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Preparation method of thermal conducting and insulating material of LED substrate

A technology of thermally conductive insulating material and LED substrate, applied in the field of material chemistry, can solve the problems of poor physical properties and thermal conductivity of thermally conductive resin materials, poor bending and kink resistance, and poor compression and shock resistance. The branch copolymerization reaction is sufficient, the rate is fast, and the effect of increasing stiffness

Inactive Publication Date: 2015-11-11
朱海燕
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Commonly used thermally conductive fillers include alumina, magnesia, silicon oxide, aluminum nitride, boron nitride, silicon carbide, etc. These thermally conductive fillers are filled in the resin material to make the resin material have high thermal conductivity, and the higher the proportion of thermally conductive filler in the resin The larger the resin, the better the thermal conductivity of the resin. In the past, micron-sized thermal conductive fillers were added to the resin and placed in an extruder to extrude and granulate. Due to the addition of inorganic substances in the resin, the mechanical strength of the resin was reduced, and it was resistant to bending and twisting. The performance is poor, and the anti-compression and anti-shock ability becomes poor, so people began to study adding nano-scale inorganic fillers to organic resin materials, but it is difficult to make nano-scale inorganic fillers into organic resin materials. The fillers are well dispersed, and the nano-scale inorganic fillers are easy to agglomerate together, resulting in poor physical properties and thermal conductivity of thermally conductive resin materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] This embodiment provides a thermally conductive insulating material for a high-power LED substrate, and the thermally conductive insulating material for a high-power LED substrate is prepared through the following steps:

[0033] (1) In parts by mass, add 30 parts of silicon oxide powder with an average particle size of 10nm to 3 parts of graft modifier maleic anhydride, then add 0.1 part of dispersant to polyacrylamide, and stir for 10 to 15 minutes. Then use ultrasonic dispersion for 20-30 minutes to disperse the nano-silica powder in the mixed solvent of maleic anhydride and polyacrylamide to form an emulsion-like dispersion;

[0034] (2) the emulsion-like dispersion prepared in the above-mentioned steps (1) is added to ultrasonic spray drying equipment and spray-dried to prepare a powdery composite material comprising nano-silicon oxide;

[0035] (3) Add the powdery composite material prepared in the above step (2) together with 7 parts of polypropylene resin powder...

Embodiment 2

[0042] This embodiment also provides a thermally conductive insulating material for a high-power LED substrate. The thermally conductive insulating material for a high-power LED substrate is prepared through the following steps:

[0043] (1) Add 80 parts of alumina powder with an average particle size of 30nm in 20 parts of graft modifier oleic acid, then add 10 parts of dispersant as sodium lauryl sulfate, and stir for 10~ 15 minutes, and then use ultrasonic dispersion for 20-30 minutes to disperse the nano-alumina powder in a mixed solvent of oleic acid and sodium lauryl sulfate to form an emulsion-like dispersion;

[0044] (2) the emulsion-like dispersion prepared in the above-mentioned steps (1) is added to ultrasonic spray drying equipment and spray-dried to prepare a powdery composite material comprising nano-silicon oxide;

[0045] (3) The powdered composite material prepared in the above-mentioned step (2) and 40 parts of polyethylene resin powder are added to the twin...

Embodiment 3

[0052] This embodiment also provides a thermally conductive insulating material for a high-power LED substrate. The thermally conductive insulating material for a high-power LED substrate is prepared through the following steps:

[0053] (1) In parts by mass, add 30 parts of magnesium oxide powder with an average particle size of 50nm to 20 parts of graft modifier acrylic acid, then add 10 parts of dispersant as fatty acid polyethylene glycol ester, and stir for 10 to 15 minutes , and then use ultrasonic dispersion for 20 to 30 minutes to disperse the nano magnesium oxide powder in a mixed solvent of acrylic acid and fatty acid polyethylene glycol ester to form an emulsion-like dispersion;

[0054] (2) join the emulsion-like dispersion made in above-mentioned steps (1) to ultrasonic spray drying equipment and carry out spray-drying and prepare powdery composite material comprising nano magnesium oxide;

[0055] (3) The powdered composite material prepared in the above step (2) i...

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PUM

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Abstract

The invention relates to a preparation method of a thermal conducting and insulating material of an LED substrate. The thermal conducting and insulating material comprises, by mass, 30-80% of nanoscale inorganic thermal conducting powder with thermal conductivity coefficient larger than 10 W / mk, 10-60% of graft copolymer of grafting modifier and polyolefin resin and 0.25-10% of dispersing agents. The nanoscale inorganic thermal conducting powder is grafted on the grafting modifier, and the grafting modifier is grafted on branch chains of the polyolefin resin; maleic anhydride serves as the grafting modifier; one or more of organic dispersants or silane coupling agents such as 3-ethylhexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derivatives, polyacrylamide, gul glue and fatty acid polyglycol ester serves / serve as the dispersing agents. By adding the nanoscale inorganic thermal conducting powder to resin material, the resin material has good thermal conductivity, and the rigidity of the resin material is increased.

Description

technical field [0001] The invention belongs to the technical field of material chemistry, and relates to a thermally conductive insulating material for a high-power LED substrate and a preparation method thereof. Background technique [0002] For low-power LED packaging, ordinary PCB boards can meet the demand, but for high-power LEDs, only 20% of the input energy is converted into light, and the rest is consumed in the form of heat. If the outside world is excluded, the life of the LED will be greatly reduced. The heat dissipation capability of LEDs is usually affected by the packaging mode and the thermal conductivity of the materials used. [0003] The traditional cannonball-type package is used in a plug-in type. It is widely used in the indicator lights of home appliances or communication products. The colors that are often seen are red, yellow, and green. However, because most of the heat generated by LEDs can only pass through two The wire conducts heat to the asse...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/06C08L33/26C08L71/08C08K3/34C08K3/22C08K5/41C08K5/54C08F255/02C08F255/10C08F255/08C08F220/06C08F220/64C08F222/06
Inventor 不公告发明人
Owner 朱海燕