Preparation method of phosphate esterification starch adhesive based formaldehyde-free building inner wall putty

A technology of esterifying starch and starch, which is applied in the direction of starch-derived adhesives, adhesive types, filling pastes, etc., can solve the problems of high viscosity of starch adhesives and poor bonding strength that have not been reported on building interior wall putty. There are still some problems to be improved to achieve the effect of improved construction performance, good fluidity and low price

Inactive Publication Date: 2017-06-13
SOUTHWEAT UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, according to the requirements of construction putty on viscosity, strength and workability, there has been no report on starch phosphate modification, nor has there been any report on phosphated starch adhesive type construction interior wall putty.
In addition, unmodified starch adhesives prepared directly by alkali gelatinization or after high-temperature gelatinization have disadvantages such as high viscosity, bond strength to be improved, and poor construction performance.

Method used

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  • Preparation method of phosphate esterification starch adhesive based formaldehyde-free building inner wall putty
  • Preparation method of phosphate esterification starch adhesive based formaldehyde-free building inner wall putty
  • Preparation method of phosphate esterification starch adhesive based formaldehyde-free building inner wall putty

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A method for preparing phosphated starch adhesive-based formaldehyde-free building interior wall putty, comprising the following steps:

[0044] a. Preparation of phosphated starch adhesive:

[0045] The first step: batching: be 1.3% sodium dihydrogen phosphate by mass percentage and raw material component, 10% starch, 10% mass percentage concentration is the NaOH aqueous solution of 20%, and 78.7% water (included in preparation process The proportioning of 8% in the second step and 70.7% in the fourth step) gets raw material sodium monohydrogen phosphate or / and sodium dihydrogen phosphate, starch, the NaOH aqueous solution that mass percent concentration is 20%, and water; 4 parts of washing water, each with a quality of 25% of the starch quality, set aside;

[0046] Preparation process:

[0047] The second step: esterification synthesis: add 8% water to sodium dihydrogen phosphate, stir to dissolve, adjust the pH value to 5.5 with NaOH aqueous solution with a mass p...

Embodiment 2~7

[0061] A preparation method of phosphated starch adhesive-based formaldehyde-free building interior wall putty, mainly aiming at changing the temperature, time, pH and other process conditions of esterification of phosphated starch adhesive, and the content of each raw material component Consistent with the preparation procedure and embodiment 1;

[0062] Table 1: The different technological conditions of esterification synthesis among the embodiment 2~7 are shown in the table below:

[0063]

[0064] The components, preparation process and construction process of the phosphated starch adhesive-based formaldehyde-free building interior wall putty in Examples 2 to 7 are the same as those in Example 1, and are omitted;

Embodiment 8~14

[0066] A method for preparing phosphated starch adhesive-based formaldehyde-free building interior wall putty, comprising the following steps:

[0067] a. Preparation of phosphated starch adhesive:

[0068] The specific mass percentages of each raw material component in the phosphated starch adhesive of each embodiment are shown in Table 2;

[0069] Configuration process: its preparation process is consistent with embodiment 1;

[0070] Table 2: The specific mass percentages of the components of the phosphated starch adhesive in each embodiment are shown in the following table:

[0071]

[0072] b. Preparation of phosphated starch adhesive-based formaldehyde-free building interior wall putty:

[0073] The specific mass percentage consumption of each raw material component of A component is shown in the following table 3 in each embodiment;

[0074] Configuration process: its preparation process is consistent with embodiment 1;

[0075] Table 3: The specific mass percent...

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Abstract

The invention discloses a preparation method of phosphate esterification starch adhesive based formaldehyde-free building inner wall putty. The method is characterized by comprising the following steps that a phosphate esterification starch adhesive is prepared: raw materials of disodium phosphate or/and sodium dihydrogen phosphate, starch, NaOH water solution and water are taken; esterification synthesis, esterification starch washing and esterification starch pasting are performed to prepare the phosphate esterification starch adhesive; then, an ingredient A and gypsum or white cement are mixed to prepare the phosphate esterification starch adhesive based formaldehyde-free building inner wall putty; the ingredient A is mainly prepared from the phosphate esterification starch adhesive, heavy calcium carbonate, carboxymethylcellulose and preservatives. By using the method provided by the invention, the prepared phosphate esterification starch adhesive based formaldehyde-free building inner wall putty does not contain formaldehyde; ecological and environment-friendly effects are achieved; the preparation process is completed under the low-temperature condition; the energy consumption is low; a good energy-saving and emission reduction effect is achieved; the raw material resources are wide; the comprehensive cost is low; the phosphate esterification starch adhesive based formaldehyde-free building inner wall putty can be widely applied to various building inner walls of residences, schools, hospitals and the like.

Description

technical field [0001] The invention belongs to the preparation of filling slurry, and relates to a method for preparing phosphated starch adhesive-based formaldehyde-free building interior wall putty. The preparation of phosphated starch adhesive-based formaldehyde-free building interior wall putty is green and environmentally friendly , no formaldehyde pollutants, high strength, good construction performance, simple production process, low overall cost, and can be widely used in various types of building interior walls. Background technique [0002] Putty is a material for smoothing and protecting the surface of the wall. It is an indispensable process before the paint is painted. It acts as a bond between the wall and the paint. It can firmly bond the wall and provide a good coating for the paint. base. Traditional building interior wall putty generally uses polyvinyl formal construction glue, formaldehyde-containing construction rubber powder, etc. Although it has high ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/34C09J103/06C08B31/06
Inventor 邓跃全邓爽李光华田含旭汪彬彬李霞郭李琴
Owner SOUTHWEAT UNIV OF SCI & TECH
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