Strong-strength denitration catalyst and preparation method for same

A denitration catalyst, high-strength technology, applied in chemical instruments and methods, physical/chemical process catalysts, chemical elements of heterogeneous catalysts, etc., can solve the problems of large catalyst dosage, low catalyst strength, and low catalytic efficiency, and achieve good Forming effect, stable mechanical properties, high catalytic efficiency

Inactive Publication Date: 2017-09-08
HEFEI DAZHUO ELECTRIC POWER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The catalyst has low pressure drop, wear resistance and excellent denitrification activity and has been widely used, but the existing honeycomb catalyst has some shortcomings, and its optimum working temperature is generally 300-450 °C. In actual working conditions, it is difficult for the flue gas temperature to reach this temperature range; on the other hand, in order to achieve better denitrification effect and anti-sulfur and water resistance, the honeycomb denitrification catalyst generally has a higher pore density, but in the actual flue gas Contains a large amount of water, sulfur dioxide and dust, which can easily block the catalyst
Therefore, there are still problems such as low catalyst strength, easy pulverization, short service life, low catalytic efficiency, large amount of catalyst, and high cost.

Method used

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  • Strong-strength denitration catalyst and preparation method for same

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Embodiment 1

[0022] A high-strength denitration catalyst, including the following raw materials in weight: 92g of titanium dioxide, 26g of silicon dioxide, 10g of tungsten trioxide, 4g of vanadium pentoxide, 3g of expanded perlite, 5g of attapulgite, 2g of hollow glass beads, and Ester fiber 3g. Among them, titanium dioxide is rutile-type titanium dioxide, with a particle size range of 90-110nm; the standard for selecting expanded perlite is 10-20 times the expansion coefficient, and the thermal conductivity is 0.045-0.052W / (m·K).

[0023] The preparation method of the above-mentioned high-strength denitration catalyst comprises the following steps:

[0024] (1) Preparation of catalyst base material: Weigh titanium dioxide, silicon dioxide, tungsten trioxide, and vanadium pentoxide according to weight, mix and stir evenly at 35°C, then send them into a calender with gears, and roll through two gears. Obtain a substrate plate, and then pass it into a hydraulic press to compress to obtain a...

Embodiment 2

[0028] A high-strength denitration catalyst, including the following raw materials: 88g of titanium dioxide, 27g of silicon dioxide, 12g of tungsten trioxide, 5g of vanadium pentoxide, 2g of expanded perlite, 4g of attapulgite, 2g of hollow glass beads, and Ester fiber 3g. Among them, titanium dioxide is rutile-type titanium dioxide, with a particle size range of 90-110nm; the standard for selecting expanded perlite is 10-20 times the expansion coefficient, and the thermal conductivity is 0.045-0.052W / (m·K).

[0029] The preparation method of the above-mentioned high-strength denitration catalyst comprises the following steps:

[0030] (1) Preparation of catalyst substrate: Weigh titanium dioxide, silicon dioxide, tungsten trioxide, and vanadium pentoxide according to weight, mix and stir evenly at 40°C, then send them into a calender with gears, and roll through two gears. Obtain a substrate plate, and then pass it into a hydraulic press to compress to obtain a catalyst subs...

Embodiment 3

[0034] A high-strength denitrification catalyst, including the following raw materials in weight: 83g of titanium dioxide, 30g of silicon dioxide, 15g of tungsten trioxide, 6g of vanadium pentoxide, 5g of expanded perlite, 3g of attapulgite, 2g of hollow glass beads, poly Ester fiber 1g. Among them, titanium dioxide is rutile-type titanium dioxide, with a particle size range of 90-110nm; the standard for selecting expanded perlite is 10-20 times the expansion coefficient, and the thermal conductivity is 0.045-0.052W / (m·K).

[0035] The preparation method of the above-mentioned high-strength denitration catalyst comprises the following steps:

[0036] (1) Preparation of catalyst substrate: Weigh titanium dioxide, silicon dioxide, tungsten trioxide, and vanadium pentoxide according to weight, mix and stir evenly at 30-40°C, then send them into a calender with gears, and pass through two gears The substrate plate is obtained by occlusal rolling, and then passed into a hydraulic ...

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Abstract

The invention discloses a strong-strength denitration catalyst and a preparation method for the same. The denitration catalyst is prepared from the following raw materials in parts by weight: 80 to 100 parts of titanium dioxide, 20 to 35 parts of silicon dioxide, 8 to 16 parts of tungsten trioxide, 3 to 8 parts of vanadium pentoxide, 1 to 6 parts of expanded perlite, 2 to 7 parts of attapulgite, 1 to 3 parts of hollow glass beads and 1 to 3 parts of polyester fibers. The preparation method for the denitration catalyst comprises preparation of a catalyst substrate, impregnation and adsorption with mixed liquor, and drying and calcination. The denitration catalyst disclosed by the method is strong in compressive strength and cleavage strength, moderate in porosity, low in pulverization and cracking rate, high in catalytic efficiency and long in service life, the using amount is greatly reduced, a preparation process is simple and controllable, and the energy consumption is reduced.

Description

technical field [0001] The invention relates to the field of electric catalysts, in particular to a high-strength denitration catalyst and a preparation method thereof. Background technique [0002] The installed capacity, power generation and coal consumption of my country's thermal power industry are all showing a growing trend, and the resulting nitrogen oxides are increasingly harmful to the environment. According to different catalyst carriers, the catalysts currently on the market for stationary source tail gas denitrification are mainly honeycomb catalysts. The catalyst has low pressure drop, wear resistance and excellent denitrification activity and has been widely used, but the existing honeycomb catalyst has some shortcomings, and its optimum working temperature is generally 300-450 °C. In actual working conditions, it is difficult for the flue gas temperature to reach this temperature range; on the other hand, in order to achieve better denitrification effect and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/30B01J35/10
CPCB01J23/002B01J23/30B01J35/1004B01J2523/00B01J2523/41B01J2523/47B01J2523/55B01J2523/69
Inventor 杨自芬
Owner HEFEI DAZHUO ELECTRIC POWER CO LTD
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