Method for producing battery diaphragm
A battery diaphragm and production process technology, applied in the field of battery diaphragm production technology, can solve the problems of dendrite short circuit, poor ion conductivity, ceramic material layer shedding, etc.
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Embodiment 1
[0020] 80 parts by weight of polyimide, 20 parts by weight of polyvinylidene fluoride, 3 parts by weight of dibutyl phthalate, and 0.5 parts by weight of butyl hydroxyanisole are mixed to obtain a polymer fiber blend, The polymer fiber blend is made into a 6um non-woven fabric layer A by a melt-blown method, and rolled at 180° C.;
[0021] 18 parts by weight of perfluorosulfonic acid resin and 1 part by weight of styrene-butadiene rubber are mixed and prepared to obtain a resin blend, and after the resin blend is melted, it is sprayed on one side surface of the non-woven fabric layer A to form a 4um The surface film layer A, 140 ℃ roll forming;
[0022] 10 parts by weight of Al2O3 ceramic powder, 5 parts by weight of Na 3 PMo 12 o 40 Powder, 0.2-0.5 parts by weight of water-soluble modified polyvinylidene fluoride, 0.1 parts by weight of sodium polyacrylate, 0.1 parts by weight of sodium carboxymethylcellulose, 0.05 parts by weight of kh-550 and 35 parts by weight of water ...
Embodiment 2
[0027] 80 parts by weight of polyimide, 20 parts by weight of polyvinylidene fluoride, 2 parts by weight of dibutyl phthalate, and 0.8 parts by weight of propyl gallate are mixed and prepared to obtain a polymer fiber blend. The polymer fiber blend is made into a 5um non-woven fabric layer A by melt blowing method, and it is rolled and shaped at 160°C;
[0028] 18 parts by weight of perfluorosulfonic acid resin and 1 part by weight of styrene-butadiene rubber are mixed and prepared to obtain a resin blend, and after the resin blend is melted, it is sprayed on one side surface of the non-woven fabric layer A to form a 5um The surface film layer A, 120 ℃ roll forming;
[0029] 8 parts by weight of Al2O3 ceramic powder, 5 parts by weight of Na 3 PMo 12 o 40 Powder, 0.5 parts by weight of polymethyl methacrylate; 0.2 parts by weight of polyethylene glycol, 0.1-0.2 parts by weight of polyvinyl alcohol, 0.05 parts by weight of kh-550 and 25 parts by weight of water are mixed to p...
Embodiment 3
[0034] 82 parts by weight of polyimide, 18 parts by weight of polyvinylidene fluoride, 3 parts by weight of dibutyl phthalate, and 0.5 parts by weight of butyl hydroxyanisole are mixed to obtain a polymer fiber blend, The polymer fiber blend is made into an 8um non-woven fabric layer A by a melt-blown method, and rolled at 180° C.;
[0035] 15 parts by weight of perfluorosulfonic acid resin and 1.2 parts by weight of styrene-butadiene rubber are mixed and prepared to obtain a resin blend. After the resin blend is melted, it is sprayed on one side of the non-woven fabric layer A by a sprayer to form a 3um The surface film layer A, 140 ℃ roll forming;
[0036] 10 parts by weight of Al2O3 ceramic powder, 4 parts by weight of Na 3 SiMo 12 o 40 , 0.5 parts by weight of polyethyl acrylate; 0.1 parts by weight of sodium polyacrylate, 0.2 parts by weight of sodium carboxymethylcellulose, kh-550 of 0.02 parts by weight and water of 35 parts by weight are mixed and prepared to obtain...
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