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A kind of latex without precipitation and bactericidal function, preparation method and application

A latex and functional technology, applied in the field of functional latex preparation, can solve the problems of easy occurrence of bubbles, pinholes, color spots, silver ion precipitation and discoloration, agglomeration and uneven dispersion, etc. , to ensure long-term effect

Active Publication Date: 2020-11-27
苏州美纳福健康科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when nano-silver is mixed with natural latex, there are problems of agglomeration and uneven dispersion. In addition, silver antibacterial has the problem of silver ion precipitation and discoloration, and the effect on Candida albicans is weak. In addition, silver ion precipitation is easy to cause adverse effects on the environment and human health.
[0006] Chinese invention patent (CN101541312A) provides a preparation method of nano-composite antibacterial agent and antibacterial NL latex and antibacterial TPI rubber. The calcined powder of the composite antibacterial agent is added to the latex collagen solution. There are mainly composite antibacterial agent powder and natural The problems of agglomeration and uneven dispersion during latex mixing lead to the inability to fully exert the antibacterial effect. At the same time, quality problems such as air bubbles, pinholes, and color points are prone to occur during the production of the film, which affects the mechanical properties and appearance of the film.

Method used

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  • A kind of latex without precipitation and bactericidal function, preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Dissolve zinc acetate, cerium nitrate, and polyvinylpyrrolidone in water at a molar ratio of 1:0.01:2.2 to prepare a 0.05M aqueous dispersion A; gradually add 10 ml of aqueous solution A to 100 ml of glycerol B; In a microwave oven, react at 150°C for 30 minutes, cool, centrifuge, and filter off the supernatant to obtain a nanocrystalline self-dispersion slurry with a crystallite size below 5nm; in latex liquid, 2% relative to natural latex The above-mentioned nano-mineral self-dispersion is injected into the above-mentioned nano-mineral self-dispersion according to the mass ratio, and the nano-emulsion mother liquor is obtained by mixing uniformly; the antibacterial latex condom is obtained by performing dipping, drying, demoulding, vulcanization, and post-treatment according to conventional production methods.

[0024] Table 1 is the metal ion precipitation detection result of the nano antibacterial latex product that is made according to the processing method of the p...

Embodiment 2

[0030] Dissolve copper acetate, cerium nitrate, and cyclodextrin in water at a molar ratio of 1:0.01:2.2 to prepare 0.05M aqueous dispersion A; gradually add 10 ml of aqueous solution A to 100 ml of polyethylene glycol B; put Put it into a microwave oven, react at 160°C for 30min, cool, centrifuge, and filter the supernatant to obtain a nanocrystalline self-dispersion slurry with a crystallite size below 5nm; % mass ratio Inject the above-mentioned nano-mineral self-dispersion, mix evenly, and obtain a brown nano-emulsion mother liquor; perform dipping molding, drying, demoulding, vulcanization, and post-treatment according to conventional production methods to prepare antibacterial gloves.

[0031] The metal ion precipitation detection result of the nano antibacterial latex product obtained by the processing method of this embodiment: Cu element is 0.435 mg / L, Ce element is 0.037 mg / L, all less than 1ppm, can be regarded as no precipitation. Its antibacterial effect is simila...

Embodiment 3

[0033] Dissolve zirconium acetate, neodymium nitrate, and lecithin in water at a molar ratio of 1:0.01:3 to prepare 0.05M aqueous dispersion A; gradually add 10 ml of aqueous solution A to 100 ml of glycerol B; put it in a microwave oven , react at 150°C for 30 minutes, cool, centrifuge, and filter off the supernatant to obtain a nanocrystalline self-dispersion slurry with a crystallite size below 5nm; in latex liquid, according to 3% mass relative to natural latex The above-mentioned nano-mineral self-dispersion is injected, mixed evenly, to obtain a nano-emulsion mother liquor; dipping molding, drying, demoulding, vulcanization, and post-treatment are carried out according to conventional production methods to prepare antibacterial pillows.

[0034] The metal ion precipitation test results of the nano antibacterial latex products prepared by the processing method of this embodiment are all less than 1ppm, which can be regarded as no precipitation. Its antibacterial effect is...

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Abstract

The invention discloses latex without separation and with sterilizing function as well as a preparation method and application thereof. The method comprises the following steps: preparing one or more soluble metal salt into an aqueous solution, adding few rare earth mineral elements and complexing agent and then dropwise adding into an organic solvent, thereby forming a stable water-in-oil system; reacting for 30-90min under the temperature at 120-170 DEG C, cooling, centrifugally separating and filtering supernate, thereby acquiring a nano-crystalline self-dispersing component; adding the nano-crystalline self-dispersing component which is 2-10% of the latex at mass ratio into a latex solution and uniformly mixing, thereby acquiring a nanometer latex mother liquor. The nanometer latex mother liquor can be used for preparing the latex products, such as, antibacterial condoms, gloves, pillows, and the like. The latex product provided by the invention has an efficient long-lasting antibacterial odor-removing function, does not separate metal ion, is safe and environmentally friendly and is capable of effectively solving the problem of separation discoloration caused by the generally used silver ion at present.

Description

technical field [0001] The invention discloses a latex with a bactericidal function, a preparation method and an application, in particular to a latex without a sterilizing function, a preparation method and an application, and belongs to the technical field of functional latex preparation. Background technique [0002] Latex products are one of the necessities of life, among which condoms, pillows, and gloves are widely used in latex. With the development of science and technology and the further improvement of people's living standards, the development and application of antibacterial latex has become a major direction for the research and development of functional latex in my country. [0003] Condoms are one of the main products of latex. Antibacterial condoms are more necessary. On the one hand, they can avoid cross-infection. In addition, the antibacterial properties of condoms are beneficial to the alleviation of female gynecological diseases. Therefore, research on a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L7/02C08L39/06C08L5/16C08L91/00C08J5/02
CPCC08J5/02C08J2307/02C08J2405/16C08J2439/06C08J2491/00C08L7/02C08L39/06C08L5/16C08L91/00
Inventor 王作山郑敏
Owner 苏州美纳福健康科技有限公司
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