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Preparation method of lithium ion battery pole piece

A lithium ion battery and pole piece technology is applied in the field of preparation of lithium ion battery pole pieces, and can solve the problems of low area utilization rate of current collector 12, reduced battery pole piece area utilization rate, low volume energy density of lithium ion battery, etc. Achieve the effect of reducing increase, low battery internal resistance, and high volumetric energy density

Active Publication Date: 2016-11-23
NINGDE AMPEREX TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the fabrication of electrode sheets in this assembly method, a certain length is usually reserved at the end of the current collector 12, and a blank area that is not coated with the active material membrane layer 11 is welded to the blank area of ​​the current collector 12. area, thus resulting in a reduction in the utilization rate of the battery electrode area
Taking a thin lithium-ion battery with a thickness of 1.0mm, a width of 66mm, and a length of 125mm as an example, the battery pole piece with the above-mentioned traditional winding structure has a ratio of the area of ​​the positive electrode active material membrane layer to the area of ​​the positive electrode current collector aluminum foil. %, it can be seen that the area utilization of the current collector 12 is very low, which in turn leads to a low volumetric energy density of the lithium-ion battery

Method used

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  • Preparation method of lithium ion battery pole piece
  • Preparation method of lithium ion battery pole piece
  • Preparation method of lithium ion battery pole piece

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] 1) Install a single-sided automatic glue-applying mechanism between the unwinding and coating head of the extrusion coating machine, and automatically paste a 25mm wide, 10mm long, and 70μm thick glue on the fixed position of the current collector according to the designed coating size. Thermally expandable foam release acrylic pressure sensitive tape. In the heat-expandable foamable peelable acrylate pressure-sensitive adhesive tape used: the thickness of the heat-expandable foamable peelable acrylate pressure-sensitive adhesive is 50 μm, the particle size of the expanded foamed microspheres is 20-40 μm, and the foaming expansion temperature is at 100-130°C, the volume expansion of the expanded microspheres is 50-150 times during the thermal foaming process; the thickness of the matrix resin film is 20 μm, and the matrix resin film is polyester polyethylene terephthalate; this The peeling strength of the pressure-sensitive adhesive tape to copper foil or aluminum foil ...

Embodiment 2

[0041] Using the same automatic glue-applying mechanism, the heat-expandable foaming peelable acrylic pressure-sensitive tape is pre-attached to one side of the positive electrode current collector or the negative electrode current collector according to the above size. Then carry out the extrusion coating of positive electrode active material slurry or negative electrode active material slurry. After the coated film enters the oven for drying, use the temperature of the oven (80-150° C.) to thermally foam and peel off the adhesive tape to realize heating. Foaming and removing the slurry coated on the upper layer, so as to realize the welding hollow area reserved for the single membrane sheet layer, and the welding hollow area of ​​the symmetrical surface is implemented in the same way. The difference between this embodiment and embodiment 1 is: embodiment 1 is coating while pasting glue, and this embodiment is pasting film in advance, and then coating.

Embodiment 3

[0043] 1) Spray or print a heat-expandable foaming peelable acrylate adhesive equal to the area of ​​the preset hollowed-out area on the corresponding positions of the positive and negative current collectors. Among them, the thickness of the heat-expandable foamable peelable acrylate adhesive is 70 μm, the particle size of the foamed and expanded microspheres is 20-40 μm, and the expansion temperature of the expanded microspheres is 100-130° C. The multiple is 50 to 150 times, and the peel strength of the adhesive layer to copper foil or aluminum foil at room temperature is ≥10N / m.

[0044] 2) to 4) are the same as in Example 1.

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Abstract

The invention provides a preparation method of a lithium ion battery pole piece. The preparation method comprises the following steps: 1) providing a current collector, and sticking a thermal expansion foaming pressure sensitive adhesive tape or coating a thermal expansion forming adhesive at the preset position of a plug on the current collector, and forming a peelable adhesive sheet; 2) coating an active substance sizing agent on the current collector, and forming an active substance diaphragm layer; 3) drying the active substance diaphragm layer under the foaming expansion temperature of the adhesive sheet, carrying out thermal expansion foaming on the adhesive sheet in a drying process so as to be separated from the current collector, and forming an active substance hollow-out area in which the diaphragm layer is not covered with active substances on the current collector; and 4) fixing the lug on the current collector that the active substance hollow-out area is exposed out to obtain the required pole piece. Compared with the prior art, the pole piece prepared by the preparation method makes full use of the area of the current collector, and the increase of battery thickness is reduced, so that a lithium ion battery prepared by using the pole piece has relatively high volume energy density and relatively low battery internal resistance.

Description

technical field [0001] The invention relates to the field of lithium ion batteries, more specifically, to a preparation method of lithium ion battery pole pieces. Background technique [0002] Since the promotion of commercialization, lithium-ion batteries have been widely used as a variety of portable batteries due to their advantages such as high energy density, high working voltage, long cycle life, no memory effect, green environmental protection, and flexible design of size and shape according to actual needs. The power supply of electronic appliances; these broad application fields and various actual needs have in turn greatly promoted the development of lithium-ion batteries. [0003] The rapid development of mobile electronic and electrical equipment requires lithium-ion batteries that provide power for these thin, portable and powerful devices to have higher capacity (ie, volumetric energy density); however, the energy density and operating voltage of lithium-ion ba...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/139H01M4/04
CPCH01M4/0404H01M4/0471H01M4/139Y02E60/10
Inventor 平翔张文广沈华光陶兴华张盛武程文强耿继斌
Owner NINGDE AMPEREX TECH
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