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Preparation method of metal/nanocarbon composite

A composite material, nano-carbon technology, applied in the direction of pressure inorganic powder coating, can solve the problems of poor bonding, poor dispersion of nano-carbon and metal matrix, etc., to increase mechanical properties and thermal conductivity, and the method is simple and feasible. good control effect

Inactive Publication Date: 2015-07-29
SUZHOU FIRST ELEMENT NANO TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to solve the problems of poor dispersion and poor bonding between nano-carbon and metal matrix existing in the preparation process of a metal / nano-carbon composite material in the prior art, and to provide a nano-carbon and metal material with strong bonding force. Preparation

Method used

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  • Preparation method of metal/nanocarbon composite
  • Preparation method of metal/nanocarbon composite
  • Preparation method of metal/nanocarbon composite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The aluminum billet is rolled to obtain an aluminum foil with a thickness of 5 μm; adding a dispersant, a stabilizer, and water to the carbon nanotubes, stirring, and sanding to obtain a carbon nanotube slurry with a concentration of 5wt%; on the coating machine, Coating the carbon nanotube slurry onto the aluminum foil while controlling the thickness, such as figure 1 As shown, the composite aluminum foil is obtained by drying at 120°C; the aluminum foil coated with carbon nanotubes is laminated through a lamination machine; the laminated aluminum foil is subjected to repeated three-dimensional hot rolling at 500-660°C, including Two-dimensional semi-solid calendering of the vertically stacked foil surface, then lamination, winding, and hot rolling of the composite foil along the axial direction; finally, an aluminum-based / carbon nanotube composite material with uniform distribution of carbon nanotubes in three dimensions is obtained. Such as figure 2 shown.

[0033...

Embodiment 2

[0036] Roll the copper blank to obtain a copper foil with a thickness of 5 μm; add a dispersant, a stabilizer, and water to the carbon nanotubes, stir, and sand to obtain a carbon nanotube slurry with a concentration of 5wt%; on the coating machine , the carbon nanotube slurry is coated on the copper foil, and dried at 120°C; the copper foil coated with carbon nanotubes is laminated through a lamination machine; the laminated copper foil is protected by argon at 1083°C, The semi-solid repeated hot rolling is carried out, and the copper matrix / carbon nanotube composite material with uniform three-dimensional distribution of carbon nanotubes is finally obtained.

Embodiment 3

[0038] The nickel billet is rolled to obtain a nickel foil with a thickness of 5 μm; adding a dispersant, a stabilizer, and water to the carbon nanotubes, stirring, and sanding to obtain a carbon nanotube slurry with a concentration of 5wt%; on the coating machine , the carbon nanotube slurry is coated on the nickel foil, and dried at 120°C; the nickel foil coated with carbon nanotubes is laminated by a stacker; the stacked nickel foil is protected by argon at 1455°C, The semi-solid repeated hot rolling was carried out, and finally a nickel-based / carbon nanotube composite material with uniform three-dimensional distribution of carbon nanotubes was obtained.

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Abstract

The invention discloses a preparation method of a metal / nanocarbon composite. The method comprises the following steps: calendaring metal raw materials into foils, smearing nanocarbon slurry on the metal foils, drying the foils, folding the foils into slices or winding the foils, and repeatedly carrying out three-dimensional hot rolling, so as to obtain the metal / nanocarbon uniformly mixed composite. The preparation method of metal / nanocarbon composite effectively solves the problem that nanocarbon material cannot be uniformly distributed in metallic matrixes, and has the advantages of simple technology, good controllability and high simplicity in scale production.

Description

technical field [0001] The invention relates to the field of synthesis of metal-based nano-carbon composite materials, in particular to methods for preparing metal / carbon nanotubes, metal / fullerenes, metal / graphene composite materials, and metal / graphene oxide. Background technique [0002] Nano-phase reinforced metal matrix composites are a new type of material that has been developed rapidly in recent years. It has the advantages of low density, corrosion resistance and good processing performance. As a one-dimensional nano-reinforced and toughened material, carbon nanotubes can greatly improve the strength, hardness, thermal stability, corrosion resistance, electrical conductivity, thermal conductivity and friction properties of metals. At present, the methods for preparing metal / nano-carbon composite materials mainly include: hot pressing method, vacuum suction casting method, powder metallurgy sintering method and surface deposition method. However, these methods have ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/06
Inventor 李峰李红董明
Owner SUZHOU FIRST ELEMENT NANO TECH