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Modified VAE emulsion formaldehyde-free adhesive and using method thereof

An aldehyde adhesive and emulsion technology, applied in the directions of adhesive additives, chemical instruments and methods, chemical modification of natural resins, etc., can solve the problems of carcinogenic viscosity and poor waterproof performance, and achieve high bonding strength and high bonding degree. , good viscosity

Inactive Publication Date: 2015-10-07
GUANGXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a modified VAE emulsion formaldehyde-free adhesive that is environmentally friendly, formaldehyde-free, good in viscosity and high in waterproof performance, so as to overcome the carcinogenicity of adhesives releasing formaldehyde and poor viscosity and waterproof performance in the current technology. shortcoming

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Preparation of Rosin Ester Emulsion:

[0024] The preparation of stabilizer solution: take 22g polyvinyl alcohol (PVA), put into 350g distilled water, stir and dissolve evenly, set aside;

[0025] Take g as the unit, weigh the required raw materials of each component: rosin glyceride 200g, dimethyl carbonate (DMC) 150g, emulsifier alkylphenol polyoxyethylene ether 28g, dibutyl phthalate 17.5g, Prepare 375 g of the stabilizer solution obtained above; mix rosin glyceride with dimethyl carbonate (DMC), heat and dissolve to obtain rosin ester liquid, then naturally cool the obtained rosin ester liquid to room temperature, and put it into a reaction kettle with a stirring device In the middle, start stirring, the stirring speed is 100~300r / min, add dibutyl phthalate (DBP), emulsifier alkylphenol polyoxyethylene ether, stir for 10min, adjust the stirring speed to 1800r / min, within 10min Add the stabilizer solution, continue to stir for 25 minutes, discharge, seal, the solid ...

Embodiment 2

[0031] Preparation of Rosin Ester Emulsion:

[0032] Preparation of stabilizer solution: Weigh 22g of polyacrylamide (PAM), put it into 280g of distilled water, stir and dissolve evenly, and set aside;

[0033] Take g as the unit, weigh the required raw materials of each component: hydrogenated rosin glyceride 150g, dimethyl carbonate (DMC) 112.5g, emulsifier alkylphenol polyoxyethylene ether 24g, dibutyl phthalate 15g , 302g of the above-mentioned prepared stabilizer solution, hydrogenated rosin glyceride and dimethyl carbonate (DMC) are mixed, heated and dissolved to obtain the rosin ester liquid, then the gained rosin ester liquid is naturally cooled to room temperature, and put into a In the reaction kettle, start stirring, the stirring speed is 100-300r / min, add dibutyl phthalate (DBP), emulsifier alkylphenol polyoxyethylene ether, stir for 10min, adjust the stirring speed to 1500r / min, Add the stabilizer solution within 10 minutes, continue to stir for 20 minutes, disch...

Embodiment 3

[0039] Preparation of Rosin Ester Emulsion:

[0040] The preparation of stabilizer solution: take 4g polyvinyl alcohol (PVA), put into 55g distilled water, stir and dissolve evenly, set aside;

[0041] Take g as the unit, weigh the required raw materials of each component: rosin glyceride 28g, dimethyl carbonate (DMC) 21g, emulsifier alkylphenol polyoxyethylene ether 5g, dibutyl phthalate 2g, the above Prepare 59 g of the resulting stabilizer solution, mix rosin glyceride with dimethyl carbonate (DMC), heat and dissolve to obtain the rosin ester liquid, then naturally cool the gained rosin ester liquid to room temperature, and put it into a reaction kettle with a stirring device , start stirring, the stirring speed is 100~300r / min, add dibutyl phthalate (DBP), emulsifier alkylphenol polyoxyethylene ether, stir for 10min, adjust the stirring speed to 1600r / min, add in 10min Stabilizer solution, continue to stir for 20 minutes, discharge, seal, the solid content of the prepared r...

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Abstract

The invention discloses modified VAE emulsion formaldehyde-free adhesive. The modified VAE emulsion formaldehyde-free adhesive comprises the following raw material components: VAE emulsion, rosin ester emulsion, isocyanate and light calcium carbonate. Conditions for pressing plywood by using the modified VAE emulsion formaldehyde-free adhesive disclosed by the invention are that the adhesive coating amount for a wood single plate is 260-280g / m<2>, the prepressing pressure is 1.0-1.5MPa, the prepressing time is 10-30min, the hot pressing temperature is 80-125 DEG C, the hot pressing pressure is 0.6-1.0MPa and the hot pressing time is 5-15min. The purpose of the invention is to provide the modified VAE emulsion formaldehyde-free adhesive which is environmental-friendly, formaldehyde-free, good in adhesiveness and high in waterproof performance, so as to overcome the disadvantages that formaldehyde emitted by adhesive in the prior art causes cancers and the adhesiveness and waterproof performance are not good.

Description

technical field [0001] The invention relates to an adhesive and a using method thereof, in particular to a modified VAE emulsion formaldehyde-free adhesive and a using method thereof. Background technique [0002] my country is a big country in the world for wood production and wood products use. With the serious shortage of forest resources, the use of solid wood boards to make furniture and decorate houses not only has limited resources but also high cost, so the boards usually used are plywood. Plywood is made by turning (planing) logs of certain specifications into veneers, and then drying, gluing, billeting, and hot pressing. Considering the production cost of plywood, most of the adhesives for wood-based panels in China currently use trialdehyde resin glue (urea-formaldehyde resin, phenolic resin, melamine-formaldehyde resin) produced with formaldehyde as the main raw material. In 2012, the total amount of "trialdehyde glue" was 13.127 million tons, accounting for 94....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J131/04C09J193/04C09J11/04C09F1/04B27D1/08B32B37/12B32B37/06B32B37/10B32B7/12
Inventor 韦小杰陈小鹏张洋王琳琳梁杰珍
Owner GUANGXI UNIV