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an alternative to cabr 2 Strong inhibition and low corrosion brine completion fluid and preparation method thereof

A low-corrosion, well-completion fluid technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of slow dissolution rate, loss of oil-producing capacity, reduction of oil-reservoir productivity, etc. The effect of low self performance and reservoir damage

Active Publication Date: 2020-07-03
BC P INC CHINA NAT PETROLEUM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But CaBr 2 There are also many disadvantages in brine completion fluid: 1) During construction in winter, due to the low outdoor temperature (below 10°C), the physical and chemical properties of CaBr make CaBr 2 The dissolution rate is slow, the solid phase content increases, and the density of the brine solution is difficult to meet the requirements, and sometimes the density can only reach 1.45g / cm 3 left and right; 2) due to poor solubility, insoluble particles of inorganic salts precipitate and invade the formation, resulting in pore blockage; 3) due to CaBr 2 For divalent metal salt, Ca 2+ Salt meets CO 3 2- , SO 4 2- etc. prone to scaling, not environmentally friendly, and damaging to the reservoir; 4) CaBr 2 The brine completion fluid is highly corrosive to the casing, and after a long time, there is a potential danger; 5) The completion fluid system itself lacks performance, which makes the cemented particles loose and then dissolves, dissolves or recrystallizes minerals, and particles migrate and minerals Precipitation, causing rock damage to the reservoir
After the reservoir is damaged, first, it is easy to reduce the production capacity of the oil reservoir, and in severe cases, it will completely lose the oil production capacity, resulting in huge economic losses in the oil field; second, it is very difficult to restore to the original level, and of course the cost is also very expensive

Method used

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  • an alternative to cabr  <sub>2</sub> Strong inhibition and low corrosion brine completion fluid and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Add 32 parts of deionized water, 60 parts of complex potassium salt (the mass ratio of potassium formate and potassium pyrophosphate is 1.5:8.5), 2 parts of clay antiswelling agent, and 1.5 parts of acrylic acid-acrylamide copolymer fluid loss control agent Stir in the reaction flask evenly, and stir at room temperature for 0.5-1h; then add 1 part of hydrophobically modified sodium alginate to the reaction flask, and continue stirring for 0.5-1h to make the mixed system uniform; finally add 3.5 parts of organic amine corrosion inhibitor, Baracor300, continue to stir until a uniform transparent strong-inhibited low-corrosion brine completion fluid is formed.

Embodiment 2

[0025] Add 37 parts of deionized water, 55 parts of compound potassium salt (the mass ratio of potassium formate and potassium pyrophosphate is 2:8), 1.5 parts of clay anti-swelling agent, and 2 parts of sulfonated starch into the reaction flask and stir evenly, and Stir at room temperature for 0.5 to 1 hour; then add 1.5 parts of hydrophobically modified sodium alginate to the reaction flask, and continue to stir for 0.5 to 1 hour to make the mixed system uniform; finally add 3 parts of imidazoline corrosion inhibitor to the reaction flask , continue to stir until a uniform transparent strong inhibition low corrosion brine completion fluid is formed.

Embodiment 3

[0027] Add 11.5 parts of deionized water, 80 parts of compound potassium salt (the mass ratio of potassium formate and potassium pyrophosphate is 1:9), 1 part of clay anti-swelling agent, and 1.5 parts of carboxymethyl cellulose into the reaction bottle and stir evenly , and stirred at room temperature for 0.5 to 1 hour; then added 2 parts of hydrophobically modified sodium alginate to the reaction bottle, and continued to stir for 0.5 to 1 hour to make the mixed system uniform; finally, added 4 parts of cyano-inorganic compound to the reaction bottle The corrosion inhibitor, Baracor 450, was stirred until a uniform clear, strongly inhibited, low-corrosion brine completion fluid was formed.

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Abstract

The invention discloses strong-inhibition low-corrosion brine completion fluid capable of replacing CaBr2, and a preparation method thereof. The alkaline completion fluid comprises the following components in percentage by mass: 50 to 80 percent of composite potassium salt, 1 to 3 percent of hydrophobic modified sodium alginate, 1 to 2 percent of a clay anti-swelling agent, 1.5 to 2 percent of a filtrate reducer, 2 to 5 percent of a corrosion inhibitor and the balance of water. The novel strong-inhibition low-corrosion brine completion fluid capable of replacing CaBr2 brine completion fluid with the density being 1.70 g / cm<3> is prepared by adopting the hydrophobic modified sodium alginate as a completion fluid tackifier and adopting the clay anti-swelling agent, the filtrate reducer and the corrosion inhibitor for the first time; in addition, the preparation method is simple and safe, and has extremely good industrial prospect.

Description

technical field [0001] The invention relates to the technical field of brine completion fluid, in particular to a CaBr substitute 2 Strong inhibition and low corrosion brine completion fluid and preparation method thereof. Background technique [0002] Completion fluid is the working fluid used in the well completion process. Its main functions are to balance formation pressure, carry suspended solid particles, and improve reservoir protection capabilities. The use of inferior completion fluids can reduce well productivity by more than 30%, causing formation damage. [0003] CaBr 2 As a commonly used well killing fluid system, brine completion fluid has the advantages of moderate price, and the density of saturated solution can reach 1.70g / cm3 after complete dissolution 3 about. But CaBr 2 There are also many disadvantages in brine completion fluid: 1) During construction in winter, due to the low outdoor temperature (below 10°C), the physical and chemical properties o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/12
CPCC09K8/12C09K2208/12
Inventor 刘音陈世春白田增解洪祥王玉忠王丹张世林刘泸萍
Owner BC P INC CHINA NAT PETROLEUM CORP
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