Preparation method of rare earth transition alloy rotary target for film coating of magneto-optical recording medium and prepared target of rare earth transition alloy rotary target

A magneto-optical recording and rotating target technology, applied in metal material coating process, sputtering coating, ion implantation coating and other directions, can solve the problems of uneven alloy composition, composition segregation, high oxygen content, and reduce the subsequent process. , reduce production costs, overcome the effect of component segregation

Active Publication Date: 2016-07-27
亚芯半导体材料(江苏)有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, vacuum casting and vacuum sintering methods are mainly used to prepare small-sized planar rare earth-transition metal targets. Although the oxygen content is lower than 500ppm during vacuum casting, the alloy composition is uneven and segregation occurs; although the sintering method has uniform composition, the oxygen content Higher than 2000ppm, especially unsuitable for rare earth transition metals that are easily oxidized
In addition, the utilization rate of large planar targets is low, between 20-30%, while the utilization rate of rotating targets reaches 80-90%. Large-size, high-density, high-utilization and low-rotating targets are the future targets development trend
Although the rotating target can be realized by vacuum casting, due to the composition segregation and the brittleness of the rare earth alloy target, it is difficult to prepare a large-size rotating target with uniform composition by casting.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] This embodiment is a method for preparing a (NdDy)(FeCo) rotating target, comprising the following steps:

[0023] (1) Nd23Dy77 (indicating that the atomic ratio of Nd and Dy is 23:77; hereinafter all expressed as such) the rare earth metal alloy block is broken into a particle size of 400 microns, and the Fe80.5Co19.5 transition metal alloy block is broken into a particle size of 200 microns ;Put Nd10, Dy35, Fe44, Co11 (Nd, Dy, Fe, Co atomic ratio is 10:35:44:11) powder into the crucible and heat to 1540°C, keep it warm for 2 hours, then cool down to 1260°C, put Nd23Dy77 and Put the Fe80.5Co19.5 powder into the molten Nd10Dy35Fe44Co11 alloy in the crucible. Since the melting point of the Nd23Dy77 alloy is 1400°C and that of the Fe80.5Co19.5 alloy is 1530°C, they will not melt in the crucible at 1260°C. The original alloying method exists to produce rare earth transition metal alloys.

[0024] (2) Under vacuum, pour the molten rare earth transition metal alloy into a m...

Embodiment 2

[0031] This embodiment is a method for preparing a (PrTb)(FeCo) rotating target, comprising the following steps:

[0032] (1) The Pr30Tb70 rare earth metal alloy block is broken into a particle size of 500 microns, and the Fe65.5Co34.5 transition metal alloy block is broken into a particle size of 250 microns; Pr15, Tb40, Fe25, Co20 powder is put into a crucible and heated to 1570 ° C, Keep warm for 2 hours, then cool down to 1240°C, put Pr23Tb77 and Fe66.5Co34.5 powder into the molten Pr15Tb40Fe25Co20 alloy in the crucible, since the melting point of Pr30Tb70 alloy is 1370°C, and Fe65.5Co34.5 alloy is 1530°C. They will not melt into the crucible at 1240°C, and they still exist in the original alloy form, making rare earth transition metal alloys.

[0033] (2) Under vacuum, pour the molten rare earth transition metal alloy into a mold for molding, and demould after cooling.

[0034] (3) Put the poured target tube into the hot isostatic pressing with argon as the medium, the p...

Embodiment 3

[0040] This embodiment is a method for preparing a (SmGd)(FeCo) rotating target, comprising the following steps:

[0041] (1) The Sm35Gd65 rare earth metal alloy block is broken into a particle size of 550 microns, and the Fe70.5Co29.5 transition metal alloy block is broken into a particle size of 200 microns; Sm12, Gd39, Fe32, Co17 powders are put into a crucible and heated to 1580 ° C, Keep warm for 1.5 hours, then cool down to 1220°C, put Sm35Gd65 and Fe70.5Co29.5 powder into the molten Sm12Gd39Fe32Co17 alloy in the crucible, since the melting point of Sm35Gd65 alloy is 1270°C, and Fe70.5Co29.5 alloy is 1530°C, in They will not melt into the crucible at 1220°C, and still exist in the original alloy form, making rare earth transition metal alloys.

[0042] (2) Under vacuum, pour the molten rare earth transition metal alloy into a mold for molding, and demould after cooling.

[0043] (3) Put the poured target tube into the hot isostatic pressing with argon as the medium, the...

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Abstract

The invention discloses a preparation method of a rare earth-transition alloy rotary target for film coating of a magneto-optical recording medium and a prepared target of the rare earth transition alloy rotary target. The method comprises the steps that rare earth transition metal alloy is prepared; rare earth transition metal alloy hollow target tubes are formed through vacuum pouring; the poured rare earth transition metal alloy target tubes are subjected to hot isostatic pressing; machining is conducted; and indium binding is conducted. The rare earth transition alloy rotary target prepared through the method is even in composition, the relative density can reach 99.9%, the purity can reach 99.99%, the length is not limited, the defects of rotary target composition segregation, high fragility and the like are overcome, the porosity of the target is lowered, and the target is made to stably discharge in the application process, so that the quality of a magneto-optical recording medium thin film is improved. In addition, the method is simple in process and convenient to operate, conventional sheaths and argon arc welding are not needed during hot isostatic pressing, subsequent procedures are reduced, and the target tubes can be directly subjected to hot isostatic pressing, so that the production cost is reduced.

Description

technical field [0001] The invention relates to a target material and target material preparation technology, in particular to a method for preparing a rare earth transition alloy rotating target material for coating a magneto-optical recording medium and the target material. Background technique [0002] Rare earth-transition metal (Nd, Pr, Sm, Ce, Gd, Tb, Dy-Fe, Co) targets are widely used in optical communications, magnetic storage coatings and other fields, which requires rare earth-transition alloy targets with high purity, High density, large size integration and other advantages. At present, vacuum casting and vacuum sintering methods are mainly used to prepare small-sized planar rare earth-transition metal targets. Although the oxygen content is lower than 500ppm during vacuum casting, the alloy composition is uneven and segregation occurs; although the sintering method has uniform composition, the oxygen content Above 2000ppm, it is not suitable for rare earth tran...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/34G11B5/84
CPCC23C14/3414G11B5/84
Inventor 徐从康
Owner 亚芯半导体材料(江苏)有限公司
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