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Preparation method of environment-friendly composite engineering plastic

An engineering plastics, environmental protection technology, applied in the field of engineering plastics, can solve the problems of PVC recycling, potential impact on the environment, etc., and achieve the effect of improving fluidity and processing performance, improving flame retardancy and anti-aging performance, and saving energy

Inactive Publication Date: 2017-06-06
肇庆汇展塑料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the recycling problem of PVC and the potential impact on the environment have not been solved, and the restrictions on PVC still exist in many occasions.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] The waste polyvinyl chloride raw materials are crushed, washed with detergent, rinsed with clean water, iron removed by electromagnetic iron remover, heated and extruded by extruder, and regenerated polyvinyl chloride is obtained after cutting by pelletizer. Vinyl material. The detergent includes at least 0.01mol / L of hydrochloric acid, 0.1mol / L of acetic acid and 0.01mol / L of sodium fluoride, and the waste water generated is discharged into the sewage treatment pool, and the sewage treatment pool includes 3 stages in series sedimentation tank.

[0039] With the above-mentioned regenerated polyvinyl chloride material, dipropylene phthalate and polyvinyl ester elastomer as basic raw materials, xylene as solvent, under the action of bridging agent styrene, acrylic acid and initiator benzoyl peroxide The following reaction is carried out to obtain the masterbatch of recycled engineering plastics.

[0040] Ingredients according to the following parts by weight:

[0041] ...

Embodiment 2

[0061] The waste polyvinyl chloride raw materials are crushed, washed with detergent, rinsed with clean water, iron removed by electromagnetic iron remover, heated and extruded by extruder, and regenerated polyvinyl chloride is obtained after cutting by pelletizer. Vinyl material. The detergent includes at least 0.02mol / L of hydrochloric acid, 0.2mol / L of acetic acid and 0.02mol / L of sodium fluoride, and the waste water produced is discharged into the sewage treatment pool, and the sewage treatment pool includes 4 stages in series sedimentation tank.

[0062] With the above-mentioned regenerated polyvinyl chloride material, dipropylene phthalate and polyvinyl ester elastomer as basic raw materials, xylene as solvent, under the action of bridging agent styrene, acrylic acid and initiator benzoyl peroxide The following reaction is carried out to obtain the masterbatch of recycled engineering plastics.

[0063] Ingredients according to the following parts by weight:

[0064] 1...

Embodiment 3

[0084]The waste polyvinyl chloride raw materials are crushed, washed with detergent, rinsed with clean water, iron removed by electromagnetic iron remover, heated and extruded by extruder, and regenerated polyvinyl chloride is obtained after cutting by pelletizer. Vinyl material. The detergent includes at least 0.03mol / L of hydrochloric acid, 0.3mol / L of acetic acid and 0.03mol / L of sodium fluoride, and the waste water produced is discharged into the sewage treatment pool, which includes 3-5 Sedimentation tanks in series.

[0085] With the above-mentioned regenerated polyvinyl chloride material, dipropylene phthalate and polyvinyl ester elastomer as basic raw materials, xylene as solvent, under the action of bridging agent styrene, acrylic acid and initiator benzoyl peroxide The following reaction is carried out to obtain the masterbatch of recycled engineering plastics.

[0086] Ingredients according to the following parts by weight:

[0087] 113 parts of the above composi...

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PUM

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Abstract

The invention discloses a preparation method of an environment-friendly composite engineering plastic, which uses recycled polyvinyl chloride material, dipropylene phthalate and polyvinyl ester elastomer to make a composite engineering plastic masterbatch, which has excellent impact toughness , and reduce the cost; highly dispersed nano-calcium carbonate and composite engineering plastic masterbatch have good dispersion and compatibility, improve the fluidity and processing performance of composite engineering plastic masterbatch, and endow engineering plastics with better physical and mechanical properties , to further improve the toughness; flame-retardant materials such as graphene, titanium dioxide, and halloysite nanotubes in the modified anti-aging flame-retardant system and anti-aging materials such as wollastonite needle-like fibers form a composite synergistic effect, which greatly improves the engineering quality. Flame retardant and anti-aging properties of plastics; no secondary pollution, clean and civilized production, less labor, high labor efficiency, energy saving, and environmental protection.

Description

technical field [0001] The invention relates to the technical field of engineering plastics, in particular to a preparation method of environment-friendly composite engineering plastics. Background technique [0002] While engineering plastics satisfy people's life and social development, the social and environmental problems caused by the "white pollution" caused by the sharp increase of plastic waste are also becoming more and more serious. Recycled engineering plastics is an effective way to solve the pollution caused by engineering plastics, but recycled engineering plastics have disadvantages such as low strength, no toughness, low gloss, and poor thermal oxygen stability. In addition, due to the macromolecular chain of recycled engineering plastics There are tertiary carbon atoms. During storage, processing and daily use, they are prone to aging and degradation due to the effects of heat, light and oxygen. The weather resistance is extremely poor, which seriously affec...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L71/02C08K13/06C08K9/02C08K9/00C08K9/04C08K5/12C08K3/26C08K3/04C08K3/34C08K7/26C08K3/22C08K7/10
CPCC08L27/06C08K2201/003C08K2201/004C08K2201/011C08K2201/014C08L2201/02C08L2201/08C08L71/02C08K13/06C08K9/02C08K9/00C08K9/04C08K5/12C08K2003/265C08K3/04C08K3/346C08K7/26C08K2003/2241C08K7/10
Inventor 罗文平王厚群
Owner 肇庆汇展塑料科技有限公司
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