Preparation method of anti-aging polypropylene fiber

A polypropylene fiber, anti-aging technology, applied in fiber chemical characteristics, rayon manufacturing, conjugated synthetic polymer rayon, etc., can solve the problems of poor thermal stability, easy ash absorption, airtight and other problems

Active Publication Date: 2016-11-16
ZHEJIANG MODERN TEXTILE IND RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The abrasion resistance of polypropylene fiber is second only to that of polyamide fiber, and it has good corrosion resistance, especially for inorganic acid and alkali stability, no mildew, no rot, and no fear of insects, etc. , such as various furniture cloths, decorative cloths, advertising cloths, carpets, bags, tents, geotextiles, cables, fishing equipment, packaging materials and filter cloths, etc., but polypropylene fibers do not absorb water, are difficult to dye, and have a lot of static electricity. And low temperature, due to the high regularity of its molecular structure, so the impact strength is poor
Polypropylene fiber is very sensitive to ultraviolet rays, easy to age, and has poor flame resistance. Due to its non-hygroscopic, airtight, uncomfortable, poor thermal stability, and easy to absorb dust, it is not suitable for clothing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Embodiment 1: a kind of preparation method of antiaging polypropylene fiber, adopt following steps:

[0028] A) According to the number of parts by mass, take 0.8 parts of wollastonite needle-shaped fibers with an aspect ratio of 14:1, 0.5 parts of laurylamine polyoxyethylene ether, 0.6 parts of rutile titanium dioxide, and 0.2 parts of characteristic parameters with a diameter of 0.5 μm and a length of 5 μm aluminum borate whiskers, 0.3 parts of characterization parameters of 0.5 μm long, 0.01 μm wide concave-convex rod crystals, 4.0 parts of 20% sodium bicarbonate aqueous solution, 0.2 parts of nano-montmorillonite, mixed with superheated steam at 150 ° C Stir and steam in the reaction kettle for 45 minutes, irradiate with vacuum microwave at 300°C for 2h, then immerse in 80 parts of 30% sulfamic acid solution for vacuum moisture absorption treatment, heat to 60°C and ultrasonically disperse for 0.5h after absorption, and then Stir and disperse for 2 hours, take the s...

Embodiment 2

[0032] Embodiment 2: a kind of preparation method of antiaging polypropylene fiber, adopt following steps:

[0033] A) According to the number of parts by mass, 1.0 parts of wollastonite needle-like fibers with an aspect ratio of 15:1, 0.75 parts of laurylamine polyoxyethylene ether, 0.6 parts of rutile titanium dioxide, and 0.3 parts of characterization parameters have a diameter of 0.75 μm and a length of 15 μm of aluminum borate whisker, 0.4 parts of characterization parameter length of 2.5 μm, width of 0.05 μm concave-convex rod crystal, 5..0 parts of sodium bicarbonate aqueous solution with a mass fraction of 25%, 0.3 parts of nano-montmorillonite mixed, at 160 Stir and steam in a superheated steam reactor at ℃ for 50min, irradiate with vacuum microwave at 350℃ for 3h, then immerse in 100 parts of sulfamic acid solution with a mass fraction of 30% for vacuum moisture absorption treatment, heat to 75℃ after absorption and ultrasonically disperse for 1h , then stir and disp...

Embodiment 3

[0037] Embodiment 3: a kind of preparation method of antiaging polypropylene fiber, adopt following steps:

[0038] A) According to the number of parts by mass, take 1.2 parts of wollastonite needle-shaped fibers with an aspect ratio of 16:1, 1.0 parts of laurylamine polyoxyethylene ether, 1.0 parts of rutile titanium dioxide, and 0.4 parts of characterization parameters. The diameter is 1 μm and the length is 20 μm. Aluminum borate whiskers, 0.5 parts of characterization parameters are 5 μm long, 0.10 μm wide as concave-convex rod crystals, 6.0 parts of 30% sodium bicarbonate aqueous solution, 0.4 parts of nano-montmorillonite, mixed in a superheated steam reactor at 170 ° C Internal stirring and steaming reaction for 60min, vacuum microwave irradiation at 400°C for 4h, then immerse in 120 parts of 30% sulfamic acid solution for vacuum moisture absorption treatment, after absorption, heat to 95°C for ultrasonic dispersion for 1.5h, then stir to disperse 4h, take the suspensio...

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Abstract

The invention relates to a preparation method of anti-aging polypropylene fiber, and belongs to the technical field of functional fiber preparation. According to the method, wollastonite raphioid fiber, aluminum borate whisker, concave-convex rod crystals, sodium bicarbonate water solution and nano-montmorillonite are mixed and stirred; then, the materials are soaked into a sulfamic acid solution for heating, stirring and dispersing; suspended solids are taken to be subjected to ultrasonic treatment; then, upper layer suspended solids are taken to be filtered, washed and dried; obtained materials are mixed with the aluminum borate whisker, PP-g-MAH, silane coupling agents, ultraviolet absorbents, light stabilizers and antioxidants; the obtained mixture is stirred and dried; isotatic polypropylene is added; the mixture is stirred; fusion compounding is performed to prepare the anti-aging polypropylene fiber. The preparation method has the advantages that the defects in the prior art are overcome; the aluminum borate whisker, the PP-g-MAH, the wollastonite raphioid fiber, the ultraviolet absorbents, the light stabilizers and the antioxidants are added in the isotactic polypropylene; the blending fusion is performed with the isotactic polypropylene to prepare the sheath core type anti-aging polypropylene fiber using the anti-aging polypropylene as a sheath layer.

Description

technical field [0001] The invention relates to a preparation method of anti-aging polypropylene fiber, which belongs to the technical field of functional fiber preparation. Background technique [0002] Polypropylene fiber or PP fiber is a fiber melt-spun from isotactic polypropylene. Its biggest advantage is light weight and a density of 0.91 / cm 3 , 20-30% lighter than ordinary chemical fibers, is the smallest specific gravity of all textile fibers, high strength, large elongation, high initial modulus, and excellent elasticity. The abrasion resistance of polypropylene fiber is second only to that of polyamide fiber, and it has good corrosion resistance, especially for inorganic acid and alkali stability, no mildew, no rot, and no fear of insects, etc. , such as various furniture cloths, decorative cloths, advertising cloths, carpets, bags, tents, geotextiles, cables, fishing equipment, packaging materials and filter cloths, etc., but polypropylene fibers do not absorb wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/06D01F1/10
CPCD01F1/10D01F1/106D01F8/06
Inventor 凌文嘉
Owner ZHEJIANG MODERN TEXTILE IND RES INST
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