Method for detoxicating chrome leaching residues through sintering technology

A technology for leaching slag and technology, which is applied in the detoxification field of chromium leaching slag, can solve the problems of large consumption of raw materials, high processing cost, and low detoxification efficiency, and achieve the effects of low production energy consumption, high detoxification efficiency, and cost saving

Active Publication Date: 2017-03-15
CITIC JINZHOU METAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Even if the anti-seepage treatment is adopted for the chromium slag piled in the open air, the pollution problem cannot be solved fundamentally
[0003] In recent years, due to the attention of the national environmental protection department, many chromium slag detoxification technologies have emerged in my country, but most detoxification technologies use a large amount of other raw materials, chromium slag only accounts for a small amount of ingredients, the consumption of raw materials is large, the detoxification efficiency is low, and the treatment cost is high. , not conducive to large-scale industrial processing

Method used

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  • Method for detoxicating chrome leaching residues through sintering technology
  • Method for detoxicating chrome leaching residues through sintering technology
  • Method for detoxicating chrome leaching residues through sintering technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] 1. Screening of chromium leaching residue

[0051] The chromium slag (the industrial waste slag produced by calcium roasting to produce metal chromium) is screened, and the chromium slag whose granularity is selected is 50 orders-3mm;

[0052] 2. Mix the ingredients evenly

[0053] Chromium slag (composition is shown in Table 1), water-quenched slag discarded during silicon-manganese alloy production (composition is shown in Table 1), and coke powder are batched according to the mass ratio of 80:20:15; after being fully mixed by a mixer, the mixture is obtained. Add water to make mixture particles with a particle size of 5mm-8mm, and control the water content of the particles to 7%;

[0054] 3. Cloth, ignition, sintering

[0055] Distribute the mixture particles evenly on the sintering trolley to ensure that the mixture particles are spread evenly and cover the sintering trolley. The thickness of the sintering material layer is controlled at 450mm, and the thickness o...

Embodiment 2

[0062] 1. Screening of chromium leaching residue

[0063] like figure 1 As shown, chromium slag (composition is as table 1) is screened, and choosing particle size is the chromium slag of 50 order-3mm;

[0064] 2. Mix the ingredients evenly

[0065] The chromium slag, the water-quenched slag discarded during the production of silicomanganese alloy (the composition is shown in Table 1), and the coke powder are mixed according to the mass ratio of 90:10:15; after being fully mixed by the mixer, the mixture is obtained, and the particle size is 5mm after adding water. -8mm mixture particles, and control the particle moisture to 6.5%;

[0066] 3. Cloth, ignition, sintering

[0067] Distribute the mixture particles evenly on the sintering trolley to ensure that the mixture particles are spread evenly and cover the sintering trolley. The thickness of the sintering material layer is controlled at 450mm, and the thickness of the bottom layer is 80mm; use air and electric furnace ga...

Embodiment 3

[0074] 1. Screening of chromium leaching residue

[0075] Sieve the chromium slag (with calcium roasting), and select the chromium slag whose particle size is 50 mesh-3mm;

[0076] 2. Mix the ingredients evenly

[0077] The water-quenched slag and coke powder discarded during the production of chromium slag and silicon-manganese alloy are mixed according to the mass ratio of 70:30:15; the mixture is obtained after being fully mixed by the mixer, and the mixture granules with a particle size of 5mm-8mm are made by adding water , and control the particle moisture to 6%;

[0078] 3. Cloth, ignition, sintering

[0079] Distribute the mixture particles evenly on the sintering trolley to ensure that the mixture particles are spread evenly and cover the sintering trolley. The thickness of the sintering material layer is controlled at 450mm, and the thickness of the bottom layer is 80mm; the ignition temperature is controlled at 1100°C-1200°C; sintering The negative pressure of the...

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Abstract

The invention discloses a method for detoxicating chrome leaching residues through a sintering technology. The method comprises the steps that the chrome residues are screened and fully mixed with water-quenched slag and coke powder through a blender mixer, the mixture is prepared into particles by adding water, the particles are uniformly distributed on a sintering trolley, the effect that the mixture particles are spread flatly and completely distributed on the sintering trolley to be sintered is ensured, and the ignition temperature is controlled to be 1100-1200 DEG C; the negative pressure of a sintering wind box is controlled to be 12-13 kpa; the vertical sintering speed is less than 18 mm/min; high-temperature finished product sintered ore is subjected to air blast cooling; and screening is conducted, and finished product sintered ore is obtained. The method has the advantages that the process is reasonable, the production energy consumption is low, the cost is reduced, harmless treatment of the chrome residues is achieved, and the detoxication efficiency is high; and the index of Cr6+ in a water leaching sample is lower than the national standard, and the method is suitable for industrial large scale treatment.

Description

technical field [0001] This technology belongs to the field of detoxification of chromium leaching slag, and particularly relates to a method for detoxifying chromium leaching slag by using sintering technology. 6+ Convert to Cr 3+ , and achieve a method that meets the national solid waste discharge standards. Background technique [0002] Most of the chromium leaching slag discharged from chromium salt factories and metal chromium factories in our country is piled up in the open air due to its low utilization value. Chromium slag piled up in the open air, after being washed by rainwater, a large amount of hexavalent chromium ions infiltrate into the soil, polluting surface water and groundwater, and also polluting rivers and lakes, thereby endangering crops and aquatic products as well as human and animal health; Chromium valence dust floats into the air and has a strong carcinogenic effect on the human respiratory tract, digestive tract, skin, and mucous membranes. Even...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F23G5/02F23G5/44B07B1/00
CPCB07B1/00F23G5/02F23G5/444
Inventor 齐牧崔传海刘亮王刚龙遇海朱洁韩建强胡兵
Owner CITIC JINZHOU METAL
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