Light diffusion membrane for display and preparation method thereof
A technology of light diffusion film and diffusion film, which is applied in chemical instruments and methods, optics, luminescent materials, etc., can solve the problems that quantum dots have not been reported, and achieve stable fluorescence of photoluminescence phenomenon, strong shielding of ultraviolet radiation, large The effect of applying value
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Embodiment 1
[0019] Add 0.04 mol of zinc acetate and 0.04 mol of vinyltrimethoxysilane together into the reaction kettle and stir for 1 h for later use. Then add 0.04mol vinyltrimethoxysilane and 1.5mol distilled water into another reaction kettle and stir, adjust the pH to 5.5 with 0.01M dilute hydrochloric acid, react at room temperature for 4 hours, and then adjust the pH of the above reaction solution with 0.01M ammonia water 8.0, continue to react at room temperature for 4 hours, then add the spare mixed solution, and add 0.06mol hexamethylenetetramine to the above reaction solution, raise the temperature to 75°C, continue to stir and react for 4 hours, stand and filter, and use anhydrous Wash with ethanol until neutral, and then bake in an oven at 60°C for 6 hours to obtain micron-sized ZnO-Qds@polysiloxane core-shell light-diffusing microspheres.
[0020] Take the prepared hybrid microsphere 5g, urethane acrylate 45g, triethylene glycol diacrylate 25g, and 0.3g 1-hydroxycyclohexyl p...
Embodiment 2
[0022] Add 0.04 mol of zinc acetate and 0.12 mol of γ-methacryloxypropyltrimethoxysilane into the reaction kettle and stir for 1 hour for later use. Then add 0.04mol γ-methacryloxypropyltrimethoxysilane and 1.5mol distilled water into another reaction kettle and stir, adjust the pH to 5.5 with 0.01M dilute hydrochloric acid, react at room temperature for 4 hours, and then use 0.01 M ammonia water to adjust the pH of the above reaction solution to 8.0, continue the reaction at room temperature for 4 hours, then add the spare mixed solution, and add 0.06mol hexamethylenetetramine to the above reaction solution, raise the temperature to 75 ° C, and continue to stir the reaction for 4 hours, Stand and filter, wash with absolute ethanol until neutral, and then bake in an oven at 60°C for 6 hours to obtain micron-sized ZnO-Qds@polysiloxane core-shell light-diffusing microspheres.
[0023]Take the prepared hybrid microsphere 5g, polyurethane acrylate 45g, triethylene glycol diacrylat...
Embodiment 3
[0025] Add 0.06 mol of zinc acetate and 0.04 mol of vinyl tris(β-methoxyethoxy)silane together into the reaction kettle and stir for 1 h for later use. Then add 0.04mol vinyl tris(β-methoxyethoxy)silane and 1.5mol distilled water into another reaction kettle and stir, adjust the pH to 5.5 with 0.01M dilute hydrochloric acid, react at room temperature for 4h, and then use Adjust the pH of the above reaction solution to 8.0 with 0.01M ammonia water, continue to react at room temperature for 4 hours, then add the spare mixed solution, and add 0.06mol hexamethylenetetramine to the above reaction solution, raise the temperature to 80°C, and continue to stir and react for 4 hours , stand and filter, wash with absolute ethanol until neutral, and then bake in an oven at 60°C for 6 hours to obtain micron-sized ZnO-Qds@polysiloxane core-shell light-diffusing microspheres.
[0026] Take 5g of the prepared hybrid microspheres, 45g of polyacrylate, 25g of triethylene glycol diacrylate and ...
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