Adhesive sheet, method for producing the same, and method for producing optical member using the same
A manufacturing method and technology of optical components, applied in the direction of bonding method, adhesive, adhesive type, etc., can solve the problems of floating, peeling, decreased cohesion, contamination of the adherend, etc., and achieves excellent absorption of height difference, Excellent reworkability and excellent properties
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Embodiment
[0067] Hereinafter, the present invention will be described in further detail by way of examples. In the following description, "part" and "%" mean "part by mass" and "% by mass".
[0068]
[0069] In a reaction vessel equipped with a stirrer, a reflux condenser, a thermometer, a UV lamp, and a nitrogen gas inlet, the acrylic monomers of the composition (%) shown in Table 1 were charged, and further added to 100 parts of the total monomers as a photopolymerization initiator. 0.01 part of an acetophenone-based initiator (manufactured by BASF Japan, trade name DAROCUR1173) and 0.01 part of n-dodecyl mercaptan as a chain transfer agent. Then, UV light was irradiated in a nitrogen atmosphere to perform partial polymerization by a bulk polymerization method, and solventless syrupy acrylic resin compositions a to c were obtained. Table 1 shows the weight average molecular weight (Mw) and concentration (%) of the polymers in the composition.
[0070]
[0071] In a reaction vess...
Embodiment 2
[0085] A solventless curable resin was prepared in the same manner as in Example 1, except that 0.03 part of n-dodecanethiol (nDSH) as a chain transfer agent was further added to 100 parts of syrupy acrylic resin composition a. composition to produce an adhesive sheet.
Embodiment 3
[0087]With respect to 100 parts of syrupy acrylic resin composition a, 0.03 parts of n-dodecanethiol (nDSH) as a chain transfer agent and an epoxy-based silane coupling agent (manufactured by Shin-Etsu Chemical Co., Ltd., trade name KBM-403) were further added ), except that, it carried out similarly to Example 1, and prepared the solvent-free curable resin composition, and produced the adhesive sheet.
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Abstract
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