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A kind of preparation method of hollow fiber composite loose nanofiltration membrane

A fiber composite, nanofiltration membrane technology, applied in spinning solution preparation, chemical instruments and methods, membranes, etc., can solve problems such as large pollution, odor, sensory pollution, etc., and achieve simple preparation method and small separation pore size. , the effect of small footprint

Active Publication Date: 2020-10-30
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to biodegradation, the organic matter in the concentrated water will make the receiving water body anoxic or even anaerobic, and most aquatic organisms will die, resulting in foul smell, deteriorating water quality and environment
② Sensory pollution
Concentrated organic matter not only makes the water body lose its use value, but also seriously affects the normal life of people near the water body
③ Toxic hazard
Organic matter in concentrated water has a high degree of pollution to the environmental water body, and the treatment is difficult, which is one of the problems in the field of environmental protection research at home and abroad.

Method used

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  • A kind of preparation method of hollow fiber composite loose nanofiltration membrane
  • A kind of preparation method of hollow fiber composite loose nanofiltration membrane
  • A kind of preparation method of hollow fiber composite loose nanofiltration membrane

Examples

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Effect test

Embodiment 1

[0028] (1) Preparation of polyethersulfone casting solution:

[0029] According to the proportion by weight: the mass ratio of polyethersulfone: dimethylacetamide: polyethylene glycol is 34:50:16 and mixed in the stirring tank, stirring and dissolving in the stirring tank at a temperature of 65°C for 12 hours ; The polyethersulfone casting solution obtained by stirring and dissolving is transferred to the spinning storage tank, and the polyethersulfone spinning casting solution is obtained by standing at a temperature of 65° C. for defoaming and aging.

[0030] (2) Preparation of polyethersulfone hollow fiber nanofiltration membrane:

[0031] The pressure of 0.2MPa is provided by the nitrogen cylinder, so that the casting liquid passes through the flow-controllable feed metering pump, enters the spinneret at a flow rate of 15mL / min, and is sprayed vertically downward under the action of the core liquid at a flow rate of 5mL / min. out. After passing through a 40cm air bath, th...

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Abstract

The invention provides a preparation method of a hollow fiber composite loose nanofiltration membrane. The method comprises the following steps: blending and dissolving polyether sulfone, dimethylacetamide and polyethylene glycol, so as to form spinning casting membrane solution, spinning through certain technological conditions, so as to obtain hollow fiber external pressed film, and soaking through sulfuric acid aqueous solution, so as to obtain a hollow fiber composite loose nanofiltration membrane with the a separation aperture reaching a nanoscale. The loose nanofiltration membrane has the advantages of simple preparation method, large volume fraction, small floor space, high treatment efficiency and small separation aperture, has good removal effect on particulate matter colloid, has good removal effect on low molecular weight organic matter in water, and can intercept molecules with molecular weight below 1000Da. The loose nanofiltration membrane can be effectively applied to the pretreatment of organic matter in concentrated water, for example the loose nanofiltration membrane can be applied to the separation of antibiotics and dye, with the molecular weight being about 1000g / mol, in water and an organic solvent. The loose nanofiltration membrane further has good removal effect on inorganic matter.

Description

technical field [0001] The invention relates to the technical field of polymer material membranes, in particular to a method for preparing hollow fiber composite loose nanofiltration membranes. Background technique [0002] With the development of economy and technology, separation technology occupies a pivotal position in modern industry, especially in the field of chemical industry. In recent years, membrane separation technology has gradually replaced traditional separation technologies such as extraction and rectification due to its advantages of low energy consumption, low emission, high degree of automation, and small footprint. It is one of the emerging separation technologies and is a solution to sewage treatment, An important means of water problems such as seawater desalination and reclaimed water reuse. At present, the membrane separation industry can not only carry out gradient separation for different molecular weight substances, but also realize the recovery o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D61/02B01D63/02B01D69/12B01D67/00B01D71/06D01D1/02D01D5/06
CPCB01D61/027B01D63/02B01D67/0088B01D69/12B01D71/06B01D2323/46D01D1/02D01D5/06
Inventor 褚华强张亚雷周雪飞马睿蒋淑红赵新华
Owner TONGJI UNIV
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