Lithium-ion power battery material

A power battery and lithium-ion technology, applied in battery electrodes, secondary batteries, circuits, etc., to achieve excellent cycle discharge performance, excellent thermal stability and safety, and high safety effects

Inactive Publication Date: 2016-01-20
WUHU KAIER ELECTRICAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0001] At present, most commercial lithium-ion battery anode materials are lithium-intercalated carbon materials. Since the potential of the carbon electrode after lithium intercalation is very close to that of metal lithium, when the battery is overcharged, metal lithium is easily precipitated on the surface of the carbon electrode, and it interacts with the electrolyte. The reaction produces a flammable gas mixture, which poses a great safety hazard to batteries, especially power batteries
At the same time, graphite electrodes also have the problem of co-intercalation of the electrolyte, which will also affect the cycle stability of the electrode.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The mass ratio of the lithium iron phosphate and lithium vanadium phosphate composite material, the conductive agent, and the binder is 90:5:5. The Li 4 Ti 5 o 12 (spinel lithium titanate), conductive agent, thickener, and binder in a mass ratio of 92:3:2:3. The conductive agent is acetylene black. The binder is vinylidene fluoride. The thickener is carboxymethyl cellulose; the binder is water-based styrene-butadiene rubber.

Embodiment 2

[0020] The mass ratio of the lithium iron phosphate and lithium vanadium phosphate composite material, the conductive agent, and the binder is 93:3:4. The Li 4 Ti 5 o 12 (spinel lithium titanate), conductive agent, thickener, and binder in a mass ratio of 93:2:3:3. The conductive agent is conductive carbon black. The binder is polytetrafluoroethylene. The thickener is carboxymethyl cellulose; the binder is water-based styrene-butadiene rubber.

Embodiment 3

[0022] The mass ratio of the lithium iron phosphate and lithium vanadium phosphate composite material, the conductive agent, and the binder is 95:3:2. The Li 4 Ti 5 o 12 (spinel lithium titanate), conductive agent, thickener, and binder in a mass ratio of 95:1:2:2. The conductive agent is SuperP. The binder is vinylidene fluoride. The thickener is carboxymethyl cellulose; the binder is water-based styrene-butadiene rubber.

[0023] The battery materials of the above three embodiments have high-current charge-discharge performance, extremely high safety, and excellent cycle discharge performance, and are suitable for the field of electric vehicles.

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PUM

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Abstract

The invention aims at providing a lithium-ion power battery material. Spinel lithium titanate is adopted as a negative electrode; and the lithium-ion power battery material is high in discharge speed, good in overcharge resistance, excellent in heat stability and excellent in safety. A positive electrode of the lithium-ion power battery material comprises a main material, namely a lithium iron phosphate and lithium vanadium phosphate composite material; a positive electrode material and a negative electrode material can be used cooperatively; and the lithium-ion power battery material has the advantages of high current charge-discharge capability, extremely high safety and excellent circulating discharge performance, and is suitable for the field of electric automobiles.

Description

Background technique [0001] At present, most commercial lithium-ion battery anode materials are lithium-intercalated carbon materials. Since the potential of the carbon electrode after lithium intercalation is very close to that of metal lithium, when the battery is overcharged, metal lithium is easily precipitated on the surface of the carbon electrode, and it interacts with the electrolyte. The reaction produces a flammable gas mixture, thus causing a great safety hazard to the battery, especially the power battery. At the same time, the graphite electrode also has the problem of co-intercalation of the electrolyte, which will also affect the cycle stability of the electrode. Therefore, it is necessary to find new anode materials that can intercalate lithium at a slightly positive potential than carbon anodes, are cheap, easy to obtain, safe and reliable. Among them, low-potential transition metal oxides and composite oxides have attracted widespread attention as negative e...

Claims

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Application Information

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IPC IPC(8): H01M4/485H01M4/58H01M4/62H01M10/0525
CPCH01M4/362H01M4/485H01M4/5825H01M4/623H01M4/625H01M10/0525Y02E60/10
Inventor 汪桂云汪劲松王鸣
Owner WUHU KAIER ELECTRICAL TECH
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