Denture base for preventing denture stomatitis
A technology for denture base and stomatitis, which is applied in the field of denture base for preventing and treating denture stomatitis, can solve the problems of side effects of surrounding tissues, limit antibacterial activity, affect the mechanical properties of carrier materials, etc. effect of stomatitis
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Embodiment 1
[0034] Synthesis and Characterization of 1AgBr / NPVP
[0035] The raw materials required for the synthesis experiment are polyvinylpyridine, silver p-toluenesulfonate, nitromethane, 1-bromohexane, diethyl ether and dimethyl sulfoxide.
[0036]The method for synthesizing AgBr / NPVP is as follows: Dissolve poly-4-vinylpyridine [poly(4-vinylpyridine), PVP] (2.1g, 20mmol) and 0.3 equivalent of 1-bromohexane (0.85mL, 6mmol) in 25ml Nitromethane was stirred in a 60°C water bath for 24h to obtain a pale yellow product NPVP. Subsequently, an excess of silver paratoluenesulfonate solution (AgPTS) was slowly added to the polymer, and through this in-situ precipitation method, it was mixed to finally obtain a quaternary ammonium salt polymer-wrapped silver bromide nanocomposite (AgBr / NPVP ),See figure 1 with figure 2 . figure 2 Among them, n represents the degree of polymerization of poly-4-vinylpyridine, x represents the grafting amount of 1-bromohexane, and the value of x has litt...
Embodiment 2
[0082] 1 Materials and methods
[0083] 1.1 Main materials, reagents and instruments: silver bromide nanocomposite coated with quaternary ammonium salt, Streptococcus mutans UA159, brain heart extract broth, artificial saliva, live / dead bacteria staining kit, Bis-GMA, TEGDMA, camphorquinone, Dimethylaminoethyl methacrylate, ultra-clean bench, anaerobic culture tank, Vitek bacterial turbidimeter, vortex mixer, micro-sampler, 24-well cell culture plate, laser confocal microscope, universal testing machine, dimension Hardness tester.
[0084] 1.2 Experimental method
[0085] 1.2.1 Synthesis of quaternary ammonium salt-wrapped silver bromide nanocomposites First, bromohexane and methyl 2-bromoethylacrylate were grafted onto poly-4-vinylpyridine [poly(4-vinylpyridine) by quaternization reaction. , PVP] on the side chain, nitromethane as a solvent, stirred in a water bath at 60°C for 24h, and synthesized quaternary ammonium methacrylates (quaternary ammoniummethacrylates, BHPVP). ...
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