Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A nitric acid selective leaching method for low-nickel high-iron alloy powder

A ferroalloy and selective technology, applied in the direction of improving process efficiency, can solve the problems of high iron removal cost, cobalt loss, and difficulty in iron removal, and achieve the effects of saving nitric acid consumption, ensuring leaching rate, and saving production costs

Active Publication Date: 2019-01-22
JINCHUAN GROUP LIMITED
View PDF10 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The ferronickel powder is mainly directly used in the production of stainless steel, in which nickel can only be used as a low-end product, and cobalt enters the stainless steel with nickel, causing a large loss of cobalt, which does not reflect the value of cobalt
The metals in the coarse nickel-iron powder mainly exist in the form of simple substances or alloys. Using traditional sulfuric acid leaching, the leaching rate of nickel and cobalt is below 50%, and a large amount of iron enters the solution in the form of divalent iron, which makes it difficult to remove iron in the next step; chlorine The leaching rate of nickel, iron and cobalt in chemical leaching can reach about 95%, but the cost of iron removal is high

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A nitric acid selective leaching method for low-nickel high-iron alloy powder
  • A nitric acid selective leaching method for low-nickel high-iron alloy powder
  • A nitric acid selective leaching method for low-nickel high-iron alloy powder

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] The composition of the low-nickel high-iron alloy powder is shown in Table 1.

[0015] Table 1: Composition of low-nickel high-iron alloy powder (%)

[0016]

[0017] The nitric acid selective leaching method of the low-nickel high-iron alloy powder comprises the following steps:

[0018] a) One-stage full immersion-magnetic separation: Add concentrated nitric acid to the low-nickel and high-iron alloy powder, the amount of concentrated nitric acid is 100ml / 100g of low-nickel and high-iron alloy powder, then add diluent to control the liquid-solid ratio to 5:1, the leaching temperature at 105°C, the leaching time is 4h, and NO is recovered during the leaching process x (a mixture of NO and NO2), magnetic separation is carried out at the end of full leaching, the magnetic separation concentrate returns to continue leaching, the rest of the pulp is filtered and separated from liquid to solid, and the obtained leaching slag is silicon slag, which is discharged outside;...

Embodiment 2

[0022] The composition of the low-nickel high-iron alloy powder is shown in Table 2.

[0023] Table 2: Composition of low-nickel and high-iron alloy powder (%)

[0024]

[0025] The nitric acid selective leaching method of the low-nickel high-iron alloy powder comprises the following steps:

[0026] a) One-stage full immersion-magnetic separation: Add concentrated nitric acid to the low-nickel and high-iron alloy powder, the amount of concentrated nitric acid is 200ml / 100g of low-nickel and high-iron alloy powder, then add diluent to control the liquid-solid ratio to 10:1, and the leaching temperature at 75°C, the leaching time is 8h, and NO is recovered during the leaching process x (a mixture of NO and NO2), magnetic separation is carried out at the end of full leaching, the magnetic separation concentrate returns to continue leaching, the rest of the pulp is filtered and separated from liquid to solid, and the obtained leaching slag is silicon slag, which is discharged ...

Embodiment 3

[0030] The composition of the low-nickel high-iron alloy powder is shown in Table 3.

[0031] Table 3: Composition of low-nickel and high-iron alloy powder (%)

[0032]

[0033] The nitric acid selective leaching method of the low-nickel high-iron alloy powder comprises the following steps:

[0034] a) One-stage full immersion-magnetic separation: Add concentrated nitric acid to the low-nickel and high-iron alloy powder, the amount of concentrated nitric acid added is 300ml / 100g of low-nickel and high-iron alloy powder, then add diluent to control the liquid-solid ratio to 8:1, and the leaching temperature at 90°C, the leaching time is 6h, and NO is recovered during the leaching process x (a mixture of NO and NO2), magnetic separation is carried out at the end of full leaching, the magnetic separation concentrate returns to continue leaching, the rest of the pulp is filtered and separated from liquid to solid, and the obtained leaching slag is silicon slag, which is discha...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention discloses a method for leaching low-nickel high-iron alloy powder selectively through nitric acid. The method comprises the steps that firstly, primary leaching is conducted on the low-nickel high-iron alloy powder through the concentrated nitric acid; when total immersion is ended, magnetic separation is conducted; magnetic separation concentrate is returned for further leaching, so that after remaining ore pulp is filtered, leaching residues and a leaching solution are obtained, and the leaching solution enters a neutralization-for-iron-removal procedure; the low-nickel high-iron alloy powder is added to the leaching solution, so that neutralization for iron removal is conducted; after a neutralization-for-iron-removal reaction is ended, magnetic separation is conducted; magnetic separation concentrate is returned to the primary total immersion procedure, so that after ore pulp is filtered, neutralization iron slag and a separation and immersion solution are obtained; and the neutralization iron slag obtained after filtration is subjected to washing, drying and calcinations, so that an iron ore concentrate product with the iron content ranging from 60% to 65% is obtained. By means of the method, nickel and cobalt leaching and iron removal are completed through one step, and selective leaching of nickel, cobalt and iron is achieved; the nickel and the cobalt enter the solution, and the iron is inhibited in the slag, so that the nickel and the cobalt are effectively separated from the iron; and the leaching rate of the nickel and the cobalt is greater than 98%; the nickel content of the leaching residues is less than 0.5%, the iron content of the leaching residues is less than 10%, and the cobalt content of the leaching residues is less than 0.02%; the iron content of the neutralization iron slag is greater than 50%, and the nickel content o the neutralization iron slag is less than 0.1%; and the iron content of the separation and immersion solution is less than 3 g / L.

Description

technical field [0001] The invention belongs to the technical field of nonferrous metal hydrometallurgy, and in particular relates to a nitric acid selective leaching method for low-nickel and high-iron alloy powder. Background technique [0002] The laterite nickel ore adopts the crude ferronickel produced by the RKEF smelting process, which is low-nickel and high-iron alloy powder, and the composition is 2%-8%Ni, 50%-68%Fe, 0.08%-0.3%Co, 0.1%-0.6%Mn , 3%-10%Mg, 0.3%-1.0%Al, 1.0%-2.8%Cr, 3%-10%Si. The ferronickel powder is mainly directly used in the production of stainless steel, in which nickel can only be used as a low-end product, and cobalt enters the stainless steel with nickel, causing a large loss of cobalt, which does not reflect the value of cobalt. The metals in the coarse nickel-iron powder mainly exist in the form of simple substances or alloys. Using traditional sulfuric acid leaching, the leaching rate of nickel and cobalt is below 50%, and a large amount of...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C22B3/06C22B3/44C22B23/00
CPCC22B3/065C22B3/44C22B23/0438C22B23/0461Y02P10/20
Inventor 刘玉强李尚勇张晗陈彩霞张娟朱锐伦张树峰李娟李维舟田忠元李全沙滨欧晓健席海龙王书友高晓婷郁洪波孔令军马天飞
Owner JINCHUAN GROUP LIMITED
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products