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Cover rubber used for low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt, and preparation method thereof

A low-temperature vulcanization, high-performance technology, applied in the field of conveyor belts, can solve the problems of equipment control system corrosion, loss of mechanical properties of skeleton materials, asynchronous temperature rise of rubber materials, etc. Safety, the effect of excellent mechanical properties

Active Publication Date: 2017-10-20
WUXI BOTON CONVEYOR SOLUTION CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

(2) The smog contains a large amount of corrosive substances, which will corrode the control system of equipment and instruments, and cause secondary disasters due to operation failure
[0003] If the vulcanization temperature is too high, the disadvantages are obvious: firstly, if the vulcanization temperature is too high, the rubber and the skeleton material will be aged and scorched, resulting in a serious loss of the mechanical properties of the skeleton material, and the mechanical properties of the conveyor belt cannot be guaranteed; secondly, due to the thermal conductivity of the rubber material Poor, when vulcanized at a higher temperature, the temperature rise between the inside and outside of the rubber material will not be synchronized, and the temperature difference between the inside and the outside will increase, so that the outside of the rubber has reached a positive vulcanization state, but the internal temperature continues to rise and cause the rubber The volume of the material continues to expand, causing defects such as product wrinkles, cracks, and inner voids

Method used

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  • Cover rubber used for low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt, and preparation method thereof
  • Cover rubber used for low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt, and preparation method thereof
  • Cover rubber used for low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A high-performance halogen-free flame-retardant laminated conveyor belt cover rubber, the formula ratio is as follows in parts by weight: 100 parts of rubber matrix (50 parts of EVM 400 rubber, 30 parts of EVM 500 rubber, 20 parts of EBA 17BA07 rubber), cross-linked 2.5 parts of agent (1 part of TBPO, 1.5 parts of BPO), 1.2 parts of co-crosslinking agent (1 part of TAIC, 0.2 part of HVA-2), 3 parts of plasticizer DOS, 2 parts of anti-aging agent DDA-702 parts, anti-hydrolysis agent PCD- 6 parts of 50, 2 parts of Chemmix 18D anti-sticking agent, 2 parts of silane coupling agent (1.2 parts of KH-570, 0.8 parts of SI-69), 45 parts of filling and reinforcing agent (15 parts of N234, 10 parts of N330, high dispersion SiO 2 20 parts) and 35 parts of flame retardant (15 parts of aluminum diethylphosphinate, 15 parts of diphenyl sulfone polyphenylphosphate, 5 parts of melamine polyphosphate).

[0025] Specific steps are as follows:

[0026] (1) Primary mixing: Control the te...

Embodiment 2

[0030] A high-performance covering rubber for halogen-free flame-retardant laminated conveyor belts, the formula ratio is as follows in parts by weight: 100 parts of rubber matrix (30 parts of EVM 400 rubber, 40 parts of EVM 500 rubber, 30 parts of EBA 17BA04 rubber), cross-linked 3.5 parts of agent (2 parts of TBPO, 0.5 parts of BPO, 1 part of TBPB), 2.5 parts of co-crosslinking agent (1.5 parts of TAIC, 0.5 parts of HVA-2, 0.5 parts of TMPTMA), 3 parts of plasticizer DOS, anti-aging agent DDA- 70 2 parts, anti-hydrolysis agent PCD-50 6 parts, anti-adhesive additive Chemmix 18D 2 parts, silane coupling agent 2.5 parts (KH-570 1 part, KH-550 1.5 parts), filling reinforcing agent 60 parts (N234 20 parts, highly dispersed SiO 2 40 parts), 45 parts of flame retardant (18 parts of aluminum diethylphosphinate, 15 parts of diphenyl sulfone polyphenylphosphate, 8 parts of melamine polyphosphate, 4 parts of zinc borate).

[0031] Specific steps are as follows:

[0032] (1) Primary ...

Embodiment 3

[0036] A high-performance halogen-free flame-retardant laminated conveyor belt cover rubber, the formula ratio is as follows in parts by weight: 100 parts of rubber matrix (30 parts of EVM 500 rubber, 50 parts of EVM 600 rubber, 20 parts of EBA 17BA07 rubber), cross-linked 5 parts of agent (TBPO 2 parts, TBPB 1.5 parts, CH 335 1.5 parts), co-crosslinking agent 3.5 parts (TAIC 1.7 parts, HVA-2 0.8 parts, TMPTMA 1 part), plasticizer DOS 3 parts, antioxidant DDA 2 parts of -70, 6 parts of anti-hydrolysis agent PCD-50, 2 parts of anti-sticking additive Chemmix 18D, 4 parts of silane coupling agent (2 parts of KH-570, 0.8 parts of KH-550, 1.2 parts of SI-69), filling 75 parts of reinforcing agent (25 parts of N234, 10 parts of N3302, 40 parts of highly dispersed SiO2), 60 parts of flame retardant (35 parts of polyphenylsulfone diphenyl phosphate, 12 parts of melamine polyphosphate, 13 parts of zinc borate).

[0037] Specific steps are as follows:

[0038] (1) Primary mixing: contr...

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PUM

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Abstract

The invention relates to a low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt cover rubber, and belongs to the technical field of conveyor belt. According to a preparation method, EVM and EBA mixed rubber is taken as a matrix; a peroxide is taken as a cross-linking agent, and an auxiliary crosslinking agent, a silane coupling agent, a filling reinforcing agent, a fire retardant, and other auxiliary agents are added; and high-performance halogen-free flame-retardant laminated conveyor belt is obtained via low temperature (95-120 DEG C) vulcanization using a plate vulcanizing machine. Effective low temperature vulcanization of the low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt cover rubber can be realized at a relatively low temperature; vulcanization of the low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt cover rubber at low temperature conditions is capable of protecting the excellent performance of a cover rubber matrix and adopted skeleton materials, ensuring the safety of conveyor belt technology, and increasing production efficiency. The preparation method is capable of solving a difficult problem that the excellent performance of rubber matrix and the skeleton materials is destroyed by relatively high halogen-free flame-retardant cover rubber vulcanization temperature; rubber vulcanization technology is improved; a method is provided for production of special conveyor belt; and company benefit is increased.

Description

technical field [0001] The invention relates to a low-temperature vulcanized high-performance halogen-free flame-retardant laminated conveyor belt covering rubber and a preparation method thereof, belonging to the technical field of conveyor belts. Background technique [0002] Flame retardant research in the rubber industry started in the 1950s and developed in the 1960s. The most commonly used method is to add non-combustible or flame-retardant materials and additives to the rubber product materials, such as: aluminum hydroxide, magnesium hydroxide, chlorinated paraffin, phosphate esters and brominated flame retardants. These flame-retardant materials have obvious flame-retardant effects, making rubber products flame-retardant or non-flammable. However, with the development of science and technology, people have found that although many fires have adopted high-efficiency flame-retardant materials, the losses caused by fires are still very large. It can be classified into...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L85/02C08K13/02C08K3/36C08K5/5313C08K5/3492C08K3/38C08K3/04B29B7/00B29B7/72B29C35/02
CPCB29B7/005B29B7/726B29C35/02C08K2003/387C08L23/0853C08L2201/02C08L2201/04C08L2201/22C08L2205/025C08L2205/035C08L85/02C08K13/02C08K3/36C08K5/5313C08K5/34928C08K3/04C08K3/38
Inventor 宁南英邢永昌萨日娜田明杨鑫陈思献孙业斌吴建国
Owner WUXI BOTON CONVEYOR SOLUTION CO LTD
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