Novel metal oxide iron-copper composite modified quartz sand filter material, and preparation method and application thereof

A composite modification, quartz sand technology, applied in chemical instruments and methods, silicon compounds, separation methods, etc., to achieve the effect of improving efficiency, reducing energy consumption, and achieving the best removal effect

Inactive Publication Date: 2016-01-13
GUANGDONG UNIV OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The technical problem to be solved by the present invention is to overcome the defects and technical deficiencies of the existing composite modified fi

Method used

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  • Novel metal oxide iron-copper composite modified quartz sand filter material, and preparation method and application thereof
  • Novel metal oxide iron-copper composite modified quartz sand filter material, and preparation method and application thereof
  • Novel metal oxide iron-copper composite modified quartz sand filter material, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
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Example Embodiment

[0052] Example 1 Preparation of metal oxide iron copper composite modified quartz sand filter material

[0053] 1. Materials required for the preparation of metal oxide composite modified sand

[0054] (1) The required materials are shown in Table 1.

[0055] Table 1

[0056]

[0057] (2) Handling of test materials

[0058] Ordinary quartz sand (RQS): sieve the diameter of 0.9~1.43mm, immerse in HCl solution of pH=1 for 24h, then wash with distilled water to neutrality, then dry in 110℃ oven, cool at room temperature and put into polyethylene bottle In standby.

[0059] Iron trichloride modifier (FeCl 3 ): Accurately weigh 270.5g of ferric chloride hexahydrate (analytical purity) and dissolve it in distilled water, transfer to a 500mL volumetric flask, dilute the distilled water to 500mL, shake well, the concentration of the solution of ferric chloride is 2.000mol / L . The amount of ferric chloride added per gram of quartz sand is called the ferric chloride dosing ratio C 1 , Unit mL·g...

Example Embodiment

[0079] Example 2 BET specific surface area and morphology of metal oxide iron copper composite modified quartz sand filter material

[0080] 1. The size of the specific surface area reflects the size of the particle load capacity, and the size of the specific surface area passes through S BET Value to measure. Use the BET specific surface area tester F-Sorb2400 to measure the specific surface area of ​​ordinary quartz sand and metal composite oxide modified sand, and calculate the ratio of the specific surface area of ​​the modified sand to the specific surface area of ​​ordinary quartz sand. The effect of sex. From Table 6, the specific surface area of ​​metal oxide composite modified sand is 8.96 times that of ordinary quartz sand.

[0081] Table 6 BET specific surface area measurement results of filter sand

[0082]

[0083] 2. The physical picture of metal oxide composite modified sand figure 2 The metal oxide composite modified sand has a particle size range of 0.9mm to 1.4...

Example Embodiment

[0084] The SEM image of the metal oxide composite modified sand image 3 , Combining Table 6 and image 3 (a) The surface of ordinary quartz sand is flat, the specific surface area is small, and the adsorption capacity is small. image 3 (b) and (c) are SEM images of composite modified quartz sand surface magnified 5000 and 10000 times. It can be seen that the surface of metal oxide composite modified sand has very clear and dense pores with a specific surface area of ​​0.959, which is ordinary quartz 8.96 times that of sand, it has a larger adsorption capacity than ordinary quartz sand. The substance attached to the surface of the modified quartz sand is Fe 2 O 3 And CuO, making metal oxides successfully modified on the surface of ordinary quartz sand, Fe 3+ And Cu 2+ The positive charge on the surface of ordinary quartz sand is increased, which has a very good adsorption effect on negatively chargeable organic pollutants in water. Example 3 Removal of humic acid by static adso...

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Abstract

The invention discloses a novel metal oxide iron-copper composite modified quartz sand filter material, and a preparation method and application thereof. Concretely, the metal oxide iron-copper composite modified quartz sand filter material is prepared by modifying quartz sand with ferric trichloride and copper sulfate as modifying agents by adopting a microwave technology at the same time. The metal oxide iron-copper composite modified quartz sand filter material prepared by using the method in the invention can effectively adsorb organic and inorganic pollutants, heavy metals, phosphorus, etc. in water; the material has a specific surface area which is 8.96 times of the specific surface area of ordinary quartz sand, and has larger adsorption capacity than the ordinary quartz sand; a removal rate of the material to humic acid is 96.58% and is increased by 67.86% than the removal rate of the ordinary quartz sand to the humic acid; and the removal rate of the material to the phosphorus in water is 71.5% to 96.23%. Moreover, the modified quartz sand filter material has higher adhesion strength to pollutants and is reduced in desorption rate to surface metals; meanwhile, the material has low production cost and investment cost and is convenient for industrial production.

Description

technical field [0001] The invention belongs to the technical field of modified filter material. More specifically, it relates to a novel metal oxide iron-copper composite modified quartz sand filter material and its preparation method and application. Background technique [0002] The modified filter material is mainly to attach an active modifier to the surface of the quartz sand through a chemical reaction, thereby changing the properties of the original filter material surface, and making a modified filter material with excellent adsorption performance and pollution interception ability, so as to improve the removal of the filter material. The purpose of organic pollutants and heavy metal substances in water. [0003] At present, the modification technology at home and abroad mainly uses iron salts and aluminum salts as modifiers, and changes the surface potential of the filter particles and the internal structure of the metal medium by alkaline deposition, high-tempera...

Claims

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Application Information

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IPC IPC(8): B01D39/06B01J20/10B01J20/30C02F1/28
Inventor 李冬梅杨翾王逸之李国浩任毅刘贝梅胜
Owner GUANGDONG UNIV OF TECH
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