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Method for preparing organic carbon fertilizer from agricultural wastes as raw materials

A technology of agricultural waste and organic carbon, applied in the direction of organic fertilizers, etc., can solve the problems of difficult crop absorption and utilization, high equipment requirements, high energy consumption, etc., and achieve the effect of improving crop quality, low requirements, and low energy consumption

Inactive Publication Date: 2016-03-02
SHENZHEN BATIAN ECOTYPIC ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the above aspects can recycle straw, the obtained fertilizer is a macromolecular organic matter, which is difficult to be absorbed and utilized by crops. Moreover, high temperature and high pressure require high equipment, high energy consumption, and long biological fermentation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Corn stalks from Shangqiu area of ​​Henan Province were selected, which contained 38.5% cellulose, 26.8% hemicellulose, 13.6% lignin, 5.3% ash and 15.8% others.

[0028] Use nitric acid from Shenzhen Dingqing Chemical Co., Ltd. 90% nitric acid is configured into a 20% nitric acid solution.

[0029] First crush the corn stalks into small stalks with a length of 2 to 5 cm with a pulverizer, place them in a reaction kettle with a capacity of 500 L, add 350 L of water, and add 175 kg of crushed stalks under stirring conditions. After stirring and dispersing, 35kg of nitric acid with a mass fraction of 4% was added to carry out the digestion reaction. After heating the reaction temperature to 150°C, react for 10 minutes. Putting the reaction solution into a storage tank to cool down, settling, taking the supernatant after separation, evaporating and concentrating until the content of the organic carbon small molecule organic compound is 15%, and then obtaining the organic ...

Embodiment 2

[0031] Corn stalks from Shangqiu area of ​​Henan Province were selected, which contained 38.5% cellulose, 26.8% hemicellulose, 13.6% lignin, 5.3% ash and 15.8% others.

[0032] Use nitric acid and hydrogen peroxide from Shenzhen Dingqing Chemical Co., Ltd.

[0033] First crush the corn stalks into small stalks with a length of 2 to 5 cm with a pulverizer, place them in a reaction kettle with a capacity of 500 L, add 350 L of water, and add 175 kg of crushed stalks under stirring conditions. After stirring and dispersing, add 30kg of nitric acid with a mass fraction of 3% and 5kg of hydrogen peroxide with a mass fraction of 1% for digestion. After heating the reaction temperature to 180°C, react for 5 minutes. Putting the reaction solution into a storage tank to cool down, settling, taking the supernatant after separation, evaporating and concentrating until the content of organic carbon small molecule organic compounds is 5%, and then obtaining an organic carbon fertilizer co...

Embodiment 3

[0035] Corn stalks from Shangqiu area of ​​Henan Province were selected, which contained 38.5% cellulose, 26.8% hemicellulose, 13.6% lignin, 5.3% ash and 15.8% others.

[0036] Use nitric acid and perchloric acid from Shenzhen Dingqing Chemical Co., Ltd.

[0037] First crush the corn stalks into small stalks with a length of 2 to 5 cm with a pulverizer, place them in a reaction kettle with a capacity of 500 L, add 350 L of water, and add 175 kg of crushed stalks under stirring conditions. After stirring and dispersing, add 20kg of nitric acid with a mass fraction of 6% and 15kg of perchloric acid with a mass fraction of 3% for digestion. After heating the reaction temperature to 80°C, react for 30 minutes. Putting the reaction solution into a storage tank to cool down, settling, taking the supernatant after separation, evaporating and concentrating until the organic carbon small molecular organic compound content is 25%, and then obtaining the organic carbon fertilizer contai...

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Abstract

The invention discloses a method for preparing organic carbon fertilizer from agricultural wastes as raw materials. The method comprises, 1, raw material pretreatment: crushing agricultural wastes, adding water into the agricultural wastes and carrying out blending, 2, acid addition and digestion reaction, and 3, centrifugal separation or settling separation and supernatant collection. The agricultural wastes comprise straws. The straws comprise corn stalks, wheat straws, paddy rice straws, sugar cane stalks, cotton stalks or the rest part of crops treated by seed collection. The acid comprises more or more of sulfuric acid, nitric acid, perchloric acid, hypochlorous acid and hydrogen peroxide. The digestion reaction temperature is in a range of 80-180 DEG C and digestion reaction time is in a range of 1-30min. A mass ratio of the agricultural wastes to the acid is 100: (1-9). The method has simple and fast processes and small energy consumption. The obtained organic carbon fertilizer comprises micromolecule organic carbon and can be absorbed easily by crops.

Description

technical field [0001] The invention relates to the technical field of fertilizers, in particular to a method for preparing organic carbon fertilizers from agricultural wastes. Background technique [0002] Agriculture is one of the pillars of national economic development, and chemical fertilizers are the material basis for sustainable agricultural development and the guarantee for increasing grain production. With the gradual expansion of construction land and the relative shortage of arable land, improving soil fertility through fertilization is an important guarantee for sustainable land use and agricultural development. It has been reported in the literature that the utilization rate of nitrogen fertilizer in my country is only 20-50%, that of phosphorus fertilizer is 15-25%, and that of potassium fertilizer is 30-35%. The low utilization rate of fertilizers leads to huge waste of resources, and also reduces the quality of soil, and pollutes surface water, groundwater ...

Claims

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Application Information

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IPC IPC(8): C05F11/00
Inventor 裴福云
Owner SHENZHEN BATIAN ECOTYPIC ENG