Graphene compounded anti-impact PP (Polypropylene) plastic and preparation method thereof

A graphene composite and impact-resistant technology, which is applied in the field of plastic modification and its preparation, can solve problems such as poor aging resistance, large molding shrinkage, and poor dimensional stability, and achieve good impact resistance and cold and heat resistance. Improvement of bending performance and tensile performance, and improvement of poor low-temperature impact resistance

Inactive Publication Date: 2017-01-04
XIAMEN RUNNER IND CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

PP also has many shortcomings: low-temperature brittleness, poor dimensional stability, poor aging resistance, and large molding shrinkage, easy to burn, and because of its non-polar characteristics, it is not easy to effectively combine with other polar polymers and inorganic fillers. Compatibility, which limits the application and development of PP

Method used

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  • Graphene compounded anti-impact PP (Polypropylene) plastic and preparation method thereof
  • Graphene compounded anti-impact PP (Polypropylene) plastic and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0023] A graphene composite impact-resistant PP plastic, consisting of the following components in parts by weight: PP 70 parts, 50 wt% tetrakis [β-(3,5-tertiary butyl-4-hydroxyphenyl) propionate] pentaerythritol ester and 0.3 part of 50 wt% dilauryl thiodipropionate, 0.8 part of polyethylene wax, 0.5 part of 1-vinyltrimethoxysilane, and 1 part of graphene oxide.

[0024] The preparation method of described graphene composite impact-resistant PP plastic, comprises the following steps:

[0025] 1. Preparation of graphene oxide: Add 2.0g of graphite and 10g of potassium permanganate to 150-200ml of concentrated sulfuric acid with a mass concentration of 98% and 10-30ml of concentrated phosphoric acid with a mass concentration of 65% and stir for reaction 12 -24h, then add 5-10ml of hydrogen peroxide with a mass concentration of 30%, continue to stir for 30-60min, vacuum filter, and then place in a vacuum drying oven to dry for 24-48h to prepare graphene oxide.

[0026] 2. Mix 1...

Embodiment 2

[0030] A graphene composite impact-resistant PP plastic, consisting of the following components in parts by weight: PP 70 parts, 50 wt% tetrakis [β-(3,5-tertiary butyl-4-hydroxyphenyl) propionate] pentaerythritol ester And 0.3 parts of 50wt% dilauryl thiodipropionate, 0.8 parts of polyethylene wax, 1 part of aminopropyltrimethoxysilane, and 2 parts of graphene oxide.

[0031] The preparation method of described graphene composite impact-resistant PP plastic, comprises the following steps:

[0032] 1. Preparation of graphene oxide: Add 2.0g of graphite and 10g of potassium permanganate to 150-200ml of concentrated sulfuric acid with a mass concentration of 98% and 10-30ml of concentrated phosphoric acid with a mass concentration of 65% and stir for reaction 12 -24h, then add 5-10ml of hydrogen peroxide with a mass concentration of 30%, continue to stir for 30-60min, vacuum filter, and then place in a vacuum drying oven to dry for 24-48h to prepare graphene oxide.

[0033] 2. M...

Embodiment 3

[0037] A graphene composite impact-resistant PP plastic, consisting of the following components in parts by weight: PP 70 parts, 50 wt% tetrakis [β-(3,5-tertiary butyl-4-hydroxyphenyl) propionate] pentaerythritol ester and 0.3 parts of 50 wt% dilauryl thiodipropionate, 1.5 parts of white oil, 1 part of 1-vinyltrimethoxysilane, and 2 parts of graphene oxide.

[0038] The preparation method of described graphene composite impact-resistant PP plastic, comprises the following steps:

[0039] 1. Preparation of graphene oxide: Add 2.0g of graphite and 10g of potassium permanganate to 150-200ml of concentrated sulfuric acid with a mass concentration of 98% and 10-30ml of concentrated phosphoric acid with a mass concentration of 65% and stir for reaction 12 -24h, then add 5-10ml of hydrogen peroxide with a mass concentration of 30%, continue to stir for 30-60min, vacuum filter, and then place in a vacuum drying oven to dry for 24-48h to prepare graphene oxide.

[0040] 2. Mix 2 parts...

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Abstract

The invention discloses graphene compounded anti-impact PP (Polypropylene) plastic. The graphene compounded anti-impact PP plastic is prepared from the following components in parts by weight: 70-80 parts of PP, 0.2-0.6 part of an antioxidant, 0.5-2 parts of a lubricant, 0.5-3 parts of a coupling agent and 1-3 parts of graphene oxide. The invention further discloses a preparation method of the graphene compounded anti-impact PP plastic. By adopting the graphene compounded anti-impact PP plastic, the impact strength of the PP plastic is high and the graphene compounded anti-impact PP plastic has a good anti-ageing performance.

Description

technical field [0001] The invention relates to the technical field of plastic modification and preparation thereof, in particular to a graphene composite impact-resistant PP plastic and a preparation method thereof. Background technique [0002] Polypropylene (PP) is polymerized from propylene monomer and belongs to a non-polar crystalline plastic with a very low water absorption rate of about 0.03%-0.04% and a melting point of 165-170°C. PP is a thermoplastic general-purpose plastic with excellent comprehensive properties, with a small density of about 0.91g / cm 3 , high strength and high temperature corrosion resistance, as well as good transparency and electrical insulation, PP is widely used in many fields such as industry, agriculture, medical treatment, daily necessities and packaging. PP also has many shortcomings: low temperature brittleness, poor dimensional stability, poor aging resistance, and large molding shrinkage, easy to burn. Compatibility limits the appli...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L91/00C08L27/18C08K13/06C08K9/06C08K3/04C08K5/134
CPCC08L23/12C08L2201/08
Inventor 金碧孙昇凌黄贤明李明仁
Owner XIAMEN RUNNER IND CORP
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