Functional cellulose fiber containing graphene and preparation method thereof

A technology of cellulose fiber and alkene function, applied in graphene functionalized cellulose fiber and its preparation, in the field of preparing graphene functionalized cellulose fiber, which can solve the problem of low heating rate, far-infrared and low temperature of graphene functionalized cellulose fiber. Problems such as poor anti-ultraviolet performance and poor thermal stability, to achieve the effect of good far-infrared and anti-ultraviolet performance, good functionality, and improved performance

Active Publication Date: 2016-05-25
潍坊欣龙生物材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] (4) The prepared graphene-functionalized cellulose fiber has a small heati

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0054] Example 1:

[0055] 1) Preparation of graphene / cellulose spinning solution

[0056] (1) Preparation of graphene dispersion

[0057] Disperse graphene in deionized water by heating, stirring and dispersing method and adding hydroxyethyl cellulose to prepare graphene dispersion, wherein the graphene dispersion in the graphene dispersion: hydroxyethyl cellulose: quality of deionized water The ratio is 2.0:0.5:100.

[0058] The graphene dispersion is further ground and dispersed by a sand mill to reduce the particle size of the graphene and improve the dispersion effect of the graphene.

[0059] (2) Preparation of graphene / cellulose primary spinning solution

[0060] Add the prepared graphene dispersion to the prepared cellulose spinning solution at a mass ratio of 1:1, and stir for 0.5h through high-speed shear stirring to obtain a preliminary graphene / cellulose mixed solution , And then use continuous deaeration or static spinning for deaeration and standby;

[0061] (3) Preparatio...

Example Embodiment

[0073] Example 2:

[0074] 1) Preparation of graphene / cellulose spinning solution

[0075] (1) Preparation of graphene dispersion

[0076] Disperse graphene in deionized water by heating ultrasonic dispersion method and adding silane coupling agent to prepare graphene dispersion, wherein the graphene dispersion contains graphene: hydroxyethyl cellulose: quality of deionized water The ratio is 4.0:0.8:100.

[0077] The graphene dispersion is further ground and dispersed by a sand mill or a ball mill, etc., to reduce the particle size of the graphene and improve the dispersion effect of the graphene.

[0078] (2) Preparation of graphene / cellulose primary spinning solution

[0079] Add the prepared graphene dispersion to the prepared cellulose spinning solution at a mass ratio of 1:1.2, and stir for 0.8h by means of high-speed shear stirring to obtain a preliminary graphene / cellulose mixed solution , And then use continuous deaeration or static spinning for deaeration and standby;

[0080...

Example Embodiment

[0087] Example 3:

[0088] 1) Preparation of graphene / cellulose spinning solution

[0089] (1) Preparation of graphene dispersion

[0090] Disperse graphene in deionized water by heating high-speed shearing auxiliary method and adding carboxymethyl cellulose to prepare a graphene dispersion, wherein the graphene dispersion contains graphene: hydroxyethyl cellulose: deionized The ratio of water mass is 6.0:1.2:100.

[0091] The graphene dispersion is further ground and dispersed by a sand mill to reduce the particle size of the graphene and improve the dispersion effect of the graphene.

[0092] (2) Preparation of graphene / cellulose primary spinning solution

[0093] Add the prepared graphene dispersion to the prepared cellulose spinning solution at a mass ratio of 1:1.5, and stir for 1.0h by means of high-speed shear stirring to obtain a preliminary graphene / cellulose mixed solution , And then use continuous deaeration or static spinning for deaeration and standby;

[0094] (3) Prepara...

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Abstract

The invention provides a functional cellulose fiber containing graphene. The functional cellulose fiber containing the graphene is obtained by mixing graphene dispersion liquid with a cellulose spinning solution to prepare a graphene/cellulose spinning solution and then subjecting the graphene/cellulose spinning solution to wet spinning, wherein mass content of the graphene, in the graphene/cellulose spinning solution, accounting for Alpha cellulose in the graphene/cellulose spinning solution ranges from 2.0% to 6.0%. The invention further provides a preparation method of the functional cellulose fiber containing the graphene. In the graphene/cellulose spinning solution prepared by the method, uniformity in dispersion and difficulty in agglomeration of the graphene are achieved. According to the method, the step that oxidized graphene is reduced by a reducing agent in a follow-up process is omitted, so that fiber performance is improved. Content of the graphene in the functional cellulose fiber containing the graphene is 2.0-6.0%. The functional cellulose fiber containing the graphene is uniform in graphene distribution, high in temperature rise rate, excellent in far-infrared and anti-ultraviolet performance and better in thermal stability performance.

Description

technical field [0001] The invention relates to a graphene-functionalized cellulose fiber and a preparation method thereof. Specifically, a flexible online adding device is used to realize uniform dispersion of graphene in a cellulose solution, and is applied to prepare graphene-functionalized cellulose fibers. It belongs to the field of textile technology. Background technique [0002] Graphene is a planar film composed of carbon atoms in a hexagonal honeycomb lattice with sp2 hybrid orbitals. It is a new material with a two-dimensional single-layer sheet structure with a thickness of only one carbon atom. It has excellent electrical conductivity, thermal conductivity and Mechanical properties, thus becoming an ideal functional filler for the preparation of functional polymer composites. [0003] Viscose fiber is similar to cotton fiber in performance, comfortable to wear, has good hygroscopicity and dyeability, and has advantages that other chemical fibers cannot match. ...

Claims

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Application Information

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IPC IPC(8): D01F2/08D01F1/10
CPCD01F1/10D01F2/08
Inventor 马君志李昌垒秦翠梅王东吴亚红郝连庆刘乐
Owner 潍坊欣龙生物材料有限公司
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