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Gallium nitride-based light-emitting diode and preparation method thereof

A light-emitting diode and gallium nitride-based technology, applied in the field of ion beams, can solve problems such as the ratio error between gallium and nitrogen elements in thin films, the problems that need to be improved, and the damage to the structure of gallium nitride semiconductor films, etc., to achieve uniform thickness, high precision, The effect of overcoming the ratio error

Active Publication Date: 2018-04-27
北京埃德万斯离子束技术研究所股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the surface of the gallium nitride semiconductor film obtained by the commonly used high-temperature vacuum environment preparation process is prone to structural damage, and the comprehensive properties such as uniformity and roughness need to be improved.
In addition, there is an error in the proportion of gallium and nitrogen in the film, and the lack of nitrogen is more

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  • Gallium nitride-based light-emitting diode and preparation method thereof
  • Gallium nitride-based light-emitting diode and preparation method thereof
  • Gallium nitride-based light-emitting diode and preparation method thereof

Examples

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preparation example Construction

[0049] The preparation method of the gallium nitride semiconductor thin film provided by the present invention adopts dual ion sources to bombard the gallium-containing target 3 and the substrate 8 respectively. Among them, argon (Ar) is filled in the main ion source 1 to generate argon (Ar + ) ion beam 2 bombards the gallium-containing target 3 , and the sputtered particles 5 generated are deposited on the substrate 8 . At the same time, ammonia gas (NH 3 ) or nitrogen (N 2 ), producing nitrogen (N + ) ion beam 7 bombards the surface of substrate 8, wherein nitrogen ions (N + ) combined with the sputtered particles 5 deposited on the surface of the substrate 8 to form a gallium nitride semiconductor thin film. The gallium-containing target 3 contains gallium element, so gallium atoms in the sputtered particles 5 can chemically react with nitrogen ions to form gallium nitride. Preferably, the gallium-containing target 3 also contains group IIIA elements or other elements....

no. 1 example

[0064] see figure 2 , is a structural schematic diagram of the first embodiment of the GaN-based light-emitting diode according to the present invention. Such as figure 2 As shown, the gallium nitride-based light emitting diode is a vertical structure light emitting diode. Correspondingly, the first embodiment of the preparation method of the GaN-based light-emitting diode provided by the present invention includes the following steps:

[0065] 1) A substrate 8 is provided, and gold targets, gallium-silicon targets, gallium-aluminum targets, gallium-indium targets, gallium-magnesium targets, and silicon dioxide targets are provided. The preferred compositions of these six targets are shown in Table 2.

[0066] Form 2

[0067]

[0068] In an environment with a temperature ≦28°C, fix the following 6 types of targets with a diameter of 100mm and a thickness of 3mm on the 1#~6# target positions of the six-target stage respectively. A substrate 8 with a thickness of 400 n...

no. 3 example

[0104] see Figure 4 , is a schematic structural diagram of a third embodiment of a GaN-based light-emitting diode according to the present invention. Such as Figure 4 As shown, the GaN-based light-emitting diode is a flip-chip light-emitting diode. Correspondingly, the third embodiment of the method for manufacturing a GaN-based light-emitting diode provided by the present invention includes the following steps:

[0105] 1) Provide sapphire 19, and provide gold targets, gallium-silicon targets, gallium-aluminum targets, gallium-indium targets and gallium-magnesium targets. The preferred compositions of these five targets are shown in Table 4.

[0106] Form 4

[0107]

[0108] 2) Select the gallium magnesium target, use the patterned p-GaN photoresist as a mask, and generate Ar from the main ion source 1 + The ion beam 2 bombards the GaMg target, and the auxiliary ion source 6 produces N + The ion beam 7 bombards the surface of the sapphire 19 , and the p-GaN film 13...

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Abstract

The invention relates to a gallium nitride semiconductor film, a gallium nitride-based light emitting dioxide and a corresponding preparation method therefor. The preparation method for the gallium nitride semiconductor film comprises the following steps of: bombarding a gallium-containing target and a substrate by using double ion sources, respectively, and filling the primary ion source with argon to generate argon ion beams to bombard the gallium-containing target and generate sputtering particles which are deposited on the substrate; and filling the secondary ion source with ammonia or nitrogen to generate nitrogen ions to bombard the surface of the substrate, wherein the nitrogen ions are combined with the sputtering particles deposited on the surface of the substrate to generate the gallium nitride semiconductor film. According to the invention, the primary ion source generates the argon ions to bombard the gallium-containing target and the nitrogen ions generated by the secondary ion source generate gallium nitride by virtue of a chemical reaction, and the nitrogen ions are directly supplemented to the surface of the substrate by way of shallow injection, so that the content of element nitrogen in the gallium nitride semiconductor film can be effectively improved, and the proportioning error of the element nitrogen and the element gallium is overcome, and the prepared thin is uniform in thickness and high in precision.

Description

technical field [0001] The invention relates to the technical field of ion beams, in particular to a gallium nitride semiconductor thin film and a preparation method, and a gallium nitride-based light-emitting diode and a preparation method. Background technique [0002] Thin film materials can be divided into: superconducting thin film, conductive thin film, semiconductor thin film, dielectric thin film, resistive thin film, optical thin film, photoelectric thin film, piezoelectric thin film, pyroelectric thin film, ferroelectric thin film and magnetic thin film, etc. Basic materials for emerging technologies. Group III element nitride films such as aluminum nitride (AlN) and gallium nitride (GaN) have become the next generation of cadmium (Ge), silicon (Si) semiconductors and the second generation of gallium arsenide (GaAs), indium phosphide Representative of the third generation of semiconductor materials after (InP) compound semiconductors. This nitride film can be div...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/04C23C14/06C23C14/34H01L33/00H01L33/32
CPCC23C14/042C23C14/0617C23C14/3442H01L33/007H01L33/32
Inventor 刁克明
Owner 北京埃德万斯离子束技术研究所股份有限公司