72results about How to "Increased Diffusion Depth" patented technology

The invention relates to a grain boundary diffusion method for improving properties of sintered NdFeB magnets. The grain boundary diffusion method comprises the following steps of stacking sintered NdFeB magnets and diffusion alloy sheets together and placing in a hot-pressing furnace; vacuumizing the hot-pressing furnace until the vacuum degree reaches a set value, heating the hot-pressing furnace, and when the temperature of the hot-pressing furnace reaches a set value, beginning to exert a pressure and maintaining the pressure and putting the diffused sample into a high-vacuum furnace for annealing, wherein the diffusion alloy sheets are low-melting-point eutectic diffusion alloys and are represented by R-TM, R is one or more of Sc, Y, La, Ce, Pr or Nd and TM is one or more of Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn. Compared with the prior art, the sintered NdFeB magnets modified by the pressure diffusion method, which is provided by the invention, have the advantages of large diffusion depth of a diffusion agent, uniform distribution of grain boundary phases, high coercivity and the like, especially, low-melting-point diffusion alloys designed by the invention are free of expensive heavy rare earth element dysprosium and thus the cost of the raw materials is relatively low, the diffusion temperature is low and the energy consumption in the diffusion process is small.

The invention discloses a crystal boundary diffusion method for improving the coercive force and the thermal stability of a neodymium-iron-boron magnet, and belongs to the field of rare earth permanent magnet materials. According to the method, a quaternary alloy Dy-Ni-Al-Cu with a low melting point is used as a diffusion source and melted and prepared into a rapid-hardening strip, after coarse breaking, the strip casting is laid around the neodymium-iron-boron magnet, and by the adoption of a heat treatment method, the rapid-hardening strip diffuses and enters the magnet along the crystal boundary. After the processing, the coercive force of the magnet is significantly improved, and the magnetic energy product is improved to a certain extent; meanwhile, since the temperature of the diffusion treatment is low, energy consumption can be reduced, the cost can be lowered, and Nd2Fe14B crystal grains can be prevented from growing up; compared with a coating and magnetron sputtering method, the crystal boundary diffusion method omits a powder preparing and coating process in a coating technology and a thin film preparing process in a magnetron sputtering technology. After the technology processing of the crystal boundary diffusion method, the neodymium-iron-boron magnet with the high coercive force and the high thermal stability is finally obtained.

The invention discloses a preparation method of a high-performance neodymium-iron-boron magnet. The preparation method comprises the following steps: preparing R1-Fe-B-M sintered magnet blank, configuring volatile oil solvent suspension containing alloy powder of heavy rare earth or low melting point metal, hydride, fluoride or oxide and heating, cleaning the blank and immersing the blank into thesuspension at the angle of 5-45 degrees and then taking out and sintering so as to obtain the magnet. The preparation method has the advantages that the high-temperature volatile organic solvent is applied and volatilization is quite quick so as to greatly improve uniformity and controllability, omit the conventional dip-coating or spray-drying process in the past, save energy, greatly improve the production efficiency, increase the material utilization rate reduce the cost and have higher uniformity of diffusion; and the introduction of impurities such as C is greatly reduced by the use of the volatile solvent.

The invention relates to a method for improving magnetic performance of a sintered neodymium-iron-boron magnet. The method is suitable for sintered neodymium-iron-boron magnets with various components. The method comprises low-melting-point metal or alloy grain boundary repairing, heavy rare earth element grain boundary diffusion and corresponding heat treatment technologies. According to the method, the character of the low melting point of an alloy is utilized, the surface-layer discontinuous grain boundary rare earth phase of the magnet is preferably diffused and repaired, a continuous low-melting-point rare earth phase is obtained and serves as a channel for rapid diffusion of heavy rare earth elements, the diffusion depth of the heavy rare earth elements in the magnet is effectively improved, the usage amount of the heavy rare earth elements is reduced, the coercivity of the magnet is improved, and wide application value is achieved.

A disclosed method for preparing a nanometer surface coating comprises the following steps: 1) performing ball milling on a self-propagation reaction metal mixed powder, coating on the surface of a metal plate; 2) igniting the metal mixed powder coating on the surface of the metal plate to make the metal mixed powder coating have a self-propagation reaction; and 3) performing shot blasting on the metal mixed powder coating subjected to the self-propagation reaction, to obtain the nanometer surface coating after the self-propagation reaction and shot blasting are finished. According to the method, shot blasting is performed on the coating after the self-propagation reaction is carried out for a certain time, so that the coating metal powder is increased in diffusion depth in the metal surface, and the bonding force between the coating and the matrix metal is increased; by shot blasting, the density of the coating is improved substantially, and shot blasting has surface nanocrystallization effect; the prepared coating has high density and high viscosity; and the preparation method of the invention is simple in equipment, low in energy consumption and low in cost.

