Porphyry copper molybdenum ore copper molybdenum flotation process

A copper-molybdenum ore and flotation technology, used in flotation, solid separation and other directions, can solve the problems of short structure, difficult separation of copper-molybdenum-sulfur mixed concentrate, and difficult separation of copper and molybdenum.

Inactive Publication Date: 2017-02-22
CHANGCHUN GOLD RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The recovery rate of copper and molybdenum in the mixed concentrate obtained by the full mixed flotation process is relatively high, and the main process structure is also short, but it is difficult to separate the mixed concentrate of copper, molybdenum and sulfur, and the content of valuable metals in each concentrate is high; some preferential flotation processes The process is suitable for ores with low copper content and can be desulfurized in advance, but there are still difficulties in separating copper and molybdenum; the traditional equal-floatable process is often difficult to create a favorable environment for molybdenum flotation, and the obtained copper-molybdenum mixed concentrate contains less copper. High, not conducive to the subsequent separation of copper and molybdenum, copper flotation is often due to insufficient collection capacity of the collector, resulting in low recovery of copper minerals

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1 takes a porphyry-type copper-molybdenum ore in Inner Mongolia as an ore sample, the raw ore copper grade is 0.31%, and the molybdenum grade is 0.032%, which specifically includes the following steps:

[0015] (1) Grind the raw ore sample until the content of -0.074mm accounts for 62%, the concentration of the pulp is 38%, and the pH of the lime is adjusted to 7. Add kerosene and diesel combination agents according to the amount of 0.08‰ of the solid mass in the pulp, and terpineol oil in the pulp The amount of 0.04‰ of the solid mass is added, and the copper-molybdenum mixed concentrate is obtained by using a conventional flotation process.

[0016] (2) re-slurry the tailings obtained in step (1): add butyl xanthate in an amount of 0.10‰ of the solid mass in the pulp, add terpineol oil in an amount of 0.03‰ of the solid mass in the pulp, and use conventional floating Copper flotation in the selection process to obtain copper concentrate.

[0017] In the fi...

Embodiment 2

[0019] The ore processed in this embodiment comes from a porphyry-type copper-molybdenum mine in Heilongjiang, the ore copper grade is 0.52%, and the molybdenum grade is 0.012%, which specifically includes the following steps:

[0020] (1) Grind the raw ore sample until the content of -0.074mm accounts for 68%, the concentration of the pulp is 35%, adjust the pH of the lime to 7.5, add kerosene and diesel combination agents according to the amount of 0.10‰ of the solid mass in the pulp, and terpineol oil in the pulp The amount of 0.02‰ of the solid mass is added, and the copper-molybdenum mixed concentrate is obtained by using a conventional flotation process.

[0021] (2) the tailings that step (1) is obtained re-slurry: add the compound agent of butyl xanthate and butylamine black medicine in the amount of 0.08‰ of solid mass in the ore pulp, terpineol oil presses the solid mass in the ore pulp Add in the amount of 0.02‰, adopt conventional flotation process to flotation cop...

Embodiment 3

[0024] Taking a certain porphyry-type copper-molybdenum ore in Tibet as the ore sample, the raw ore copper grade is 0.47%, and the molybdenum grade is 0.023%. The specific steps are as follows:

[0025] (1) Grind the raw ore sample until the content of -0.074mm accounts for 65%, the concentration of the pulp is 30%, adjust the pH of the lime to 8, add kerosene and diesel combination agents according to the amount of 0.06‰ of the solid mass in the pulp, and terpineol oil in the pulp Add in an amount of 0.03‰ of the solid mass, and use a conventional flotation process to obtain a copper-molybdenum mixed concentrate.

[0026] (2) re-slurry the tailings obtained in step (1): add butyl xanthate in an amount of 0.05‰ of the solid mass in the pulp, add terpineol oil in an amount of 0.02‰ of the solid mass in the pulp, and use conventional floating Copper flotation in the selection process to obtain copper concentrate.

[0027] In the finally obtained copper-molybdenum mixed concentr...

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Abstract

The invention discloses a porphyry copper molybdenum ore copper molybdenum flotation process. The porphyry copper molybdenum ore copper molybdenum flotation process is characterized by comprising the following steps: under the fineness of -0.074 mm content of 60-70%, the mass percentage concentration of pulp is within 25-40%; lime is added to adjust the pulp system pH in a low-alkalinity range of 7-8.5; a molybdenum mineral capturing agent being 0.005-0.012% of the solid mass in the pulp is added; the flotation is performed for molybdenum ore and one part of copper ore to obtain a copper molybdenum mixed concentrate for separation; flotation tailing is added with a copper mineral capturing agent being 0.004-0.010% of the solid mass in the pulp; and the flotation is performed for the remained copper ore to obtain a copper concentrate. The natural flotability of the molybdenum mineral is fully exerted through low-alkalinity condition; the recovery of the molybdenum mineral is facilitated; the molybdenum ore capturing agent with good selectivity is added to reduce the flotation rate of the copper mineral; the separation of the mixed concentrate is facilitated; the inhibitor use level in the copper mineral in the separation process is reduced; the mutual contents of the copper and molybdenum minerals in copper and molybdenum concentrate products are effectively reduced; and the copper mineral capturing agent with good capturing performance is added in copper flotation to guarantee the recovery rate of the copper mineral.

Description

technical field [0001] The invention belongs to the technical field of mineral processing, and in particular relates to a copper-molybdenum flotation process of porphyry-type copper-molybdenum ore. Background technique [0002] Porphyry-type copper-molybdenum deposits are the main source of output of copper-molybdenum ore and the main way to obtain copper-molybdenum metal. In the process of beneficiation, the comprehensive recovery of copper and molybdenum should be considered. [0003] Copper-molybdenum ore beneficiation methods include gravity separation, magnetic separation, flotation and flotation-magnetic separation-gravity separation combined method, among which flotation is the most widely used. Different technological processes in flotation have different effects on mineral processing indicators such as the grade and recovery rate of copper and molybdenum minerals. The recovery rate of copper and molybdenum in the mixed concentrate obtained by the full mixed flotati...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/012B03D101/02B03D103/02
CPCB03D1/012B03D2201/02B03D2203/04
Inventor 逄文好赵明福郑晔郝福来宋超
Owner CHANGCHUN GOLD RES INST
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