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Preparation method of two-component automotive cathodic electrophoretic coating and preparation method thereof

A cathodic electrophoretic coating, two-component technology, applied in the field of coatings, can solve the problems of high toxicity, reduce energy consumption, and environmental protection, and achieve the effect of strong coating ability, good uniformity, and high thermal stability

Inactive Publication Date: 2016-11-02
GUANGDE ZHONGYIN CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Low-temperature curing cathodic electrophoretic coatings are not only beneficial to the coating of auto parts with plastic and rubber, but also can greatly reduce energy consumption. The organic lead and tin catalysts commonly used in cathodic electrophoretic coatings in the past have disadvantages such as high toxicity and environmental protection. Already restricted in Europe and developed countries

Method used

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  • Preparation method of two-component automotive cathodic electrophoretic coating and preparation method thereof

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Embodiment 1

[0032] A two-component automotive cathodic electrophoretic coating, comprising, in parts by mass, 1 part of color paste, 6 parts of emulsion and 5 parts of deionized water;

[0033] The color paste formula includes 20 parts of water-based cationic epoxy resin, 20 parts of pigment and filler, 10 parts of solvent, 0.5 part of non-toxic drier, 0.5 part of dispersant, and 30 parts of deionized water;

[0034] The emulsion formula includes, 40 parts of modified epoxy resin A, 10 parts of modified epoxy resin B, 10 parts of curing agent, 3 parts of diketimine of diethylenetriamine and 2 parts of N-methylethanolamine , 0.1 part of emulsifier, 0.1 part of acetic acid and 30 parts of deionized water; the modified epoxy resin A formula includes, 10 parts of bisphenol A, 40 parts of epoxy resin, 8 parts of solvent, 4 parts of bisphenol A polyoxygen Vinyl ether, 10 parts of polyether diols with a number average molecular weight of 400-1500; the modified epoxy resin B formula includes 10 p...

Embodiment 2

[0040] A two-component automotive cathodic electrophoretic paint, comprising, in parts by mass, 2 parts of color paste, 6 parts of emulsion and 7 parts of deionized water;

[0041] The color paste formula includes 30 parts of water-based cationic epoxy resin, 40 parts of pigments and fillers, 20 parts of solvent, 1.5 parts of non-toxic drier, 2 parts of dispersant, and 50 parts of deionized water;

[0042] The emulsion formula includes, 50 parts of modified epoxy resin A, 20 parts of modified epoxy resin B, 30 parts of curing agent, ketimine of 4 parts of aminoethylethanolamine and 3 parts of diethanolamine, 2 parts of emulsifier, 1 part of acetic acid and 50 parts of deionized water; the modified epoxy resin A formula includes, 20 parts of bisphenol A, 60 parts of epoxy resin, 16 parts of solvent, 16 parts of bisphenol A polyoxypropylene ether, 35 parts A polyether diamine with an average molecular weight of 400-1500; the modified epoxy resin B formula includes 20 parts of bi...

Embodiment 3

[0048] A two-component automotive cathodic electrophoretic coating, comprising, in parts by mass, 1 part of color paste, 5 parts of emulsion and 6 parts of deionized water;

[0049] The color paste formula includes 35 parts of water-based cationic epoxy resin, 25 parts of pigment and filler, 15 parts of solvent, 0.7 part of non-toxic drier, 1 part of dispersant, and 40 parts of deionized water;

[0050] The emulsion formula includes, 45 parts of modified epoxy resin A, 15 parts of modified epoxy resin B, 20 parts of curing agent, ketimine of 4 parts of aminoethylethanolamine and 3 parts of diethanolamine, 0.8 part of emulsifier, 0.5 parts of acetic acid and 40 parts of deionized water; the modified epoxy resin A formula includes, 15 parts of bisphenol A, 50 parts of epoxy resin, 12 parts of solvent, 10 parts of bisphenol A polyoxypropylene ether, 25 parts of A polyether diamine with an average molecular weight of 400 to 1500; the modified epoxy resin B formula includes 15 part...

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Abstract

The invention relates to the field of coating, specifically to a preparation technology of a two-component automotive cathodic electrophoretic coating. The formula of the electrophoretic coating contains, by weight, 40-50 parts of modified epoxy resin A, 10-20 parts of modified epoxy resin B, 10-30 parts of a curing agent, 3-8 parts of single molecular amine, 0.1-2 parts of an emulsifier, 0.1-2 parts of a neutralizer and 30-50 parts of deionized water. The formula of the modified epoxy resin A contains, by weight, 10-20 parts of bisphenol A, 40-60 parts of epoxy resin, 8-16 parts of a solvent, 4-16 parts of a plasticizer and 10-35 parts of a flexible polymer. The formula of the modified epoxy resin B contains, by weight, 10-20 parts of bisphenol-F, 40-60 parts of epoxy resin, 5-10 parts of nonylphenol, 2-6 parts of xylene and 0.1-1 part of triphenyl phosphite. The formula of the curing agent contains, by weight, 20-66 parts of dimer fatty acid, 5-18 parts of vegetable oleic acid, 5-25 parts of fatty amine, 10-34 parts of ketone, 5-20 parts of ethers and 0.01-0.02 part of a terminating agent.

Description

technical field [0001] The invention relates to the field of coatings, in particular to a preparation process of a two-component automotive cathode electrophoretic coating. Background technique [0002] Since the advent of cathodic electrophoretic coatings, because the formed paint film has excellent corrosion resistance, mechanical properties, and is suitable for automatic coating, it has quickly become popular in the automotive industry. The baking temperature range of traditional cathodic electrophoretic coatings is generally 170 ~180°C. At present, many industrial workpieces are made of rubber, plastic and other materials, which are required to be dried together with electrophoretic coating after processing, so as to reduce the operating intensity of workers and control costs. However, such materials are easily deformed or melted when baked under high temperature conditions. In order to meet the needs of this type of process, there are very few varieties of low-tempera...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D7/12C09D5/44C08G59/14
CPCC09D163/00C08G59/1438C08G59/1488C08L2205/025C08L2205/035C09D5/4434C09D5/4438C09D5/4453C09D7/61C09D7/63
Inventor 彭德琼
Owner GUANGDE ZHONGYIN CHEM
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