A method for preparing a sintered rare earth-based magnet using a melting point depression element and a sintered rare earth-based magnet prepared by the same are disclosed. The method for preparing a sintered rare earth-based magnet according to the present invention includes the steps of: heating an R—Fe—B based magnet powder to a predetermined temperature to produce a sintered magnet, in which R is a rare earth element or a combination of rare earth elements; coating the surface of the produced sintered magnet with a coating solution prepared by mixing a heavy rare earth powder and a melting point depression element powder in a solvent; and heat-treating the coated sintered magnet.

A method for obtaining a high-magnetism sintered NdFeB by hot isostatic pressing low-temperature sintering belongs to the technical field of a rare-earth magnetic material. The method comprises the steps of performing half-density sintering on sintered NdFeB magnetic power, covering surrounding of half-density sintered NdFeB with a low-melting point diffusion alloy source, placing the NdFeB in a glass tube, performing vacuum glass tube sealing, and performing hot isostatic pressing low-temperature sintering and tempering to prepare the high-density and high-magnetism sintered NdFeB magnet. Inthe hot isostatic pressing low-temperature sintering process, the glass tube is a molten state, a layer of glass package sleeve is formed on a surface of a sample, and the sintering density of the half-density NdFeB magnet reaches 7.5g/cm<3> or above by air pressure acting on each surface of the glass package sleeve; meanwhile, the diffusion element diffusing along a boundary is accelerated underthe effect of air pressure, the depth of a diffusion layer is increased, and the thickness of the sample reaches 1.5 centimeter or above; the NdFeB magnet subjected to hot isostatic pressing low-temperature sintering has the advantages of large diffusion depth, uniform boundary phase distribution, clean boundary, fine crystal grain, high density, high coercivity and the like.

The invention discloses a method for improving the corrosion resistance of neodymium-iron-boron magnet by carrying out grain boundary diffusion on Al-Cu alloy, belonging to the field of rare earth magnetic materials. According to the method, an Al-Cu alloy ordinary ingot which has a low melting point and high potential is directly used as a surface diffusion source of the neodymium-iron-boron magnet after being coarsely crushed and ball-milled, and an Al-Cu-rich thin layer is formed at the crystal boundary of the neodymium-iron-boron magnet after diffusing heat treatment and annealing heat treatment are carried out, so that the neodymium-iron-boron magnet with high corrosion resistance is obtained. According to the method, Al-Cu alloy is taken as the diffusion source, thus avoiding the phenomenon that the residual magnetism of the magnet is reduced since Al and Cu elements are not directly added into the ingot, and the non-magnetic Al and Cu enter a principal phase so as to generate a magnetic dilution effect; the corrosion resistance and magnetic property of the magnet also can be improved since the grain boundary diffusion can improve the chemical stability of a grain boundary phase, optimize a microstructure, improve the distribution of the grain boundary phase, and increases the density of the magnet.

The invention discloses a zirconium-containing copper silver titanium solder alloy. The zirconium-containing copper silver titanium solder alloy comprises the following components by mass percent: 10-45% of Ag, 1-4% of Ti, 0.5-5% of Zr and Cu for the rest. A vacuum melting and argon shield casting mode is adopted, silver and copper are molten at first and then titanium and zirconium are added. The zirconium-containing copper silver titanium solder alloy can be used for directly soldering copper alloys, iron steel, ceramics and diamonds. The zirconium-containing copper silver titanium solder alloy has the advantages as follows: the cost is low; a connector is high in mechanical strength, has smooth surface, is stable in quality and is good in uniformity after the copper alloys are soldered by the zirconium-containing copper silver titanium solder alloy; and the joint clearances can be fully filled up. The zirconium-containing copper silver titanium solder alloy can replace the conventional copper silver titanium solder and is suitable for large-scale industrial application.

The invention provides a method for preparing a highly corrosion-resistant sintered NdFeB magnet. The method comprises the following steps: performing orientation pressing on sintered NdFeB magnetic powder in a 1.5-2.0T oriented magnetic field under the pressure of 16MPa, performing cold press molding on a pressed shape in an oil-cooled isostatic pressing machine so as to obtain a green body; performing low-temperature vacuum pre-sintering on the green body in a vacuum sintering furnace at the temperature of 850-890 DEG C for 3-3.5 hours so as to obtain a magnet; taking the magnet as a substrate, and covering a non-rare-earth compound layer on the surface of the substrate by adopting a magnetron sputtering method; performing high-temperature sintering in the vacuum sintering furnace for 2-3 hours, performing secondary tempering treatment, filling inert gases of 20-22MPa for applying pressure in the temperature treatment process, thereby obtaining the highly corrosion-resistant sintered NdFeB magnet. According to the magnetron sputtering manner, a diffusion source is attached to the surface of the magnet, grain boundary diffusion is completed in the sintering process, the base bonding force is improved, and the diffusion depth and corrosion resistance are improved.

