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Highly-antibacterial novel slightly-soluble nonwoven cloth capable of adsorbing heavy metal particles

A technology for adsorbing heavy metals and tiny particles. It is used in non-woven fabrics, textiles and papermaking, radiation wave/microwave fiber processing, etc. It can solve the problems of inability to adsorb toxic and harmful substances, limiting the wide application of chitosan, and harsh temperature requirements. To achieve the effect of improving water solubility, good antibacterial properties, and improving strength

Active Publication Date: 2016-06-01
湖北立天生物工程有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The non-woven fabrics used in sanitary products were originally produced by polypropylene, polyester, etc. During production, the temperature requirements were relatively strict, the operation was difficult, and the overall hardness was relatively large. Later, ES fibers were used to produce non-woven fabrics, which have bulkiness, softness, High-strength, oil-absorbing, water-absorbing, etc., can be used for disposable sanitary products such as masks, diapers, sanitary napkins, etc., but has limited functions, does not have antibacterial properties, and cannot absorb toxic and harmful substances
[0003] Chitosan, also known as water-soluble chitin, is a polysaccharide natural polymer. It is a product prepared by deacetylation of chitin. It has good biocompatibility, antibacterial, biodegradability and The ability to absorb heavy metal ions, using chitosan to spin chitosan fibers, has significant antibacterial and anti-mildew effects, and can be widely used in sanitary textiles and clothing, such as sanitary napkins, baby clothes, gauze for burns and wound treatment, etc. However, due to the strong hydrogen bonding between chitosan molecules, the ordered structure between molecules makes the chitosan crystal structure dense and stable, so it is only soluble in acidic aqueous solution, which limits the wide application of chitosan

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A new type of slightly soluble non-woven fabric with high antibacterial properties and adsorption of tiny heavy metal particles. It is prepared from carboxymethyl chitosan fiber, chitosan fiber and ES fiber with low melting point. Carboxymethyl chitosan fiber dissolves 15%, and chitosan fiber dissolves 7%, resulting in a slightly soluble state; ES fiber has an inner core structure, the inner core is PP fiber, and the outer skin is PE fiber; carboxymethyl chitosan fiber , chitosan fiber, ES fiber three kinds of weight percentages are: carboxymethyl chitosan fiber is 1%, chitosan fiber is 5%, ES fiber is 94%, carboxymethyl chitosan fiber melting point is 500~800℃, the melting point of chitosan fiber is 300~600℃, the melting point of PP fiber is 165~173℃, and the melting point of PE fiber is 124~138℃.

[0028] The preparation technology of slightly soluble nonwoven fabric comprises the following steps:

[0029] 1. Preparation of carboxymethyl chitosan fiber

[0030] (1) ...

Embodiment 2

[0041] A new type of slightly soluble non-woven fabric with high antibacterial properties and adsorption of tiny heavy metal particles, prepared from carboxymethyl chitosan fiber, chitosan fiber and ES fiber with low melting point, under the environment of temperature 30 ℃ and pH 6.0 Carboxymethyl chitosan fiber dissolves 20%, chitosan fiber dissolves 4%, resulting in a slightly soluble state; ES fiber has an inner core structure, the inner core is PP fiber, and the outer skin is PE fiber; carboxymethyl chitosan fiber , chitosan fiber, ES fiber three kinds of weight percentages are: carboxymethyl chitosan fiber is 5%, and chitosan fiber is 10%, and ES fiber is 85%, and structure is identical with embodiment 1.

[0042] The preparation technology of slightly soluble nonwoven fabric comprises the following steps:

[0043] 1. Preparation of carboxymethyl chitosan fiber

[0044] (1) Set the molecular weight to 1×10 4 , Chitosan with a deacetylation degree of 92% and isopropanol ...

Embodiment 3

[0055] A new type of slightly soluble non-woven fabric with high antibacterial properties and adsorption of tiny heavy metal particles. It is prepared from carboxymethyl chitosan fiber, chitosan fiber and ES fiber with low melting point. Carboxymethyl chitosan fiber dissolves 21%, resulting in a slightly soluble state; ES fiber has an inner core structure, the inner core is PP fiber, and the outer skin is PE fiber; carboxymethyl chitosan fiber, chitosan fiber, ES fiber The weight percent of three kinds of fibers is: carboxymethyl chitosan fiber is 10%, and chitosan fiber is 20%, and ES fiber is 70%, and structure is identical with embodiment 1.

[0056] The preparation technology of slightly soluble nonwoven fabric comprises the following steps:

[0057] 1. Preparation of carboxymethyl chitosan fiber

[0058] (1) Set the molecular weight to 1×10 4 1. Chitosan with a deacetylation degree of 92% and isopropanol were mixed evenly at room temperature at a mass ratio of 1:5, swel...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses highly-antibacterial novel slightly-soluble nonwoven cloth capable of adsorbing heavy metal particles.The nonwoven cloth is prepared from carboxymethyl chitosan fibers, chitosan fibers and low-melting-point ES fibers, the ES fibers are of a structure with an inner core which is PP fibers, outer skin is PE fibers, content of the carboxymethyl chitosan fibers is 1-10%, degree of substitution at O positions is 0.7, degree of substitution at N positions is 0.5, content of the chitosan fibers is 5-10%, content of the ES fibers is 70-94%, and the nonwoven cloth is prepared by bonding the carboxymethyl chitosan fibers, the chitosan fibers and the ES fibers through hot air.The nonwoven cloth is soft, breathable, high in strength, less prone to breakage and remarkably higher in moisture absorbing and maintaining performance.The carboxymethyl chitosan fibers and the chitosan fibers can be dissolved at different degrees when temperature is 25-40 DEG C and PH is 5.0-8.0 to be in a slightly-soluble state, so that particles can be blocked and filtered effectively and the nonwoven cloth has higher antibacterial performance and higher performance in adsorbing the heavy metal particles.

Description

technical field [0001] The invention belongs to the technical field of non-woven fabrics, and in particular relates to a novel slightly soluble non-woven fabric with high antibacterial properties and adsorption of tiny particles of heavy metals. Background technique [0002] Non-woven fabric is a kind of fabric formed without spinning and weaving. It is just oriented or randomly arranged textile short fibers or filaments to form a web structure, and then reinforced by mechanical, thermal bonding or chemical methods. A new type of fiber product with soft, breathable and planar structure. The advantage is that it does not produce lint, is breathable and waterproof, environmentally friendly, flexible, non-toxic, tasteless, durable, and silky soft. It is also a kind of reinforcing material, and it also has the feeling of cotton . The non-woven fabrics used in sanitary products were originally produced by polypropylene, polyester, etc. During production, the temperature requirem...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D04H1/4382D04H1/541D01F9/00D06M10/00D06M13/50C08B37/08D06M101/10
CPCC08B37/003D01F9/00D04H1/4382D04H1/541D06M10/003D06M13/50D06M16/00D06M2101/10
Inventor 刘小辉
Owner 湖北立天生物工程有限公司
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