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Water acid-sensitivity deformation magnetic tracer function self-suspension propping agent and preparation method thereof

A proppant and self-suspension technology, which is applied in chemical instruments and methods, earthwork drilling, mining fluids, etc., can solve the problem of endangering the health of drilling workers and surrounding residents, the ability to carry sand cannot meet the demand for large-scale sand addition, and increase equipment Load and chemical consumption and other issues, to achieve a wide range of application prospects and research value, improve the effective seepage capacity, optimize the effect of the effective fracture area

Inactive Publication Date: 2016-06-15
王展旭
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In recent years, the price of crude oil has continued to fall, the cost of mining has been tightened, and the formation water and surface water in conventional fracturing fluids have poor sand-carrying capacity and a large amount of filtration; natural guar gum and guar gum derivatives need to be added with buffers, fungicides, scale inhibitors, Various reagents such as emulsifiers, auxiliary dispersants, wetting agents, crosslinking agents, clay stabilizers, etc., and various compatibility tests such as water sensitivity, acid sensitivity, alkali sensitivity, salt sensitivity, speed sensitivity, pressure sensitivity, etc.; slippery water It consumes a lot of water resources, and the sand carrying capacity cannot meet the needs of large-scale sand addition, and the sand addition is uneven; organic / inorganic jelly, cross-linked polymer, VES, cross-linked foam, etc. will cause formation adsorption, residue and other damage, reducing penetration In addition, conventional proppants limit the growth and extension of fractures. In conventional fracturing, small particle size sand is generally added first, and then large particle size is added to gradually increase the sand ratio. The fracturing sand will settle quickly in slippery water. It will cause a "big belly" phenomenon; conventional fracturing can only effectively support 60%-70% of fractures, and the proppant cannot effectively migrate to the deep part of the fracturing fracture; conventional fracturing improves the viscosity of the fracturing fluid and the pump rate to improve the suspension of sand , will increase equipment load and chemical consumption; using small particle size proppant to improve sand suspension for fracturing will cause proppant to be embedded in the formation and reduce reservoir conductivity; low-density proppant has low strength, and high-density proppant The disadvantages of fast settlement and high price of coated sand, there is a contradiction between density, strength and price
The existing proppants can be inhaled into the lungs and cause silicosis, lung cancer and other diseases, reduce the quality of drinking water for residents, and endanger the health of drilling workers and surrounding residents. High-strength functional water with high temperature resistance, high salt resistance, and shear resistance The self-suspension proppant with magnetic tracer function is coated with resin to reduce dust and debris, and at the same time, it is coated with water-soluble expansion resin, which has the effect of reducing resistance, and the half-length of the crack is longer, so it can be transported farther away, and basically transported to the target In the oil area, there is no need for thickeners and enhancers, and clear water fracturing can be achieved, reducing the amount of chemicals used, reducing the overall cost of fracturing, simplifying the fracturing process, improving efficiency, and increasing oil and gas production. The existing functional water is acid-sensitive Deformation magnetic tracer function Self-suspension proppant is not strong enough to suspend sand, and its compressive strength and acid and alkali resistance are insufficient. At present, there is no effective high-strength water-acid-sensitive deformation magnetic tracer with high temperature resistance, high salt resistance, and shear resistance. Preparation of functional self-suspending proppant and fracturing construction method

Method used

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  • Water acid-sensitivity deformation magnetic tracer function self-suspension propping agent and preparation method thereof
  • Water acid-sensitivity deformation magnetic tracer function self-suspension propping agent and preparation method thereof
  • Water acid-sensitivity deformation magnetic tracer function self-suspension propping agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The self-suspending proppant with water acid-sensitive deformation magnetic tracer function described in this embodiment is composed of aggregate (i.e. traditional proppant), cationic polymer layer, anionic polymer layer, and anti-caking agent layer. Swelling, increasing the particle volume, thereby reducing the bulk density, reducing the proppant settling velocity, the anionic polymer layer can form a entangled network structure after expansion, with strength and elasticity, and better roundness than ceramsite and quartz sand. The frictional resistance is smaller, and the proppant can be completely suspended in low-viscosity fluid or clear water, so that the proppant migration performance is better, and the sedimentation speed is low, the dust is less, and the width of the sand pile is increased, so that the flow conductivity decreases. Slow down, the proppant can reduce the viscosity demand of the fracturing fluid, avoid the problem of large fluid loss in the fracturin...

Embodiment 2

[0059] In this example, 500g of 40 / 70 mesh fracturing sand was added to the drum of the mixer and heated to 120°C; 200g of tap water and 4g of 1% PDAC solution were added to the sand, vibrated for 5 minutes, vacuum filtered, and dried at 80°C; 20g of EM533 and glycerin Add to the sand at a ratio of 9:1; add 3.3g of fumed silica to the sample and mix again for 30 seconds; turn on the mixer to mix the sand and polymer for 7 minutes, and dry the sample at 85°C for 1 hour; remove from the drying oven Remove the sample and sieve.

Embodiment 3

[0061] In this example, add 500g of 40 / 70 mesh fracturing sand into the drum of the mixer and heat it to 120°C; add 200g of tap water and 0.4g of 1% PDAC solution to the sand, vibrate for 5 minutes, vacuum filter, and dry at 80°C; mix 20g of EM533 and Glycerin was added to the sand at a ratio of 9:1; 3.3g of fumed silica was added to the sample and mixed again for 30 seconds; the mixer was turned on to mix the sand and polymer for 7 minutes, and the sample was dried at 85°C for 1 hour; Remove the sample and sieve.

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Abstract

The invention belongs to the technical field of oil-gas field fracturing production-increase propping agent preparation, and relates to a water acid-sensitivity deformation magnetic tracer function self-suspension propping agent and a preparation method thereof. The propping agent comprises an aggregate and a surface hydration layer, wherein the aggregate is one of magnetic rare earth composite resin, quartz sand or ceramsite and like material; the surface hydration layer is composed of three layers, the innermost layer is a cationic macromolecule inner polymer layer or a modifier layer, the middle layer is an anionic macromolecule outer polymer layer, and the outer layer is anti-caking agent. The propping agent has the acid-sensitivity deformation self-suspension function of producing buoyant force while encountering water and breaking gel to precipitate while encountering the acid, and a tracer function of monitoring flow guiding position of the propping agent through electromagnetic imaging; in the process of exerting the fracturing engineering on shale, compact oil-gas or coal bed base and like argillaceous plasticity micronano hole reservoir, the fracturing liquid with the propping agent has excellent flow guiding characters of suspension sand-adding of non-floating to the roof and not sinking to the bottom; the permeation is improved, the hurt is avoided, the propping agent is efficient and capable of increasing production, the construction cost is lowered, and the application prospect is wide.

Description

Technical field: [0001] The invention belongs to the technical field of proppant preparation for oil and gas field fracturing stimulation, and relates to a self-suspension proppant with water acid-sensitive deformation magnetic tracer function and a preparation method thereof. The self-suspension performance of the proppant is eliminated by the acid-breaking gel precipitation, which is beneficial to the flowback of the fracturing fluid and reduces the reservoir damage; and because the proppant contains electromagnetic rare earth materials, the electromagnetic monitoring and imaging technology can be used to directly describe the position of the fracture where the proppant is located , so that the proppant has a magnetic tracer function; the proppant has characteristics in the tracer function of the composite material formula, the coating preparation process, the gel breaking and flowback construction method, and the electromagnetic imaging monitoring of the position of the prop...

Claims

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Application Information

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IPC IPC(8): C09K8/80
CPCC09K8/805
Inventor 王展旭张鑫王旌舟
Owner 王展旭
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