Heat-resistant metallic copper anticorrosion coating and method for preparing same

An anti-corrosion coating, heat-resistant metal technology, applied in anti-corrosion coatings, coatings, etc., can solve the problem of not being able to obtain a super-hydrophobic surface, and achieve the effect of improving hydrophobic performance, strong stability, and excellent comprehensive performance

Inactive Publication Date: 2016-10-26
HEFEI HEAN MACHINERY MFG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, even the smooth solid surface with the lowest surface energy has a contact angle with water of only 119°, therefore, superhydrophobic surfaces cannot be obtained only by reducing the surface energy.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0019] A heat-resistant metal copper anti-corrosion coating, the coating is made up of the following raw materials in parts by weight:

[0020] Bisphenol A phosphite 2, sorbitol 2, vinyltrimethoxysilane 10, 1.8g / l citric acid solution 200, silane coupling agent KBM510313, ethyl orthosilicate 100, hexafluorobutyl acrylate 30, Azobisisobutyronitrile 0.1, 20% ammonia water 5, ferric oxide 4, dimethyl vinyl phosphate 0.2, aluminum ammonium sulfate 1, calcium acetylacetonate 0.5, N-methylpyrrolidone 4, nonylphenol 0.1.

[0021] A preparation method of the heat-resistant metal copper anti-corrosion coating according to claim 1, comprising the following steps:

[0022] (1) Add the above ammonium aluminum sulfate to deionized water 10 times its weight, and stir evenly;

[0023] (2) Add the above iron ferric oxide into 1.8g / l citric acid solution, ultrasonically disperse for 1.7 hours, add the above aluminum ammonium sulfate aqueous solution, keep stirring at 60°C for 10 minutes, filt...

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PUM

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Abstract

The invention discloses a heat-resistant metallic copper anticorrosion coating and a method for preparing the same. The heat-resistant metallic copper anticorrosion coating comprises, by weight, 2-3 parts of bisphenol A phosphite, 2-3 parts of sorbitol, 10-14 parts of vinyl trimethoxy silane, 200-300 parts of 1.8-2 g / l citric acid solution, 13-17 parts of silane coupling agents KBM5103, 100-110 parts of tetraethoxysilane, 30-37 parts of hexafluorobutyl acrylate, 0.1-0.14 part of azodiisobutyronitrile, 5-7 parts of 20-25% ammonia water, 4-5 parts of ferriferous oxide, 0.2-0.4 part of dimethyl vinyl phosphate ester, 1-2 parts of aluminum ammonium sulfate, 0.5-1 part of calcium acetylacetonate, 4-5 parts of N-methyl pyrrolidone and 0.1-0.2 part of nonylphenol. The heat-resistant metallic copper anticorrosion coating has the advantages that hybrid coating surfaces with different morphological structures can be formed by the heat-resistant metallic copper anticorrosion coating; the coating surfaces which are of different structures can be combined with exposed ethylene groups with low surface energy, and accordingly the heat-resistant metallic copper anticorrosion coating has a super-hydrophobic characteristic.

Description

technical field [0001] The invention relates to the technical field of metal anticorrosion, in particular to a heat-resistant metal copper anticorrosion coating and a preparation method thereof. Background technique [0002] In recent years, with the enhancement of people's awareness of environmental protection, traditional metal coating protection or surface treatment methods are facing severe challenges. For example, although electroplating can form a uniform and dense protective layer, the electroplating process will generate a lot of waste water, waste gas and waste residue , which contains highly toxic substances such as heavy metal chromium and cyanate, which poses a serious threat to the environment; and the metal surface phosphating treatment technology, the sediment and phosphate produced by the phosphating process are likely to cause rich oxidation of water quality, nitrite, Water pollution by heavy metal ions also requires new surface treatment methods. In recent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D151/10C09D5/08C09D7/12C08F292/00C08F220/22
CPCC08F292/00C08K3/22C08K9/04C08K2003/2275C08K2201/011C08L2201/08C09D5/08C09D7/61C09D7/62C09D7/65C09D151/10C08F220/22
Inventor 沈先明牛保余海飞杨辉黄胜
Owner HEFEI HEAN MACHINERY MFG
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