The invention discloses a method for improving the performance of a rare-earth permanent magnetic material by high temperature compressive stress. The method for improving the performance of the rare-earth permanent magnetic material by high temperature compressive stress at least comprises the following steps: attaching heavy rare-earth compounds to the surface of the sintered magnet; and obtaining the magnet through heating and applying compressive stress at high temperature. According to the invention, the problems of the limitation of the magnet specification and dimension and the inconsistency of the heavy rare-earth diffusion in the traditional process can be overcome by improving the diffusion depth of magnet, therefore, the diffusion effect is enhanced, the magnet can obtain better magnetic performance, the equipment investment is simple, the cost is lower, and the invention is suitable for large-scale promotion.

The invention discloses a method for improving performance of a sintered NdFeB magnet. According to the method, a metal oxide is reduced with hydrogen under a high temperature by means of the characteristic of low-melting metal oxide, low-melting metal is sequentially obtained according to a reduction sequence, a discontinuous crystal boundary rare-earth phase of a magnet surface layer is preferably diffused and recovered, a continuous low-melting point rare-earth phase is obtained and is used as a rapid diffusion passage of a heavy rare-earth element, the diffusion depth of the heavy rare-earth element in the magnet is effectively improved, the dosage of the heavy rare-earth element is reduced, the improvement of magnet coercivity is achieved, meanwhile, the dosage of the heavy rare-earthelement is also remarkably reduced, the method is simple in process, is easy to implement and has a wide application prospect.

The invention discloses a method for improving the magnetic performance of a samarium-cobalt permanent magnet material. The method comprises the steps: providing a samarium-cobalt permanent magnet asa base material, and the chemical formula of the base material as a powder orientation forming green body being Sm(CoxFeyCuzZrm)n, wherein x is larger than 0.5 and smaller than 0.9, y is larger than 0.01 and smaller than 0.1, z is larger than 0.01 and smaller than 0.1, m is larger than 0.01 and smaller than 0.1, and n is larger than 6 and smaller than 9; applying a low-melting-point phase diffusion source to the surface of the base material in a coating and/or cladding manner, and then performing vacuum and/or pressurized thermal diffusion treatment on the obtained base material; and carryingout sintering densification and aging treatment on the base material subjected to thermal diffusion treatment to prepare the samarium-cobalt permanent magnet material. According to the method providedby the invention, the magnetic performance of the samarium-cobalt permanent magnet material is effectively improved, and the application field of the samarium-cobalt rare earth permanent magnet material is expanded.

The invention discloses a grain boundary diffusion method suitable for a large rare earth permanent magnet material. A spark plasma sintering technology is used for carrying out grain boundary diffusion treatment on a magnet, and the comprehensive magnetic performance of the magnet is improved. The method comprises the following steps: (1) preparing an initial magnet through a sintering or hot pressing or thermal deformation process; (2) loading a grain boundary diffusion alloy source on the surface of the magnet through magnetron sputtering, electroplating, chemical vapor deposition, physicalvapor deposition, direct physical contact or bonding by a binder; and (3) putting the loaded initial magnet into a discharge plasma device, and carrying out grain boundary diffusion by using discharge plasma heating to raise the temperature, thereby obtaining the final magnet. By controlling the current, the plasma, the pressure and the like in the spark plasma sintering process, the diffusion coefficient of elements is remarkably increased, and the diffusion depth of the elements is increased. According to the grain boundary diffusion rare earth permanent magnet material prepared by the method, the magnetic performance is increased more remarkably, the grain boundary diffusion process can be suitable for large magnets and is not limited by the thickness of the magnets, and the industrialproduction and market requirements are met.

The invention discloses little-defect clean Sn-Zn solder containing palladium. The solder comprises metal components including, by weight, 0.05-0.3% of Pd, 0.1-0.5% of Ga, 6-10% of In, 0.1-3.5% of Ag, 7-10% of Zn and the balance Sn. During preparation, the palladium is ground into powder for use after hydrogen absorption, and silver and tin are smelted into silver-tin intermediate alloy in proportion; remaining tin and the molten silver-tin intermediate alloy are placed in a furnace for melting, raw material zinc is added after temperature of molten liquid rises to 350-450 DEG C, heat preservation is carried out, and Sn-Zn-Ag intermediate alloy liquid is obtained; raw material indium and gallium are sequentially added, when the temperature of the molten liquid lowers to 250-350 DEG C, heat preservation is carried out, and Sn-Zn-Ag-In-Ga intermediate alloy liquid is obtained; palladium powder is added and is covered with a mixture of zinc chloride and vegetable oil after complete melting, heat preservation is carried out, and the mixture is poured to form cast ingot; the solder can be obtained after the cast ingot is extruded and drawn or rolled into a wire shape or a flaky shape. The solder has the advantages of being high in cleanliness, high wettability, little in soldering seam defect, low in melting point and the like.

