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Method for producing battery diaphragm

A battery diaphragm and production process technology, applied in the field of battery diaphragm production technology, can solve the problems of dendrite short circuit, poor ion conductivity, ceramic material layer shedding, etc.

Inactive Publication Date: 2017-04-26
安徽兰兮工程技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Lithium battery separators currently used in the market are mainly ceramic membranes coated with a ceramic material layer on the base membrane, but most of this type of ceramic membranes have some defects, such as the problem of dendrites puncturing the separator and causing a short circuit; The problem that the material layer is easy to fall off from the base film; and the poor mobility of lithium ions on the battery separator, poor ion conductivity, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 80 parts by weight of polyimide, 20 parts by weight of polyvinylidene fluoride, 3 parts by weight of dibutyl phthalate, and 0.5 parts by weight of butyl hydroxyanisole are mixed to obtain a polymer fiber blend, The polymer fiber blend is made into a 6um non-woven fabric layer A by a melt-blown method, and rolled at 180° C.;

[0021] 18 parts by weight of perfluorosulfonic acid resin and 1 part by weight of styrene-butadiene rubber are mixed and prepared to obtain a resin blend, and after the resin blend is melted, it is sprayed on one side surface of the non-woven fabric layer A to form a 4um The surface film layer A, 140 ℃ roll forming;

[0022] 10 parts by weight of Al2O3 ceramic powder, 5 parts by weight of Na 3 PMo 12 o 40 Powder, 0.2-0.5 parts by weight of water-soluble modified polyvinylidene fluoride, 0.1 parts by weight of sodium polyacrylate, 0.1 parts by weight of sodium carboxymethylcellulose, 0.05 parts by weight of kh-550 and 35 parts by weight of water ...

Embodiment 2

[0027] 80 parts by weight of polyimide, 20 parts by weight of polyvinylidene fluoride, 2 parts by weight of dibutyl phthalate, and 0.8 parts by weight of propyl gallate are mixed and prepared to obtain a polymer fiber blend. The polymer fiber blend is made into a 5um non-woven fabric layer A by melt blowing method, and it is rolled and shaped at 160°C;

[0028] 18 parts by weight of perfluorosulfonic acid resin and 1 part by weight of styrene-butadiene rubber are mixed and prepared to obtain a resin blend, and after the resin blend is melted, it is sprayed on one side surface of the non-woven fabric layer A to form a 5um The surface film layer A, 120 ℃ roll forming;

[0029] 8 parts by weight of Al2O3 ceramic powder, 5 parts by weight of Na 3 PMo 12 o 40 Powder, 0.5 parts by weight of polymethyl methacrylate; 0.2 parts by weight of polyethylene glycol, 0.1-0.2 parts by weight of polyvinyl alcohol, 0.05 parts by weight of kh-550 and 25 parts by weight of water are mixed to p...

Embodiment 3

[0034] 82 parts by weight of polyimide, 18 parts by weight of polyvinylidene fluoride, 3 parts by weight of dibutyl phthalate, and 0.5 parts by weight of butyl hydroxyanisole are mixed to obtain a polymer fiber blend, The polymer fiber blend is made into an 8um non-woven fabric layer A by a melt-blown method, and rolled at 180° C.;

[0035] 15 parts by weight of perfluorosulfonic acid resin and 1.2 parts by weight of styrene-butadiene rubber are mixed and prepared to obtain a resin blend. After the resin blend is melted, it is sprayed on one side of the non-woven fabric layer A by a sprayer to form a 3um The surface film layer A, 140 ℃ roll forming;

[0036] 10 parts by weight of Al2O3 ceramic powder, 4 parts by weight of Na 3 SiMo 12 o 40 , 0.5 parts by weight of polyethyl acrylate; 0.1 parts by weight of sodium polyacrylate, 0.2 parts by weight of sodium carboxymethylcellulose, kh-550 of 0.02 parts by weight and water of 35 parts by weight are mixed and prepared to obtain...

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Abstract

The invention discloses a method for producing a battery diaphragm. The method comprises the following steps: preparing a polymer fiber blend into a 5-8 um non-woven fabric layer by using a melt blowing method; fusing and spray coating a resin blend onto one side face of the non-woven fabric layer A to form a 3-5um surface film layer A; coating ceramic slurry on the other side face of the non-woven fabric layer A, and drying the ceramic slurry to form a 6-10um ceramic slurry layer; fusing and spry coating the polymer fiber blend onto an exposed surface of the ceramic slurry layer to form a 5-8um non-woven fabric layer B; and fusing and spry coating the resin blend onto the exposed surface of the non-woven fabric layer B to form a 3-5um surface film layer B, and performing rolling and sizing to prepare the battery diaphragm. In the scheme, the generation of dendritic crystals is prevented by changing the components of the materials and changing the stratified structure of the diaphragm, and the ceramic slurry layer will not drop from the base film; and the porosity, the high temperature resistance, the thermal stability and other performance of the diaphragm are significantly improved as well.

Description

technical field [0001] The invention relates to the field of lithium battery production, in particular to a production process of a battery diaphragm. Background technique [0002] Lithium batteries are widely used, especially in mobile devices, due to their excellent properties such as high energy density, long life, and high operating voltage. The diaphragm is an important part of the lithium battery, which has an important impact on the capacity, charge and discharge density, cycle performance and battery safety of the battery. Lithium battery separators currently used in the market are mainly ceramic membranes coated with a ceramic material layer on the base membrane, but most of this type of ceramic membranes have some defects, such as the problem of dendrites puncturing the separator and causing a short circuit; The problem that the material layer is easy to fall off from the base film; and the mobility of lithium ions on the battery separator is poor, the ion conduct...

Claims

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Application Information

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IPC IPC(8): H01M2/14H01M2/16D06M11/45D06M11/46D06M11/48D06M11/79D06M13/513D06M15/09D06M15/256D06M15/263D06M15/333D06M15/53D06M15/693
CPCD06M11/45D06M11/46D06M11/48D06M11/79D06M13/513D06M15/09D06M15/256D06M15/263D06M15/333D06M15/53D06M15/693D06M2101/22D06M2101/30H01M50/403H01M50/411H01M50/431H01M50/44H01M50/449Y02E60/10
Inventor 江兵朱仁发
Owner 安徽兰兮工程技术开发有限公司
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