43results about How to "Reduced activation energy for diffusion" patented technology

The invention relates to a lithium ion solid electrolyte and a preparation method application thereof, and belongs to the technical field of a lithium ion battery. The lithium ion solid electrolyte has the chemical formula shown as follows: Li<3+a>M

A<m>B<n>Y<1-b>, wherein a is more than or equal to -0.25 but less than or equal to 0.25, b is more than or equal to 0 but less than or equal to 0.5, m is more than or equal to 0 but less than or equal to 1.25, n is more than or equal to 0 but less than or equal to 1.25, M is one of Ca, Ba, Mg, Al and Ti, A and B are separately selected from one of O, S, Se, Te, N, P, Si, C, Sb, Bi, F, Cl, Br and I, and Y is one of halogen, minus monovalent ionic group or vacancy. The lithium ion solid electrolyte has a stable structure and favorable lithium ion transmission performance and has favorable electrochemical performance and safety performance when used as a solid electrolyte of the lithium ion battery.

The invention relates to a TiAl-intermetallic-compound vacuum diffusing connection method, belonging to the TiAl-intermetallic-compound welding field, which overcomes the technical drawbacks of high temperature of diffusing connection and high pressure of diffusing connection in the prior TiAl-intermetallic-compound diffusing connection technology. The invention adopts hydrogenated titanium or titanium alloy chaff as the interface layer of diffusing connection. Ti3Al+TiAl dual phase (Alpha2+Gamma) organ can be formed under the temperature of diffusing connection titanium, which facilitates the formation of high-intensity connector lug of TiAl-intermetallic-compound diffusing connection. And hydrogen makes the flow stress of thermal deformation of titanium or titanium alloy decrease and the thermal plasticity increase, so that hydrogenated titanium or titanium alloy is prone to deform under high temperature. Meanwhile,, the self-diffusing capacity of hydrogen in titanium or titanium alloy and the diffusing capacity of solute are enhanced, more particularly, in Beta phase the capacities are more enhanced, so that hydrogen can accelerate the diffusing of the alloy elements, reduce the atomic combination energy and the diffusing activation energy, promote the diffusing coordinated deformation capacity, and the reliable diffusing connection of connector lug of TiAl-intermetallic-compound can be realized under comparatively low temperature.

The invention relates to a method for carrying out anatonosis by adopting laser plasma impact waves in a chemical heat treatment process. According to the method, induction to generate plasma impact waves are generated by induction with high-power short-pulse laser, act on materials and are combined with chemical heat treatment, thereby improving the surface property of metal materials and members and enhancing the oxidation resistance, abrasion resistance and corrosion resistance of the metal material and the members, wherein the chemical heat treatment can be alumetizing, carburization, nitridation, aluminum-chromium penetration and the like. The method disclosed by the invention has the beneficial effects that the temperature of the chemical heat treatment in order to obtain identical penetration layer depth, the temperature of the chemical heat treatment can be obviously reduced, and the treatment time is shortened, thereby reducing the deformation of workpieces.

The invention provides a material wettability improvement device and method based on multi-field coupling. The material wettability improvement device comprises an operation platform, a vacuum furnace stored on the operation platform, a high-voltage power supply control box, an ultrasonic auxiliary device, an electric field auxiliary device and a magnetic field auxiliary device. A rack on one side of the vacuum furnace is provided with a guide rail stand column. The upper end of the guide rail stand column is provided with a movable cross beam. An ultrasonic transducer is fixed to the cross beam. An ultrasonic variable-pressure rod stretches into the vacuum furnace through a corrugated pipe. The electric field auxiliary device is arranged below the ultrasonic variable-pressure rod. A sample is stored on an insulating ceramic plate and positioned through a stop block. The inner side of the vacuum furnace is further provided with a magnetic field power coil which generates a variable magnetic field after being applied with current. By adoption of the material wettability improvement device and method, the sample can be wetted under mutual assistance of an ultrasonic vibration load, an electric field and the magnetic field, and the problems that existing additionally arranged auxiliary equipment is simplex in applying mode, the ultrasonic applying mode is large in power loss, and simplex assistance is unobvious in sample wettability improvement effect are solved.

