Method for improving magnetic properties of sintered neodymium-iron-boron thin-sheet magnet

A technology of NdFeB and magnetic properties, applied in the direction of magnetic materials, magnetic objects, inductors/transformers/magnets, etc., can solve the problem that the coercive force of sintered NdFeB thin sheet magnets does not increase significantly and affects the sintered NdFeB thin sheet magnets Squareness, rare earth metal powder instability and other problems, to achieve the effect of narrowing the content difference, easy operation, and improving the coercive force

Active Publication Date: 2016-06-01
NINGBO YUNSHENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method has the following problems: when rare earth metal powder is used, rare earth elements are more likely to enter the interior of the sintered NdFeB sheet magnet during the diffusion process, and the coercive force is significantly improved under the premise that the remanence is not significantly reduced, but Rare earth metal powders are unstable in the air environment, and atmosphere protection is required in the process of storage and surface coating formation, and it is difficult to carry out mass production; when rare earth compound powders are used, the rare earth compounds are more stable in the air environment. There is no need for atmosphere protection in the process of storage and surface coating, but the rare earth compound is not easy to decompose during the diffusion treatment, so that it is difficult for the rare earth element to diffuse into the sintered NdFeB thin sheet magnet, resulting in the sintered NdFeB thin sheet magnet. The improvement of the coercive force is not obvious, and it will affect the squareness of the final sintered NdFeB thin film magnet

Method used

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  • Method for improving magnetic properties of sintered neodymium-iron-boron thin-sheet magnet
  • Method for improving magnetic properties of sintered neodymium-iron-boron thin-sheet magnet
  • Method for improving magnetic properties of sintered neodymium-iron-boron thin-sheet magnet

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Embodiment 1

[0018] Embodiment 1: A method for improving the magnetic properties of sintered NdFeB thin-plate magnets, comprising the following steps:

[0019] ① Preparation of a suspension containing rare earth elements: the suspension containing rare earth elements is made of dysprosium oxide Dy 2 o 3 powder and calcium hydride CaH 2 The powder is uniformly dispersed in anhydrous ethanol after mixing, dysprosium oxide Dy 2 o 3 powder and calcium hydride CaH 2 The mass ratio of the powder is 3:1;

[0020] ② Evenly spray the suspension containing rare earth elements on the surface of the sintered NdFeB thin sheet magnet, and the sintered NdFeB thin sheet magnet has been surface pretreated before spraying;

[0021] ③Dry the sprayed sintered NdFeB flake magnets. The drying process is to keep warm at 60°C for 5 minutes, and store the sintered NdFeB flake magnets after drying in an inert gas environment;

[0022] ④ Put the dried sintered NdFeB sheet magnet at a pressure of 5×10 -4 In th...

Embodiment 2

[0028] Embodiment 2: A method for improving the magnetic properties of sintered NdFeB flake magnets, comprising the following steps:

[0029] ① Preparation of a suspension containing rare earth elements: the suspension containing rare earth elements is made of terbium Tb oxide 2 o 3 powder and calcium hydride CaH 2 The powder is mixed and uniformly dispersed in absolute ethanol, and the terbium oxide Tb 2 o 3powder and calcium hydride CaH 2 The mass ratio of the powder is 3:1;

[0030] ② Evenly spray the suspension containing rare earth elements on the surface of the sintered NdFeB thin sheet magnet, and the sintered NdFeB thin sheet magnet has been surface pretreated before spraying;

[0031] ③Dry the sprayed sintered NdFeB flake magnets. The drying process is to keep warm at 60°C for 5 minutes, and the sintered NdFeB flake magnets after drying are stored in an inert gas environment;

[0032] ④ Put the dried sintered NdFeB sheet magnet at a pressure of 5×10 -4 In the v...

Embodiment 3

[0038] Embodiment three: a method for improving the magnetic performance of a sintered NdFeB thin slice magnet, comprising the following steps:

[0039] ① Preparation of a suspension containing rare earth elements: the suspension containing rare earth elements is made of dysprosium oxide Dy 2 o 3 powder and calcium hydride CaH 2 The powder is mixed and uniformly dispersed in absolute ethanol, and the terbium oxide Tb 2 o 3 powder and calcium hydride CaH 2 The mass ratio of the powder is 3:1;

[0040] ②Immerse the sintered NdFeB flake magnet in a suspension containing rare earth elements for ultrasonic treatment, and the surface of the sintered NdFeB flake magnet has been pretreated before immersion;

[0041] ③Dry the impregnated sintered NdFeB thin-slice magnets. The drying process is to keep warm at 60°C for 10 minutes, and store the dried sintered NdFeB thin-slice magnets in an inert gas environment;

[0042] ④ Put the dried sintered NdFeB sheet magnet at a pressure of...

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Abstract

The invention discloses a method for improving magnetic properties of a sintered neodymium-iron-boron thin-sheet magnet. According to the method, the surface of the sintered neodymium-iron-boron thin-sheet magnet is coated with powder containing rare earth elements to form a surface coating layer, and diffusion treatment and aging treatment are carried out to allow the rare earth elements in the coating layer to enter the interior of the sintered neodymium-iron-boron thin-sheet magnet, wherein the powder containing the rare earth elements is a mixture of powder of rare earth oxide and powder of hydrogen storage alloy hydride. The method has the advantages that oxidation-reduction reaction is carried out between the rare earth elements and the hydrogen storage alloy hydride, the rare earth elements are reduced, hydrogen is released from the hydrogen storage alloy hydride during diffusion treatment, thus, the diffusion efficiency of the rare earth elements is remarkably reduced, the diffusion depth of the rare earth elements is increased, the content difference of the rare earth elements at different positions in the sintered neodymium-iron-boron thin-sheet magnet is reduced, the coercive force is obviously increased, and residual magnetism reduction is ensured not to be obvious; and moreover, mass production can be achieved, and the final squareness of the sintered neodymium-iron-boron thin-sheet magnet cannot be affected.

Description

technical field [0001] The invention relates to a method for improving the magnetic performance of a sintered NdFeB magnet, in particular to a method for improving the magnetic performance of a sintered NdFeB thin slice magnet. Background technique [0002] Sintered NdFeB magnets have excellent comprehensive magnetic properties and are widely used in aerospace, microwave communication technology, automobile industry, instrumentation and medical equipment and other fields. In recent years, the high-performance sintered NdFeB application market has rapidly developed in the direction of miniaturization, light weight and thinning. The promotion speed and application scope of high-end fields such as hybrid power are rapidly expanding, and the market has put forward higher requirements for its performance, not only requiring high remanence, but also requiring high coercive force. [0003] The traditional method to improve the coercive force of sintered NdFeB thin slice magnets is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F41/02
CPCH01F41/0293H01F1/0577
Inventor 杨庆忠石高阳张民丁勇吕向科胡依群
Owner NINGBO YUNSHENG
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