXAMPLES Raw materials in the following mass percentages: 46 parts of polyurethane prepolymer prepared by reacting isophorone diisocyanate with polyadipate-1,4-butylene glycol ester diol, 14 parts of neopentyl glycol, waste 8 parts of rubber nano-powder, 9 parts of 2,2-dimethylol propionic acid, 46 parts of deionized water, 7 parts of carboxylated styrene-butadiene rubber, the following steps are used to prepare the leather adhesive of the present invention:
[0022] (1) Add polyadipate-1,4-butylene glycol ester diol and isophorone diisocyanate into a three-necked flask according to the ratio of OH:NCO=1:2, blow nitrogen gas, and stir the reactants Evenly, react at 85°C for 2 hours to obtain a polyurethane prepolymer, then add one-half of the amount of neopentyl glycol, and continue to react for 1 hour;
[0023] (2) Cool down the reaction system in step (1) to 60°C, add waste rubber nano-powder and the remaining neopentyl glycol to react for 8 minutes;
[0024] (3) Mix...
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