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A kind of preparation method of bismuth zirconate microcrystalline ceramic glaze with photocatalytic function

A bismuth zirconate and photocatalysis technology, applied in the field of ceramic glazes, can solve the problems of poor bonding between photocatalytic films and substrates, uneven distribution of photocatalyst glazes, and affecting the aesthetics of ceramics, achieving good visible light response and improving light Good catalytic performance and surface decoration effect

Active Publication Date: 2018-12-25
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above methods, or there are shortcomings such as poor bonding between the photocatalytic film and the substrate, easy to fall off, or uneven distribution in the photocatalyst glaze, and the "rainbow effect" and other shortcomings, which directly affect the aesthetics of ceramics.

Method used

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  • A kind of preparation method of bismuth zirconate microcrystalline ceramic glaze with photocatalytic function
  • A kind of preparation method of bismuth zirconate microcrystalline ceramic glaze with photocatalytic function

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] 1) First, quartz, potassium feldspar, albite, borax, Bi 2 o 3 , Suzhou soil, lithium carbonate and other raw materials are prepared according to the following mass chemical composition ratios. SiO 2 :Al 2 o 3 :B 2 o 3 : Bi 2 o 3 : Li 2 O: Na 2 O:K 2 O=57:4:22:4:7:4:3.

[0032] 2) Dry mix and grind the above-mentioned powders, pass through a 60-mesh sieve to obtain the mixture, put it into a crucible, put it into an electric furnace and keep it at 1270°C for 20 minutes, take it out and pour it into water to quench to make a frit. Take out the frit from the water, put it into a ball mill after drying, and grind it finely. The mass ratio of control material (frit): ball: water is 1:1:0.8, pass through a 250-mesh sieve after grinding for 3 hours, and dry for later use. This powder is denoted as A material.

[0033] 3) Combine the above material A and Bi 2 o 3 , ZrO 2 And the mass ratio of Suzhou soil is A: Bi 2 o 3 : Suzhou soil = 82:7.4:7 ratio for batchi...

Embodiment 2

[0039] 1) First, quartz, potassium feldspar, albite, borax, Bi 2 o 3 , Suzhou soil, lithium carbonate and other raw materials are prepared according to the following mass chemical composition ratios. SiO 2 :Al 2 o 3 :B 2 o 3 : Bi 2 o 3 : Li 2 O: Na 2 O:K 2 O=58:5:23:3:6:3:2.

[0040] 2) Dry mix and grind the above-mentioned powders, pass through a 60-mesh sieve to obtain the mixture, put it into a crucible, put it into an electric furnace and keep it warm at 1280°C for 30 minutes, take it out and pour it into water to quench to make a frit. Take the frit out of the water, put it into a ball mill after drying, and grind it finely. The mass ratio of control material (frit): ball: water is 1:1:0.8, pass through a 250-mesh sieve after grinding for 4 hours, and dry for later use. This powder is denoted as A material.

[0041] 3) Combine the above material A and Bi 2 o 3 , ZrO 2 And the mass ratio of Suzhou soil is A: Bi 2 o 3 : Suzhou soil = 84: 7.2: 6 ratio for b...

Embodiment 3

[0045] 1) First, quartz, potassium feldspar, albite, borax, Bi 2 o 3 , Suzhou soil, lithium carbonate and other raw materials are prepared according to the following mass chemical composition ratios. SiO 2 :Al 2 o 3 :B 2 o 3 : Bi 2 o 3 : Li 2 O: Na 2 O:K 2 O=59:6:24:2:5:2:1.

[0046] 2) Dry mix and grind the above-mentioned powders, pass through a 40-mesh sieve to obtain the mixture, put it into a crucible, put it in an electric furnace at 1290° C. for 40 minutes, take it out and pour it into water to quench to obtain a frit. Take out the frit from the water, put it into a ball mill after drying, and grind it finely. The mass ratio of control material (frit): ball: water is 1:1:0.8, pass through a 250-mesh sieve after grinding for 3 hours, and dry for later use. This powder is denoted as A material.

[0047] 3) Combine the above material A and Bi 2 o 3 , ZrO 2 And the mass ratio of Suzhou soil is A: Bi 2 o 3 : Suzhou soil = 86:7:5 ratio for batching, and Bi ...

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Abstract

A method for preparing bismuth zirconate ceramic glaze with photocatalytic function. Quartz, potassium feldspar, albite, borax, Bi2O3, Suzhou soil, and lithium carbonate are mixed together and kept at 1270-1290°C for 20-40 minutes, then taken out and poured. Quench in water to obtain frit; grind the frit to obtain material A; mix material A with Bi2O3, ZrO2 and Suzhou soil to obtain material B; add material B and dispersant to water, stir and mix to prepare glaze Slurry; apply the glaze slurry on the ceramic surface and bake to obtain bismuth zirconate ceramic glaze with photocatalytic function. The enamel produced by the invention has good gloss and stable chemical properties. The present invention uses a firing process to prepare ceramic glaze without coating, so that the prepared functional ceramic glaze is closely combined with the ceramic matrix and is not easy to fall off, and crystallized flowers with special shapes can be quickly formed on the surface of the glaze. The decorative effect is good.

Description

technical field [0001] The invention belongs to the technical field of ceramic glazes. Specifically relates to a preparation method of bismuth zirconate microcrystalline ceramic glaze with photocatalytic function. Background technique [0002] Photocatalytic technology began in 1972. Japanese scholars Fujishima and Honda discovered that hydrogen can be produced by photocatalytically decomposing water on semiconductor electrodes [Fujishima A., Honda K. Photocatalysis-decomposition of water at the surface of an irradiated semiconductor[J].Nature, 1972,238(5385):37-38.], this discovery has aroused great attention of scientific and technological workers to photocatalysis. With the increasingly prominent energy and environmental issues, photocatalytic technology has received extensive attention and achieved rapid development. Photocatalytic materials have potential applications in degradation of organic pollutants, air purification, antibacterial and self-cleaning. [0003] Si...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C8/20C04B41/86B01J23/18
CPCC03C8/20C04B41/5023C04B41/86B01J23/18B01J35/39C04B41/4535
Inventor 曹丽云罗艺佳黄剑锋李嘉胤孔新刚刘一军
Owner SHAANXI UNIV OF SCI & TECH
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