The invention provides a preparation method of an annular radiation orientation magnet. The preparation method comprises the following steps: preparing a radiation ring neodymium iron boron blank; mixing HRx-My-Hz powder with an organic solvent to obtain a mixed solution, coating the surface of the radiation ring neodymium iron boron blank with the mixed solution, and then sintering; and carryingout heat treatment on the sintered radiation ring neodymium iron boron to obtain the annular radiation orientation magnet. Heavy rare earth elements are introduced into the radiation ring neodymium-iron-boron magnet through a diffusion method, the residual magnetism and coercive force of the annular radiation orientation magnet are improved, and the problem that the magnet cracks in the sinteringprocess is solved.

The invention discloses a new method for welding a ZL203 aluminum alloy on a preset magnesium-based amorphous intermediate layer, and belongs to the field of welding of aluminum alloys. The method is characterized by comprising the following steps of: cutting and sawing a self-poured ZL203 aluminum copper alloy test sample to form a block with the length of 35mm, the width of 15mm and the thickness of 15mm; polishing a surface to the welded of the test sample, and removing an oxidation film on the surface; and in order to ensure stressing uniformity of a joint, welding an aluminum copper alloy in a butt joint mode. According to the optimal parameter of a diffusion welding process, the pressure is 0.5MPa, the temperature rise velocity is 25 DEG C/min, the welding temperature is 510 DEG C, and the heat preservation time is 20 minutes; and at the moment, the tensile strength of a ZL203 aluminum copper alloy joint reaches the maximum value 185MPa, and the strength of a ZL203 aluminum copper alloy body is 180 to 190MPa.

The invention provides a neodymium iron boron permanent magnet material preparation method. Aluminum hydride is deposited on a neodymium iron boron magnet green body, the aluminum hydride releases reducing hydrogen during heating, oxidized heavy rare earth can be reduced at a high temperature, and grain boundary penetration effects can thus be improved. Aluminum is a low-melting-point metal, whenthe neodymium iron boron magnet is heated at a first sage, at a low temperature, on one hand, oil left on the surface of the neodymium iron boron green body in an isostatic pressing step is removed, and on the other hand, the low-melting-point aluminum is promoted to repair the surface grain boundary of the magnet. Dysprosium-iron alloy is then induced through second-stage heating to be quickly diffused with the well-repaired grain boundary low-melting point channel, the diffusion speed and the depth are enhanced, and the magnet can be completely dehydrogenated. Finally, through sintering, tempering and aging treatment, the neodymium iron boron permanent magnet material is obtained. The prepared neodymium iron boron permanent magnet material has the advantages of good uniformity, good consistency, deep diffusion of heavy rare earth, and the permanent magnet material performance is improved.

The invention discloses an electron beam surface alloying method for 45# steel. The electron beam surface alloying method comprises the steps of preset coating on the surface of the 45# steel and scanning through continuous electron beams, wherein the preset coating comprises the step that tungsten powder is sprayed on the surface of the 45# steel by plasma thermal spraying to form a spraying bonding layer; and scanning through continuous electron beams comprises the step that electron beam scanning is carried out on the surface of the 45# steel so as to obtain a surface alloying modification layer on the surface of the 45# steel. According to the electron beam surface alloying method, the continuous electron beam scanning technology is combined with the plasma thermal spraying, the novel medium-carbon steel-based composite material which takes a high-performance alloying element as a reinforced phase is prepared by adopting the unique advantages of the continuous surface treatment, so that the procedures are greatly simplified, the cost is reduced, the turnover time is shortened, and the surface performance of the 45# steel is improved and the service life of the 45# steel is prolonged by preparing the alloy layer with high hardness, high abrasion resistance and high corrosion resistance.

The invention discloses an R-T-B magnet material, a preparation method and an application thereof. The preparation method of the R-T-B magnet material comprises the following steps: performing hydrogen activation treatment on a sintered body of the R-T-B magnet material in a gas atmosphere; and then performing grain boundary diffusion, wherein the gas atmosphere includes a mixed gas of an inert gas and hydrogen; a temperature of the hydrogen activation treatment is 100-300 DEG C, and time is more than 10 minutes; a ratio of amass volume concentration of the hydrogen to the mass volume concentration of the sintered body is 0.01-0.1%; and the volume ratio of the hydrogen to the inert gas is 0.1-5%. The R-T-B magnet material disclosed by the invention is relatively good in high-temperature resistance, demagnetization resistance and coercive force; rare earth elements or a large amount of cobalt elements are not added during smelting so that cost is relatively low; grain refinement can beavoided, and production difficulty is low; and the R-T-B magnet material with a length within 1 mm in anorientation direction can be obtained, and the magnet material is good in magnetic performance.