The invention relates to a laser shock technology for improving the ion nitriding efficiency. The technology comprises the following steps: processing and cutting raw steel to form a sample; quenchingand tempering the sample, polishing the sample, ultrasonically cleaning the polished sample in an organic solvent, and drying the cleaned sample; clamping the sample to a laser shock peening test platform, and performing laser shock treatment on the surface; and placing the sample in an ion nitriding furnace, performing ion nitriding treatment, and performing furnace cooling to room temperature.The technology has the following advantages: laser shock treatment causes plastic deformation of the surface layer of a material to form high density dislocations, refine crystal grains and even generate nanocrystals, so diffusion channels are provided for nitrogen atom diffusion, and the diffusion activation energy is reduced, thereby the technology significantly increases the nitriding efficiency, and has the advantages of high efficiency and energy saving.

The invention relates to a metal surface aluminizing technique, in particular to a low-temperature oil casing steel surface pack cementation aluminizing technique. The invention at least solves the following problems that: the complex change of the variety and content of aluminizing agent in the aluminizing technique needs to be reduced by changing aluminizing agent, the property stability can hardly be controlled, and the cost is high. The adopted technical scheme is as follows: the low-temperature oil casing steel surface pack cementation aluminizing technique sequentially includes the following steps that: the surface nanocrystallization of an oil casing steel sample: a SNC-2 metal surface nanocrystallization tester is utilized to nanocrystallize the surface of the oil casing steel sample in order to obtain a nano-structured surface layer with the thickness of 50Mu m to 90Mu m; the aluminization of the surface-nanocrystallized oil casing steel sample: aluminizing process parameters are as follows: the aluminizing temperature is 380 DEG C to 500 DEG C, and the aluminizing time is 6 hours to 10 hours; and the composition and content of the aluminizing agent are as follows: Al powder as metal source, Zn powder, NH4CL as activating agent and Al2O3 as filler. The aluminizing temperature is low; the variety of aluminizing agent is simple, the content can be easily controlled, and the process stability is high; and the effect is good.

The invention discloses a nickel-cobalt lithium aluminate material coated with a sodium-based oxidizing agent and a preparation method thereof. According to the method, the surface of the nickel-cobalt lithium aluminate material is coated with a layer of sodium-based oxidizing agent, the sodium-based oxidizing agent is one or more of sodium peroxide, sodium bismuthate and sodium antimonate and hasstrong oxidability, in the sintering process, the oxidizing agent is partially diffused into crystal nuclei of the material, the oxidation of Ni<2+> is promoted, the lithium-nickel synchysis is reduced, a coating layer with a proper thickness is formed on the surface of the material by other part of the oxidizing agent, the material is prevented from being corroded by electrolyte in the chargingand discharging processes, and the cycling stability of the material is improved.

The invention provides a manufacturing process of hot work die steel for a high performance die-casting die and relates to the technical field of die steel. The manufacturing process of the hot work die steel comprises the following steps of (1) smelting; (2) high-temperature homogenization treatment; (3) forging; (4) annealing treatment; (5) quenching and tempering treatment; (6) nitriding treatment; and (7) tempering treatment. The hot work die steel is prepared from the following components in percent by weight: 0.33-0.46% of C, 1.5-2.3% of Si, 0.32-0.45% of Mn, 1.6-2.3% of Mo, 2.6-3.6% ofW, 0.16-0.27% of Nb, 2.8-3.7% of Cr, 0.21-0.53% of Sr, 0.16-0.31% of Ti, 0.05-0.09% of Ce, less than or equal to 0.003% of S, less than or equal to 0.03% of P and the balance Fe. The hot work die steel prepared by the manufacturing process has relatively high surface hardness and wear resistance, relatively good impact toughness and excellent fatigue resistance and strength, so that the service life of the hot work die steel for the die-casting die is prolonged effectively.

