Functional masterbatch for improving low temperature resistance of polypropylene

A technology of functional masterbatch and low temperature resistance, applied in the field of functional masterbatch, can solve the problems of poor cold resistance and achieve good compatibility, good low temperature resistance and improved low temperature resistance

Inactive Publication Date: 2017-07-21
长兴天晟能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problem that the poor cold resistance of polypropylene limits the application of polypropylene in the low temperature field, the purpose of the present invention is to provide a functional masterbatch for improving the low temperature resistance of polypropylene, which can significantly improve the low temperature resistance of polypropylene resin, and Added to polypropylene resin to disperse evenly and keep resin performance uniform

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A functional masterbatch that improves the low temperature resistance of polypropylene, prepared from components: 100g carrier resin, 25g high-density polyethylene resin, 2g crosslinking agent, 3g plasticizer, 1.6g nano-silica, and nano-alumina 1.2g, nano-scale kaolin powder 1.5g, nano-nickel oxide 0.5g, nano-iron oxide 1.2g, nano-titanium oxide 0.4g, coupling agent 0.8g, dispersant 0.6g, wherein the carrier resin is polypropylene resin, crosslinking agent One of zinc oxide, zinc acetate or aluminum isopropoxide is preferred, the coupling agent is preferably one of KR-41B or triisostearyl titanate, and the dispersant is preferably lignin fiber, oxidized polyethylene wax, three One of glyceryl stearate or calcium stearate.

[0021] A method for preparing a functional masterbatch that improves the low temperature resistance of polypropylene, comprising the following steps: (1) mixing and stirring each raw material component evenly, the mixing temperature is 60°C, and the ...

Embodiment 2

[0023] A functional masterbatch for improving the low temperature resistance of polypropylene, which is prepared from the following components: 110g carrier resin, 35g high-density polyethylene resin, 3.5g crosslinking agent, 4g plasticizer, 2g nano-silica, 2g nano-oxide Aluminum 1.5g, nano-scale kaolin powder 2.25g, nano-nickel oxide 0.65g, nano-iron oxide 1.6g, nano-titanium oxide 0.6g, coupling agent 1.0g, dispersant 0.7g, wherein the carrier resin is polypropylene resin, cross-linked The preferred agent is one of zinc oxide, zinc acetate or aluminum isopropoxide, the preferred coupling agent is one of KR-41B or triisostearyl titanate, and the preferred dispersant is lignin fiber, oxidized polyethylene wax, One of glyceryl tristearate or calcium stearate.

[0024] A method for preparing a functional masterbatch that improves the low temperature resistance of polypropylene, comprising the following steps: (1) mixing and stirring each raw material component evenly, the mixing...

Embodiment 3

[0026] A functional masterbatch for improving the low temperature resistance of polypropylene, which is prepared from the following components: 120g carrier resin, 45g high-density polyethylene resin, 5g crosslinking agent, 5g plasticizer, 2.4g nano-silica, 2.4g nano-silica Aluminum 1.8g, nano-scale kaolin powder 3g, nano-nickel oxide 0.8g, nano-iron oxide 2.0g, nano-titanium oxide 0.8g, coupling agent 1.2g, dispersant 0.8g, wherein the carrier resin is polypropylene resin, crosslinking agent One of zinc oxide, zinc acetate or aluminum isopropoxide is preferred, the coupling agent is preferably one of KR-41B or triisostearyl titanate, and the dispersant is preferably lignin fiber, oxidized polyethylene wax, three One of glyceryl stearate or calcium stearate.

[0027]A method for preparing a functional masterbatch that improves the low temperature resistance of polypropylene, comprising the following steps: (1) mixing and stirring each raw material component evenly, the mixing ...

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Abstract

Relating to the field of functional masterbatches, the invention specifically discloses a functional masterbatch for improving the low temperature resistance of polypropylene. The functional masterbatch is composed of carrier resin, high density polyethylene resin, a crosslinking agent, nanoscale silicon oxide, nanoscale alumina, nanoscale kaolin powder, nanoscale nickel oxide, nanoscale iron oxide, nanoscale titanium oxide, a coupling agent, and a dispersing agent. The carrier resin is polypropylene resin, the crosslinking agent is preferably one of zinc oxide, zinc acetate or aluminum isopropoxide, the coupling agent is preferably one of KR-41B or triisostearyl titanate, the dispersing agent is preferably one of lignocellulose, oxidized polyethylene wax, glycerol tristearate or calcium stearate. After adding of the functional masterbatch provided by the invention into polypropylene, high density polyethylene resin and polypropylene resin can be blended to improve the low temperature resistance of polypropylene, in the fusion dispersion process of nano alumina, nano silicon oxide, kaolin and the like, a ceramic structure can be formed to strengthen the low temperature resistance of polypropylene resin.

Description

technical field [0001] The invention relates to the field of functional masterbatches, in particular to a functional masterbatch for improving the low temperature resistance of polypropylene. Background technique [0002] Polypropylene (PP) is a thermoplastic resin prepared by propylene polymerization. It is non-toxic, odorless, tasteless, milky white and highly crystalline. It is divided into isotactic polypropylene, atactic polypropylene and syndiotactic polypropylene according to the position of the methyl group. There are three kinds of propylene, in which the methyl groups are arranged on the same side of the main chain of the molecule, which is called isotactic polypropylene. If the methyl groups are arranged randomly on both sides of the main chain of the molecule, it is called atactic polypropylene. The two sides of the main chain are called syndiotactic polypropylene. In general industrially produced polypropylene resins, the isotactic structure content is about 95...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L97/00C08L23/30C08K13/02C08K3/36C08K3/22C08K3/34C08K5/098C08K5/103C08J3/22
CPCC08J3/226C08J2323/12C08J2423/12C08K2201/011C08L23/12C08L2205/16C08L2207/062C08L2312/00C08L23/06C08L97/005C08L23/30C08K13/02C08K3/36C08K2003/2227C08K3/346C08K2003/2293C08K2003/2272C08K2003/2241C08K2003/2296C08K5/098C08K5/103
Inventor 佘海中
Owner 长兴天晟能源科技有限公司
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