Polarizing plate protection film, polarizing plate and liquid crystal display device
A technology of protective film and polarizer, which is applied in the direction of polarizing elements, instruments, optics, etc., can solve the problem of uneven display of liquid crystal display devices, and achieve the effect of suppressing the deterioration of polarizers and small dimensional changes
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[0169] The organic solvent useful in the preparation of a dope solution can be used without limitation as long as the above-mentioned components such as (meth)acrylic resin and urethane urea resin are simultaneously dissolved.
[0170] For example, dichloromethane is mentioned as a chlorine type organic solvent. Examples of the non-chlorine-based organic solvent include methyl acetate, ethyl acetate, amyl acetate, acetone, tetrahydrofuran, 1,3-dioxolane, 1,4-di2,3,3-hexafluoro-1- Propanol, 1,3-difluoro-2-propanol, 1,1,1,3,3,3-hexafluoro-2-methyl-2-propanol, 1,1,1,3,3, 3-hexafluoro-2-propanol, 2,2,3,3,3-pentafluoro-1-propanol, nitroethane, etc. Among them, methylene chloride, methyl acetate, ethyl acetate, acetone and the like are preferable.
[0171] In addition to the above-mentioned organic solvent, the dope preferably contains 1 to 40% by mass of a linear or branched aliphatic alcohol having 1 to 4 carbon atoms. By containing alcohol in the dope solution, gelation of the...
Embodiment 1
[0253] A dope was prepared by mixing the following components.
[0254] (composition of glue)
[0255] (Meth)acrylic resin A2: 95 parts by mass
[0256] Additive 1 (アクトフロ-UT1001): 5 parts by mass
[0257] Dichloromethane: 213.9 parts by mass
[0258] Ethanol: 67.6 parts by mass
[0259] The obtained dope was uniformly cast on a stainless steel belt support with a width of 2 m at a temperature of 30° C. using a belt casting apparatus. The solvent in the dope was evaporated on the stainless steel belt support until the residual solvent amount became 70%. Then, the obtained film was peeled off from the stainless steel belt support.
[0260] Next, after further drying the peeled film-like material at 45°C, the obtained film was dried while being conveyed by a plurality of rollers in a drying zone of 110°C and 140°C to obtain a film having a film thickness of 40 μm. .
[0261]Corona treatment was performed on the surface of the obtained film under the condition of 100W. The...
Embodiment 2
[0263] A film 102 having a film thickness of 40 μm was obtained in the same manner as in Example 1, except that the film composition was changed to (meth)acrylic resin A6 / cellulose ester E=90 parts by mass / 10 parts by mass.
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