Basalt fiber reinforced polyamide composite material and preparation method thereof

A technology of basalt fiber and composite material, applied in the field of basalt fiber reinforced polyamide composite material and its preparation, can solve the problems of poor performance, increase the compatibility between basalt fiber and polyamide material, etc., and achieve good mechanical properties and stable product quality. , the effect of good physical and chemical properties

Active Publication Date: 2017-05-31
东莞市运和高分子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The object of the present invention is to overcome the defect of poor performance of basalt fiber reinforced polyamide composite material, and provide a kind of basalt fiber reinforced polyamide composite material and its preparation method; the present invention first utilizes modifying agent to carry out surface modification treatment to basalt fiber, make The surface roughness of the fiber increases and a large number of active sites and active groups are formed, thereby increasing the compatibility between the basalt fiber and the polyamide material, enabling the chemical bonding and mechanical riveting of the basalt fiber and the polyamide material, and then the modified Treated basalt fiber is combined with polyamide material to obtain basalt fiber reinforced polyamide composite material with better performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Pretreatment: the basalt fiber is used in a modifier consisting of 3 parts by weight of potassium nitrate, 8 parts by weight of potassium hydroxide, 12 parts by weight of polysiloxane quaternary ammonium salt, and 80 parts by weight of water, Pretreatment at a temperature of 55°C for 2 hours to obtain modified basalt fibers;

[0026] (2) Composite: 2 parts by weight of modified basalt fiber and 10 parts by weight of PA66101F were compounded to obtain a basalt fiber reinforced polyamide composite material.

Embodiment 2

[0028] (1) Pretreatment: use basalt fiber in a modifier consisting of 2 parts by weight of sodium nitrate, 10 parts by weight of sodium hydroxide, 15 parts by weight of polysiloxane quaternary ammonium salt, and 100 parts by weight of water, Pretreatment at a temperature of 65°C for 3 hours to obtain modified basalt fibers;

[0029] (2) Composite: 2 parts by weight of modified basalt fiber and 10 parts by weight of PA66101F were compounded to obtain a basalt fiber reinforced polyamide composite material.

Embodiment 3

[0031] (1) Pretreatment: Put basalt fiber in a modifier consisting of 5 parts by weight of nitrate, 5 parts by weight of potassium hydroxide, 10 parts by weight of trialkoxysilane quaternary ammonium salt, and 100 parts by weight of water , pretreated at a temperature of 80°C for 1 hour to obtain modified basalt fibers;

[0032] (2) Composite: 2 parts by weight of modified basalt fiber and 10 parts by weight of PA66101F were compounded to obtain a basalt fiber reinforced polyamide composite material.

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Abstract

The invention discloses a basalt fiber reinforced polyamide composite material and a preparation method thereof. The preparation method comprises the following steps: firstly, carrying out surface modification treatment on basalt fibers by using a modifier, wherein the modifier is prepared from nitrate, strong base and quaternary ammonium salt; enabling the surface roughness of the fibers to be increased and forming a large amount of active sites and active groups, so as to improve the compatibility of the basalt fibers and a polyamide material; enabling the basalt fibers and the polyamide material to be chemically bonded and mechanically riveted; secondly, compounding the basalt fibers subjected to modification treatment and the polyamide material to obtain the basalt fiber reinforced polyamide composite material with more excellent performance.

Description

technical field [0001] The invention relates to the field of polyamide composite materials, in particular to a basalt fiber reinforced polyamide composite material and a preparation method thereof. Background technique [0002] Basalt fiber is a new type of inorganic environmentally friendly green high-performance fiber material, and it is one of the four high-performance fibers that will be developed in my country in the future. The basalt rock material composed of basalt is melted at high temperature and then prepared by spinning process. Basalt continuous fiber not only has good stability, but also has various excellent properties such as electrical insulation, corrosion resistance, combustion resistance, and high temperature resistance. Moreover, the production process of basalt fiber produces less waste and less environmental pollution. It can be directly transferred to the ecological environment without any harm, so it is a veritable green and environmental protection ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08K9/06C08K9/02C08K7/10C08J5/06
CPCC08J5/06C08J2377/06C08K7/10C08K9/02C08K9/06C08L77/06
Inventor 不公告发明人
Owner 东莞市运和高分子科技有限公司
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