Manufacturing method of electromagnetic wave shielding composite material using copper and nickel plated carbon fiber produced by continuous process of electrolysis and electrolysis, and electromagnetic wave shielding composite material
A technology of composite materials and electromagnetic waves, applied in the fields of magnetic/electric field shielding, circuits, applications, etc., can solve problems such as harsh plating methods, high productivity, high production prices, and difficulty in practical application
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Embodiment 1
[0143] Example 1: Preparation and Evaluation of Electromagnetic Wave Shielding Sheet by Injection Molding
[0144] The content of each of the above components shown in Table 1 below was molded. The injection molded articles were each prepared in the form of a sheet having a thickness of 0.7 mm. Specifically, thermoplastic resin polypropylene (grade BJ 700 of Samsung Total Company, melt index of 25, density of 0.91 g / cm 3 , heat distortion temperature is 105 ℃,), polycarbonate (grade LUPOY of LG Chemical, polycarbonate 1201-22, melt index is 22, density is 1.2g / cm 3 , heat distortion temperature of 147°C) and acrylonitrile-butadiene-styrene resin (grade ABS XR401 from LG Chem, with a melt index of 9 and a density of 1.05g / cm 3 , heat distortion temperature of 105 ℃) drying for 6 hours. Afterwards, the contents of Table 1 below were mixed with the dried thermoplastic resin. Next, the above mixture was put into an injection molding machine (twin injection machine, produced by...
Embodiment 2
[0149] Example 2: Preparation and Evaluation of Molded Articles Through Injection Molding Process and Extrusion Process
[0150] According to the ingredients in Table 2 and Table 3 below, moldings were prepared through the injection molding process and the extrusion process, respectively, and the electromagnetic wave shielding performance test was carried out. In a vacuum oven at a temperature of 80°C, polypropylene (grade BJ 700, with a melt index of 25 and a density of 0.91g / cm 3 , heat distortion temperature of 105°C, Samsung Total) dried for 6 hours, and the dried polypropylene was mixed with polypropylene and carbon fiber (6mm) plated with copper and nickel in the following Table 2, respectively, to prepare The injection molded products of the following Table 2 are listed. And, the above mixture was injection-molded into an injection molded product having a size specified by ASTM D4935 under the same conditions as in Example 1 to prepare a sheet.
[0151] Table 2
[01...
Embodiment 3
[0158] Example 3: Preparation and evaluation of molded articles using thermosetting resins
[0159] In Table 4, highly conductive carbon fibers coated with Cu and Ni were impregnated with polyurethane resin and epoxy resin as representative resins of thermosetting resins to prepare sheets, and the electromagnetic wave shielding performance was measured.
[0160] Quantitative polyurethane PU (grade UP395, viscosity of 1500cps, specific gravity of 1, one-component urethane, Korea, Kokudo Chemical) and carbon fiber (6mm short) plated with copper and nickel in a beaker with a weight ratio of 80:20 After cutting), in a mixer, mixed at 1000rpm speed for 1 minute to prepare a mixed solution. Put 20g of the prepared mixed solution on the release treatment (spray an appropriate amount of WD-40 from 3M Company on a glass plate with a thickness of 5mm, rub it evenly with the cloth of the surface material, and then place it in an oven at a temperature of 70°C. Keep it in the medium for 3...
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