Colored photosensitive resin composition and light shielding spacer prepared therefrom
A technology of photosensitive resin and composition, applied in photosensitive materials, optomechanical equipment, optics and other directions for optomechanical equipment, can solve problems such as pinholes and uneven coating, and achieve the improvement of resolution limit and illumination limit Effect
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example 1
[0109] Preparation Example 1: Copolymer
[0110] 100 g of the monomer mixture shown in Table 1 below, 300 g of PGMEA as a solvent, and 2 g of 2,2′-azobis(2,4-dimethylvaleronitrile) as a radical polymerization initiator were placed in a 500 mL circle bottom flask equipped with a reflux condenser and a stirrer. The temperature was raised to 70°C, and the mixture was stirred for 5 hours for polymerization, resulting in a copolymer with a solids content of 31% by weight. The copolymer thus produced had an acid value of 100 mgKOH / g, and a polystyrene reference weight average molecular weight (Mw) of 20,000 as measured by gel permeation chromatography.
[0111] [Table 1]
[0112]
preparation example 2
[0113] Preparation Example 2: Compound Derived from Epoxy Resin Having Dibenzopyran Main Chain Structure
[0114] 160 g of PGMEA as a solvent was placed in a flask equipped with a stirrer, a thermometer, a nitrogen replacement device, and a reflux condenser. Subsequently, 100 g of (3,3'-(spiro[fluorene-9,9'-dibenzopyran]-3',6'-diylbis(oxyl))bis((2- Hydroxypropane-3,1-diyl)diacrylate) and 0.1g hexachloroplatinum, then the mixture was heated to 80°C. 47.6g1,2,4,5-cyclohexanetetracarboxylic dianhydride were dissolved in 80 g of PGMEA, then slowly added dropwise to the above mixture. The mixture was then heated to 100° C. and reacted for 2 hours. The mixture was cooled to room temperature (25° C.) and added together with 0.3 g of pyridinium p-toluenesulfonate. , a copolymer compound having a solid content of 50% by weight, an acid value of 107 mgKOH / g, and a Mw of 6,000 was obtained.
preparation example 3
[0115] Preparation Example 3: Colored Dispersion
[0116] With the copolymer obtained in the above-mentioned preparation example 1 of 8g, 8g polymer dispersant (Dispic-2000, Bi Ke), 12g carbon black, 53g as the lactam black of organic black (Black582, BASF), 16gC.I . Pigment Blue 15:6 and 384 g of PGMEA as a solvent were placed in a paintershaker, and the mixture was dispersed at 25°C to 60°C for 6 hours. This dispersion step was performed with 0.3 mm zirconia beads. When the dispersion step is completed, the beads and the dispersion are separated, thereby producing a colored dispersion.
PUM
| Property | Measurement | Unit |
|---|---|---|
| acid value | aaaaa | aaaaa |
| acid value | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More