The invention belongs to the technical field of artificial diamonds and in particular relates to an accelerant for a gem grade colorless diamond and a preparation method thereof. The accelerant for the gem grade colorless diamond is powdery and is prepared from the following raw materials in percent by weight: 60-80% of Fe, 25-35% of Ni, greater than 0 but less than or equal to 1% of Co, greater than 0 but less than or equal to 0.5% of Si and greater than 0 but less than or equal to 0.8% of rare earth elements. The preparation method of the accelerant comprises the following steps: 1) meltingand mixing the raw materials; 2) carrying out gas atomization to prepare powder; 3) carrying out primary pressing; 4) carrying out vacuum treatment; and 5) carrying out secondary pressing. The accelerant used for prepare the colorless diamond is easy to produce, stable in structure of the diamond, good in catalytic effect, high in nitrogen removal effect, high in rate of finished products and highin practicality, and the product quality is ensured.

The invention relates to a sodium ion solid electrolyte and a preparation method thereof and belongs to the technical field of metal ion batteries. The chemical composition of the sodium ion solid electrolyte is NaaLibR(3-a-b)/2ApB1-pXmY1-m, wherein R is selected from metal ions of +2 valence, A and B are independently selected from one of SO42- and SeO42-, X and Y are independently selected fromone of monovalent chloride ions and fluoride ions, , 2.45 <= a <= 3, 0 <= b <= 0.45, 0 <= (3-a-b)/2 <= 0.05, 0 <= p <= 1, and 0 <= m <= 1. The sodium ion solid electrolyte has excellent sodium ion conductivity and thermodynamic stability, has three-dimensional equivalent ultrafast ion transmission capacity, lower diffusion activation energy and higher sodium ion conductivity, and a sodium ion battery electrode has good electrochemical compatibility.

The invention discloses a method for quickly preparing an aluminum-iron alloy coating on the surface of a metal material. According to the method, compound powder, medium balls and a to-be-treated workpiece are put into a sealed roller, and the sealed roller is put into an aluminized furnace for heating at the same time. The roller is connected with a turntable at one side by virtue of a flange, and then is connected with a gear motor by virtue of a bearing, and the gear motor rotates at different speeds to provide different rotating speeds for the roller. The surface of the to-be-treated workpiece is subjected to impact and friction by using the rolling of the medium balls and the compound powder in the sealed roller, and by virtue of the combination of heat energy, mechanical impact and mechanical friction, a sufficient quantity of spare spaces required by atomic diffusion are generated on the surface of the workpiece, and a mechanical energy aided diffusion aluminum alloy coating is formed at 400-600 DEG C. The method disclosed by the invention has the advantages that compared with the conventional metal process, the activation energy of diffusion and the diffusing permeation temperature are reduced, the diffusing permeation time is shortened, the production efficiency is improved, and the energy conservation and consumption reduction are significant.

The invention discloses a surface treatment method capable of preventing a high-strength bolt from corrosion and thread gluing. According to the surface treatment method, a carbon nitrogen lanthanum yttrium ion seeping agent, a lanthanum yttrium activation seeping agent and an oxygen ion seeping agent are utilized to seep non-metallic elements and trace metal elements into the surface of a high-strength bolt substrate so as to form a compound layer and a metal oxidation layer, so that a wearing layer is formed on the surface of the high-strength bolt substrate, the service life of the high-strength bolt is greatly prolonged, the corrosion resistance of the high-strength bolt is also improved; and the high-strength bolt has high mechanical property, and the precision of the high-strength bolt is not affected by the surface treatment. The seeping agents are low in melting point and high in stability; and the ions are cooperated with each other, so that the seeping effect can be effectively ensured to ensure the product quality.

A vacuum diffusion connecting carbon/carbon composite material method belongs to the welding field of the carbon/carbon composite material. The present invention settles the problems of high jointing temperature, large metal deformation of the partial part of joint and inferior joint capability in the existing diffusion connecting carbon/carbon composite material. The invention comprises the following steps: 1. doing cleaning to the surface of the base metal; 2. homogeneously parking the diffusion middle layer to the connecting surface of the base metal to be welded; 4. reducing temperature then the welded component which is connected well is obtained. The diffusion connecting carbon/carbon composite material of the invention is reduced by 100 to 300 DEG C, the shear strength of the diffusion connecting between the carbon/carbon composite material and the carbon/carbon composite material or the carbon/carbon composite material to other metal material is increased by 20 to 220 percent, and the metal at the joint has no evident shape change.

