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A drug-loaded hydrogel coating and its preparation method and application

A kind of alumina hydrogel, gel technology, applied in coating, medical science, medical container and other directions, can solve problems such as vascular restenosis, achieve long-lasting anti-thrombotic effect and prevent protein deposition.

Active Publication Date: 2018-06-15
WUXI ZHONGKE GUANGYUAN BIOMATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the drug coating can effectively alleviate the formation of thrombus, it does not fundamentally solve the problem. Since the drug carrier is a degradable material, when it is degraded, the drug will be completely released, so the antithrombotic effect disappears. delayed restenosis

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] In this embodiment, the drug-loaded hydrogel coating is prepared by the following method, which specifically includes the following steps:

[0043] (1) Add 2.5g of aluminum isopropoxide into 50mL of deionized water, stir the white precipitate at 80°C for 15min to obtain a dispersion, ultrasonically treat the dispersion for 2h, and cool to room temperature to obtain an alumina hydrogel (Al 2 o 3 ·H 2 O), wherein the mass content of aluminum is 2%.

[0044] (2) Dissolve 10 mg of the antithrombotic drug enoxaparin sodium in 1 mL of Tris-hydrochloric acid buffer (concentration 0.05M) at pH=7.4 to obtain an antithrombotic drug solution, and mix 100 μL of the alumina hydrogel obtained in step (1) with 50 μL of antithrombotic drug solution was mixed evenly in a 1.5mL glass tube, and then 50 μL of the mixed solution was taken on a glass slide (2cm×2cm in size) with a pipette gun, and the Meyer rod was used to repeatedly press and coat 5 times to coat evenly, and then put Dry...

Embodiment 2

[0046] In this embodiment, the drug-loaded hydrogel coating is prepared by the following method, which specifically includes the following steps:

[0047] (1) Add 2.5g of aluminum isopropoxide into 25mL of deionized water, stir the white precipitate at 80°C for 30min to obtain a dispersion, ultrasonically treat the dispersion for 1h, and cool to room temperature to obtain an alumina hydrogel (Al 2 o 3 ·H 2 O), wherein the mass content of aluminum is 3%.

[0048] (2) 10 mg of antithrombotic drug ticlopidine was dissolved in 2 mL of Tris-hydrochloric acid buffer (concentration 0.05 M) at pH=7.4 to obtain an antithrombotic drug solution, and 100 μL of the alumina hydrogel obtained in step (1) was mixed with 80 μL of antithrombotic drug solution was mixed evenly in a 1.5mL glass tube, and then 50 μL of the mixed solution was taken on a glass slide (2cm×2cm in size) with a pipette gun, and the Meyer rod was used to repeatedly press-coat 7 times to coat evenly, and then put Dry i...

Embodiment 3

[0050] In this embodiment, the drug-loaded hydrogel coating is prepared by the following method, which specifically includes the following steps:

[0051] (1) Add 2.5g of aluminum isopropoxide into 75mL of deionized water, stir the white precipitate at 80°C for 20min to obtain a dispersion, ultrasonicate the dispersion for 3h, cool to room temperature, and obtain an alumina hydrogel (Al 2 o 3 ·H 2 O), wherein the mass content of aluminum is 1%.

[0052] (2) Dissolve 10 mg of the antithrombotic drug urokinase in 3 mL of Tris-hydrochloric acid buffer (concentration 0.05 M) at pH=7.4 to obtain an antithrombotic drug solution, mix 100 μL of the alumina hydrogel obtained in step (1) with 30 μL of antithrombotic Mix the thrombus drug solution evenly in a 1.5mL glass tube, then use a pipette gun to take 50μL of the mixed solution on a glass slide (2cm×2cm in size), use a Meyer rod to repeatedly press and coat 3 times to coat evenly, and then put it in a vacuum Dry in a drying oven...

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Abstract

The invention provides a drug-loaded hydrogel coating, and a preparation method and application thereof. According to the invention, alumina hydrogel is utilized as a coating substrate to load an antithrombotic drug, so the nanometer drug-loaded hydrogel coating is obtained; since the alumina hydrogel has the characteristics that the alumina hydrogel does not degrade and is slowly absorbed by the human body, the drug is allowed to stay in the coating all the time and protein deposition is prevented; when the coating is applied onto the inner wall of an intravascular stent, the drug can stay in the inner wall of the intravascular stent all the time and exerts long-lasting antithrombotic effect, formation of thrombus at a position where the stent is placed or where a blood vessel is replaced can be prevented, so the disadvantages of conventional drug-loaded stents can be overcome fundamentally. Tardive vascular restenosis, or even re-obstruction, caused by degradation of a matrix is not incurred.

Description

technical field [0001] The invention belongs to the field of hydrogel preparation, and relates to a drug-loaded hydrogel coating and a preparation method and application thereof. Background technique [0002] Cardiovascular and cerebrovascular diseases generally refer to ischemic or hemorrhagic diseases in the heart, brain, and systemic tissues caused by hyperlipidemia, blood viscosity, atherosclerosis, and high blood pressure. The number of people who die of cardiovascular and cerebrovascular diseases in the world is as high as 15 million every year, ranking first among various causes of death. Balloon angioplasty and coronary artery stents are currently the most commonly used treatment methods, but there are still as many as 30% of cases after implantation Restenosis and thrombosis can occur. Even if the most effective drug-eluting stent is used so far, its effect is only to delay the occurrence of thrombus and restenosis, and does not fundamentally solve the problem. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A61L31/08A61L31/14A61L31/16A61L33/00
CPCA61L31/082A61L31/145A61L31/16A61L33/0011A61L33/0047A61L2300/42A61L2420/02
Inventor 韩志超许杉杉
Owner WUXI ZHONGKE GUANGYUAN BIOMATERIALS