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Preparation method of porous structure metal/rare earth co-doped inorganic nanofiber photocatalytic material

A nanofiber, metal-doped technology, applied in chemical instruments and methods, physical/chemical process catalysts, organic compound/hydride/coordination complex catalysts, etc. Easy to decompose, increase load capacity, and ensure the effect of stability

Inactive Publication Date: 2015-12-02
TIANJIN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The sol-gel method is the synthesis of nano TiO 2 One of the common methods, generally using metal alkoxide as a precursor, gradually gelling through hydrolysis and polycondensation, and then aging and drying to obtain nano-TiO 2 , but there is a complex process, TiO 2 Disadvantages such as excessive surface hydroxyl groups

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0017] Add 10ml of absolute ethanol and 15ml of n-butyl titanate into a flat-bottomed flask and stir on a magnetic stirrer, then add 5ml of acetylacetone dropwise using a pipette, stir at room temperature for 10 minutes, and prepare solution A. Add 5ml of distilled water and 5ml of absolute ethanol into a 50ml beaker, then add 0.0234g of Fe(NO 3 ) 3 9H 2 O and 0.0186 g La(NO 3 ) 3 ·6H 2 O dubbed as Fe 3+ : La 3+ Solution B with a molar ratio of 1:1; an ion concentration of 0.02%. Put solution B in a constant pressure dropping funnel and drop it into solution A drop by drop, stir at high speed for 6h to obtain Fe 3+ , La 3+ Co-doped TiO2 alcohol sol. Dissolve PVAc in acetone to form a solution with a concentration of 15%. Put 40ml of the prepared alcohol sol into a constant pressure dropping funnel and drop it into 40ml of PVAc solution drop by drop, stir for 10 hours to make PVAc / TiO 2 Hybrid sol spinning solution. Put the spinning solution into self-made electrospi...

example 2

[0019] Add 10ml of absolute ethanol and 15ml of n-butyl titanate into a flat-bottomed flask and stir on a magnetic stirrer, then add 5ml of acetylacetone dropwise using a pipette, stir at room temperature for 10 minutes, and prepare solution A. Add 5ml of distilled water and 5ml of absolute ethanol into a 50ml beaker, then add 0.2921g of Fe(NO 3 ) 3 9H 2 O and 0.0466 g La(NO 3 ) 3 ·6H 2 O dubbed as Fe 3+ Ion concentration is 0.5%, La 3+ Solution B with an ion concentration of 0.1%. Place solution B in a constant pressure dropping funnel and drop it into solution A drop by drop, stir at high speed for 8 hours to obtain Fe 3+ , La 3+ co-doped TiO 2 Alcohol sol. Dissolve PVAc in acetone to make a solution with a concentration of 15%. Put 40ml of the prepared alcohol sol into a constant pressure dropping funnel and drop it into 40ml of PVAc solution drop by drop, stir fully for 8h to make PVAc / TiO 2Hybrid sol spinning solution. Put the spinning solution into self-made ...

example 3

[0021] Add 10ml of absolute ethanol and 15ml of n-butyl titanate into a flat-bottomed flask and stir on a magnetic stirrer, then add 5ml of acetylacetone dropwise using a pipette, stir at room temperature for 10 minutes, and prepare solution A. Add 5ml of distilled water and 5ml of absolute ethanol into a 50ml beaker, then add 0.05843g of Fe(NO 3 ) 3 9H 2 O and 0.2331 g La(NO 3 ) 3 ·6H 2 O dubbed as Fe 3+ Ion concentration is 0.1%, La 3+ Solution B with an ion concentration of 0.5%. Place solution B in a constant pressure dropping funnel and drop it into solution A drop by drop, stir at high speed for 5 hours to obtain Fe 3+ , La 3+ co-doped TiO 2 Alcohol sol. Dissolve PVAc in acetone to make a solution with a concentration of 17%. Put 40ml of the prepared alcohol sol into a constant pressure dropping funnel and drop it into 40ml of PVAc solution drop by drop, stir fully for 8h to make PVAc / TiO 2 Hybrid sol spinning solution. Put the spinning liquid into self-made ...

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Abstract

The invention relates to the technical fields of preparation of a high-content titanium dioxide sol disperse system by utilizing a sol-gel method, preparation of a polyvinyl acetate / titanium dioxide nanofiber membrane by using an electrostatic spinning device, ultimate preparation of inorganic nanofiber by an autoclaved sintering process and the like, and particularly relates to a preparation method of a metal co-doped TiO2 inorganic nanofiber photocatalytic material. According to the preparation method provided by the invention, a stable TiO2 sol system co-doped with metal ions is prepared by means of a sol-gel principle, and mixed and hybridized with a PVAc solution, inorganic / polymer hybrid nanofiber is prepared by utilizing an electrostatic spinning technology, and organic components are ultimately removed by sintering to obtain the porous inorganic nanofiber. The preparation method provided by the invention solves the problems of little dispersion quantity of the TiO2 sol system, instability in hydrolysis, incompatibility with the metal ions and the like, and achieves the preparation of the metal co-doped inorganic TiO2 nanofiber with the porous structure. The porous metal doped TiO2 nanofiber membrane prepared by the invention is high in adhesion with a glass substrate, high in photocatalytic performance, small in fiber diameter and uniform in distribution, and can be widely applied to various fields such as self-cleaning materials, photocatalytic materials and dye-sensitized solar cells.

Description

technical field [0001] The invention relates to a method for preparing a metal / rare earth co-doped inorganic nanofiber membrane with a porous structure, in particular to preparing a titanium dioxide sol by using a sol-gel technology, and then preparing a polyvinyl acetate (PVAc) / titanium dioxide (TiO 2 ) hybrid sol, and finally the metal-doped polyvinyl acetate (PVAc) / titanium dioxide (TiO 2 ) nanofibrous membrane, and sintering to obtain a porous structure of metal-doped inorganic titania nanofibers. Background technique [0002] Nanofibers refer to fibers with diameters in the nanometer scale (1-100nm), which belong to one-dimensional nanomaterials. When the diameter is reduced from micron to submicron or nanometer, the fiber exhibits a series of special properties compared with the corresponding material, such as a very large specific surface area (the specific surface area is 10 times that of micron fibers. 3 Times), flexibility and super mechanical behavior (such as h...

Claims

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Application Information

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IPC IPC(8): B01J31/06B01J31/38D04H1/728B82Y30/00B82Y40/00
Inventor 吴宁胡晓敏张一帆张雅璐
Owner TIANJIN POLYTECHNIC UNIV