The invention provides a fused salt system for molybdenum or molybdenum alloy binary co-penetration, a composite catalyst and application. The fused salt system comprises 10% to 20% of borax, 0.9% to 1.2% of penetration-catalyzing activating agent rare earth metal, 2% to 6% of the composite catalyst and the balance fused salt. The mass ratio of thiourea and nickel chloride in the composite catalyst is 1:(0.8-1.25). The fused salt system for molybdenum or molybdenum alloy binary co-penetration is used for application of electrochemical binary co-penetration for manufacturing a rare earth metal-boron binary co-penetrated layer on the surface of molybdenum or molybdenum alloy. The molybdenum or molybdenum alloy manufactured through the fused salt system or provided with the binary co-penetrated layer is good in high-temperature oxidation resistance and can resist high-temperature oxidation corrosion. The composite catalyst is added to achieve the overall electrolysis effect, compared with a method that alloy is obtained through single rare earth penetration catalysis, the compatibility of the La-B binary co-penetrated layer manufactured through the method and a molybdenum or molybdenum alloy base body is good, and the La-B binary co-penetrated layer is not prone to cracking or falling. The use temperature of the molybdenum or molybdenum alloy with the surface subjected to binary co-penetration treatment can reach 1500 DEG C.

The invention provides a preparation method for a rare-earth metal-molybdenum binary diffusion coating on the surface of a kovar alloy. The method comprises the following steps that the uniform and compact rare-earth metal-molybdenum binary diffusion coating is formed on the surface of the kovar alloy by adopting a supersonic plasma spraying technology. The kovar alloy is subjected to combined oilremoval, pickling and activating, a supersonic plasma spraying method is adopted to prepare the rare-earth metal-molybdenum binary diffusion coating, and a post-treatment procedure is conducted on the diffusion coating. The obtained kovar alloy rare-earth metal-molybdenum binary diffusion coating is good in binding force and fine and smooth in appearance, can tolerate an atomic oxygen impact testand a high-low temperature impact test in a low-orbit space environment, and meets the requirements of comprehensive performance such as tensile strength. Experiments and tests prove the feasibilityof the process. According to the method, the supersonic plasma spraying technology is adopted to prepare the rare-earth metal-molybdenum binary diffusion coating on the surface of the kovar alloy, andthe method has the technical advantages that the process is simple, the cost is low, the zero pollution is realized, and the comprehensive effect of the coating is remarkable.

The invention provides a preparation method of a silicon-containing layered double-metal hydroxide, the preparation method comprises the following steps: mixing a divalent metal ion hydroxide and a trivalent metal ion hydroxide, and carrying out ball milling to obtain a hydroxide mixture; then dispersing the obtained hydroxide mixture in a solvent to obtain hydroxide mixture dispersion liquid; adding SiCl4 into the hydroxide mixture dispersion liquid, fully stirring to obtain a suspension liquid, and then standing and aging; and after the reaction is finished, filtering, washing and drying to obtain silicon-containing layered double-metal hydroxide powder. The method disclosed by the invention is mild in experimental condition, simple to operate, low in energy consumption, less in sewage discharge, high in yield, easy to industrialize and the like. The prepared product has high specific surface area and crystallinity, and has great application value in the fields of catalysis, energy storage, flame retardants, composite materials and the like.

The invention discloses a method for low-temperature diffusion welding of tungsten and low-activation steel. The method comprises the following steps: carrying out surface severe plastic deformation treatment on the low-activation steel to refine the grain sizes of the surface and near surface of the low-activation steel to nanoscale to obtain surface structure modified low-activation steel; and tungsten and the surface structure modified low-activation steel are welded through a diffusion welding method. By means of the method, high-strength connection of tungsten and the low-activation steel can be achieved near the tempering temperature of the low-activation steel, the excellent tensile strength of a connector is guaranteed, meanwhile damage to the mechanical property of a low-activation steel body in the existing diffusion welding process is reduced, and an obtained tungsten and low-activation steel connecting piece can be used at high temperature.